CA1268033C - Polyoxometalate modified carbon electrodes and uses therefor - Google Patents

Polyoxometalate modified carbon electrodes and uses therefor

Info

Publication number
CA1268033C
CA1268033C CA514106A CA514106A CA1268033C CA 1268033 C CA1268033 C CA 1268033C CA 514106 A CA514106 A CA 514106A CA 514106 A CA514106 A CA 514106A CA 1268033 C CA1268033 C CA 1268033C
Authority
CA
Canada
Prior art keywords
electrodes
charge storage
polyoxometalate
uses therefor
carbon electrodes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA514106A
Other languages
French (fr)
Other versions
CA1268033A (en
Inventor
James L Callahan
Edward A Cuellar
Michael J Desmond
John C Currie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Application granted granted Critical
Publication of CA1268033A publication Critical patent/CA1268033A/en
Publication of CA1268033C publication Critical patent/CA1268033C/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/002—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/34—Carbon-based characterised by carbonisation or activation of carbon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/52—Separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

ABSTRACT POLYOXOMETALATE-MODIFIED CARBON ELECTRODES AND USES THEREFOR Improved activated carbon electrodes are disclosed, which electrodes have increased charge storage capacity. Such improved electrodes are incorporated into energy storage devices such as electrical double layer capacitors. The improved charge storage capacity is due to the adsorption of polyoxometalate compounds into the activated carbon, which compounds are capable of reversible redox reactions and so provide a secondary charge storage mechanism without decreasing the charge storage ability of the activated carbon.
CA514106A 1985-08-26 1986-07-18 Polyoxometalate modified carbon electrodes and uses therefor Expired CA1268033C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US769,925 1985-08-26
US06/769,925 US4633372A (en) 1985-08-26 1985-08-26 Polyoxometalate-modified carbon electrodes and uses therefor in capacitors

Publications (2)

Publication Number Publication Date
CA1268033A CA1268033A (en) 1990-04-24
CA1268033C true CA1268033C (en) 1990-04-24

Family

ID=25086925

Family Applications (1)

Application Number Title Priority Date Filing Date
CA514106A Expired CA1268033C (en) 1985-08-26 1986-07-18 Polyoxometalate modified carbon electrodes and uses therefor

Country Status (5)

