CA1190923A - Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose - Google Patents
Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucoseInfo
- Publication number
- CA1190923A CA1190923A CA000371826A CA371826A CA1190923A CA 1190923 A CA1190923 A CA 1190923A CA 000371826 A CA000371826 A CA 000371826A CA 371826 A CA371826 A CA 371826A CA 1190923 A CA1190923 A CA 1190923A
- Authority
- CA
- Canada
- Prior art keywords
- reaction zone
- continuously
- cellulose
- zone
- dynamic seal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 144
- 239000001913 cellulose Substances 0.000 title claims abstract description 58
- 229920002678 cellulose Polymers 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 39
- 230000008569 process Effects 0.000 title claims abstract description 38
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 title claims abstract description 20
- 239000008103 glucose Substances 0.000 title claims abstract description 20
- 239000002699 waste material Substances 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 title claims description 46
- 239000000126 substance Substances 0.000 title claims description 7
- 239000002253 acid Substances 0.000 claims abstract description 33
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000007599 discharging Methods 0.000 claims abstract description 12
- 239000003377 acid catalyst Substances 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims description 25
- 239000000376 reactant Substances 0.000 claims description 18
- 239000002657 fibrous material Substances 0.000 claims description 14
- 238000005903 acid hydrolysis reaction Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 230000004044 response Effects 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 3
- 230000003301 hydrolyzing effect Effects 0.000 claims 5
- 208000036366 Sensation of pressure Diseases 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000001678 irradiating effect Effects 0.000 claims 1
- 235000010980 cellulose Nutrition 0.000 description 37
- 230000007062 hydrolysis Effects 0.000 description 11
- 238000006460 hydrolysis reaction Methods 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000036647 reaction Effects 0.000 description 3
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229940106135 cellulose Drugs 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 230000005865 ionizing radiation Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical class COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- 101001121591 Aplysia californica L-amino-acid oxidase Proteins 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000010006 flight Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010907 stover Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/131,340 US4316747A (en) | 1980-03-18 | 1980-03-18 | Process for the chemical conversion of cellulose waste to glucose |
| US06/131,339 US4316748A (en) | 1980-03-18 | 1980-03-18 | Process for the acid hydrolysis of waste cellulose to glucose |
| US131,339 | 1980-03-18 | ||
| US131,340 | 1980-03-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1190923A true CA1190923A (en) | 1985-07-23 |
Family
ID=26829384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000371826A Expired CA1190923A (en) | 1980-03-18 | 1981-02-26 | Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0037912B1 (enrdf_load_stackoverflow) |
| AU (1) | AU548717B2 (enrdf_load_stackoverflow) |
| BR (1) | BR8101561A (enrdf_load_stackoverflow) |
| CA (1) | CA1190923A (enrdf_load_stackoverflow) |
| DE (1) | DE3171880D1 (enrdf_load_stackoverflow) |
| IN (1) | IN153348B (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009076760A1 (en) * | 2007-12-19 | 2009-06-25 | Fpinnovations | Conversion of knot rejects from chemical pulping |
| WO2010009548A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for treating a cellulosic feedstock |
| WO2010009547A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| US8545633B2 (en) | 2009-08-24 | 2013-10-01 | Abengoa Bioenergy New Technologies, Inc. | Method for producing ethanol and co-products from cellulosic biomass |
| US9127325B2 (en) | 2008-07-24 | 2015-09-08 | Abengoa Bioenergy New Technologies, Llc. | Method and apparatus for treating a cellulosic feedstock |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2525236A1 (fr) * | 1982-04-15 | 1983-10-21 | Creusot Loire | Procede et dispositif d'hydrolyse d'une matiere cellulosique |
| US4728367A (en) * | 1985-01-31 | 1988-03-01 | Wenger Manufacturing, Inc. | Extrusion method and apparatus for acid treatment of cellulosic materials |
| SE501141C2 (sv) * | 1993-04-16 | 1994-11-21 | Regalco Ab | Förfarande för hydrolys av cellulosa- och/eller stärkelsehaltiga material |
| BRPI0613681A2 (pt) | 2005-07-19 | 2010-07-13 | Holm Christensen Biosystemer A | método e aparelho para conversão de material celulósico para etanol |
| US8546560B2 (en) | 2008-07-16 | 2013-10-01 | Renmatix, Inc. | Solvo-thermal hydrolysis of cellulose |