Country Link
US (1) US4633372A (en)
EP (1) EP0214738A3 (en)
JP (1) JPS62115818A (en)
KR (1) KR870002619A (en)
CA (1) CA1268033C (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4878150A (en) * 1987-02-20 1989-10-31 Colgate-Palmolive Co. Polarizable material having a liquid crystal microstructure and electrical components produced therefrom
US5206797A (en) * 1987-02-20 1993-04-27 Colgate-Palmolive Company Nonisotropic solution polarizable material and electrical components produced therefrom
US5038249A (en) * 1987-02-20 1991-08-06 Colgate-Palmolive Co. Nonisotropic solution polarizable material and electrical components produced therefrom
US4960450A (en) * 1989-09-19 1990-10-02 Syracuse University Selection and preparation of activated carbon for fuel gas storage
DE69128805T2 (en) * 1990-03-29 1998-05-14 Matsushita Electric Ind Co Ltd Electrolytic double layer capacitor and process for its manufacture
US5136474A (en) * 1990-04-03 1992-08-04 Giner, Inc. Proton exchange membrane electrochemical capacitors
US5501922A (en) * 1995-04-07 1996-03-26 Motorola, Inc. Polyoxometalate carbon electrodes and energy storage device made thereof
US5659457A (en) * 1995-04-07 1997-08-19 Motorola, Inc. Carbon electrodes and energy storage device made thereof
US5587250A (en) * 1995-09-27 1996-12-24 Motorola, Inc. Hybrid energy storage system
JP2947215B2 (en) * 1997-03-28 1999-09-13 日本電気株式会社 Electric double layer capacitor and method of manufacturing the same
US6479030B1 (en) 1997-09-16 2002-11-12 Inorganic Specialists, Inc. Carbon electrode material
US5993996A (en) * 1997-09-16 1999-11-30 Inorganic Specialists, Inc. Carbon supercapacitor electrode materials
US7001889B2 (en) 2002-06-21 2006-02-21 Merial Limited Anthelmintic oral homogeneous veterinary pastes
US20050142438A1 (en) * 2003-07-18 2005-06-30 Johnson George H. Hydrogen generating apparatus and methods
US7419745B2 (en) * 2004-03-31 2008-09-02 Sanjay Chaturvedi Method of forming an electrode structure useful in energy storage devices
US8362086B2 (en) 2005-08-19 2013-01-29 Merial Limited Long acting injectable formulations
KR100823021B1 (en) * 2006-12-06 2008-04-17 광주과학기술원 Liquid fuel composition and fuel cell using same
EP2445041B1 (en) * 2009-06-17 2016-04-13 Sony Corporation Nonaqueous electrolyte battery, positive electrode for nonaqueous electrolyte battery, negative electrode for nonaqueous electrolyte battery, separator for nonaqueous electrolyte battery, electrolyte for nonaqueous electrolyte battery, and method for producing separator for nonaqueous electrolyte battery
JP5273124B2 (en) * 2009-11-05 2013-08-28 ソニー株式会社 Positive electrode and non-aqueous electrolyte battery
JP5625389B2 (en) * 2010-03-02 2014-11-19 ソニー株式会社 Non-aqueous electrolyte battery
JP5463957B2 (en) 2010-03-02 2014-04-09 ソニー株式会社 Non-aqueous electrolyte and battery
JP5471598B2 (en) * 2010-03-02 2014-04-16 ソニー株式会社 Non-aqueous electrolyte battery
JP5533035B2 (en) * 2010-03-02 2014-06-25 ソニー株式会社 Nonaqueous electrolyte composition and nonaqueous electrolyte battery
CN110310839B (en) * 2019-07-05 2021-05-25 哈尔滨理工大学 A novel polyacid-based MOF material with conductive network structure and its application

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335345A (en) * 1967-08-08 Pyrolytic graphite
US3536963A (en) * 1968-05-29 1970-10-27 Standard Oil Co Electrolytic capacitor having carbon paste electrodes
US3648126A (en) * 1970-12-28 1972-03-07 Standard Oil Co Ohio Electrical capacitor employing paste electrodes
US3804740A (en) * 1972-02-01 1974-04-16 Nora Int Co Electrodes having a delafossite surface
US4173518A (en) * 1974-10-23 1979-11-06 Sumitomo Aluminum Smelting Company, Limited Electrodes for aluminum reduction cells
US4024036A (en) * 1975-02-03 1977-05-17 Agency Of Industrial Science & Technology Proton permselective solid-state member and apparatus utilizing said permselective member
US4396687A (en) * 1980-12-08 1983-08-02 Ford Motor Company Chemically regenerable redox fuel cell and method of operating the same
US4407902A (en) * 1980-12-08 1983-10-04 Ford Motor Company Chemically regenerable redox fuel cell and method of operating the same
CA1190595A (en) * 1982-05-03 1985-07-16 Donald L. Boos Double layer energy storage device
JPS5960818A (en) * 1982-09-29 1984-04-06 帝人株式会社 Electrode material
US4542442A (en) * 1983-06-17 1985-09-17 Simmonds Precision Products, Inc. Apparatus for the mounting and wiring of printed circuit boards

Also Published As

Publication number Publication date
JPS62115818A (en) 1987-05-27
US4633372A (en) 1986-12-30
CA1268033A (en) 1990-04-24
KR870002619A (en) 1987-04-06
EP0214738A3 (en) 1987-06-03
EP0214738A2 (en) 1987-03-18

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Legal Events

Date Code Title Description
MKLA Lapsed
MKLA Lapsed

Effective date: 19921026