| CN102239184B (zh) | 2008-07-16 | 2014-07-23 | 瑞恩麦特克斯股份有限公司 | 使用一种或多种超临界流体从生物质萃取糠醛和葡萄糖的方法 |
| EP3719145A1 (en) | 2010-01-19 | 2020-10-07 | Renmatix, Inc. | Production of fermentable sugars and lignin from biomass using supercritical fluids |
| EP2643485B1 (de) * | 2010-11-25 | 2014-08-13 | Studiengesellschaft Kohle MbH | Verfahren zur säurekatalysierten depolymerisation von cellulose |
| CN103502383B (zh) | 2011-05-04 | 2016-06-08 | 瑞恩麦特克斯股份有限公司 | 从木质纤维素生物质生产木质素 |
| US8801859B2 (en) | 2011-05-04 | 2014-08-12 | Renmatix, Inc. | Self-cleaning apparatus and method for thick slurry pressure control |
| US8759498B2 (en) | 2011-12-30 | 2014-06-24 | Renmatix, Inc. | Compositions comprising lignin |
| WO2014143753A1 (en) | 2013-03-15 | 2014-09-18 | Sweetwater Energy, Inc. | Carbon purification of concentrated sugar streams derived from pretreated biomass |
| FI3186286T3 (fi) | 2014-09-26 | 2024-07-10 | Renmatix Inc | Selluloosaa sisältävät koostumukset ja niiden valmistusmenetelmät |
| ES2926062T3 (es) | 2014-12-09 | 2022-10-21 | Sweetwater Energy Inc | Pretratamiento rápido |
| WO2018151833A1 (en) | 2017-02-16 | 2018-08-23 | Sweetwater Energy, Inc. | High pressure zone formation for pretreatment |
| CN207828156U (zh) | 2017-12-06 | 2018-09-07 | 易高环保能源研究院有限公司 | 利用木质纤维素类原料连续水解制糖的装置 |
| WO2021133733A1 (en) | 2019-12-22 | 2021-07-01 | Sweetwater Energy, Inc. | Methods of making specialized lignin and lignin products from biomass |
| CN115157452B (zh) * | 2022-09-08 | 2022-11-22 | 山西钢建鼎元混凝土制品有限公司 | 一种用于混凝土浇筑加工的上料装置 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000822B (en) * | 1977-07-11 | 1982-08-11 | Canadian Patents Dev | Method of rendering lignin separable from cellulose and hemicellulose in lignocellulosic material and the product so produced |
-
1981
- 1981-02-26 CA CA000371826A patent/CA1190923A/en not_active Expired
- 1981-03-06 AU AU68126/81A patent/AU548717B2/en not_active Ceased
- 1981-03-16 EP EP19810101951 patent/EP0037912B1/en not_active Expired
- 1981-03-16 DE DE8181101951T patent/DE3171880D1/de not_active Expired
- 1981-03-17 BR BR8101561A patent/BR8101561A/pt unknown
- 1981-03-17 IN IN288/CAL/81A patent/IN153348B/en unknown
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009076760A1 (en) * | 2007-12-19 | 2009-06-25 | Fpinnovations | Conversion of knot rejects from chemical pulping |
| US8283140B2 (en) | 2007-12-19 | 2012-10-09 | Fpinnovations | Conversion of knot rejects from chemical pulping |
| WO2010009548A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for treating a cellulosic feedstock |
| WO2010009547A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| US8449680B2 (en) | 2008-07-24 | 2013-05-28 | Mascoma Canada Inc. | Method and apparatus for treating a cellulosic feedstock |
| US9010522B2 (en) | 2008-07-24 | 2015-04-21 | Abengoa Bioenergy New Technologies, Llc | Method and apparatus for conveying a cellulosic feedstock |
| US9127325B2 (en) | 2008-07-24 | 2015-09-08 | Abengoa Bioenergy New Technologies, Llc. | Method and apparatus for treating a cellulosic feedstock |
| US8545633B2 (en) | 2009-08-24 | 2013-10-01 | Abengoa Bioenergy New Technologies, Inc. | Method for producing ethanol and co-products from cellulosic biomass |
| US9335043B2 (en) | 2009-08-24 | 2016-05-10 | Abengoa Bioenergy New Technologies, Inc. | Method for producing ethanol and co-products from cellulosic biomass |
Also Published As
| Publication number | Publication date |
|---|---|
| BR8101561A (pt) | 1981-09-22 |
| IN153348B (enrdf_load_stackoverflow) | 1984-07-07 |
| DE3171880D1 (en) | 1985-09-26 |
| EP0037912B1 (en) | 1985-08-21 |
| AU548717B2 (en) | 1986-01-02 |
| AU6812681A (en) | 1981-09-24 |
| EP0037912A3 (en) | 1982-04-21 |
| EP0037912A2 (en) | 1981-10-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1190923A (en) | Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose | |
| US4316748A (en) | Process for the acid hydrolysis of waste cellulose to glucose | |
| US4316747A (en) | Process for the chemical conversion of cellulose waste to glucose | |
| US4363671A (en) | Apparatus for chemical conversion of materials | |
| US4368079A (en) | Apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose | |
| US8136747B2 (en) | Apparatus for separation and treatment of solid biomass | |
| US4468256A (en) | Process for the hydrolysis of cellulose from vegetable raw materials to glucose and apparatus for performing the process | |
| US5972118A (en) | Concentrated sulfuric acid hydrolysis of lignocellulosics | |
| RU2540886C2 (ru) | Способ и устройство для подачи материала в реактор | |
| US5454911A (en) | Apparatus for hydrolyzing and drying lignocellulosic material | |
| US5143579A (en) | Treatment of black liquor with a screw extruder evaporator | |
| US4390375A (en) | Process and continuous apparatus for chemical conversion of materials | |
| US4591386A (en) | Continuous apparatus for chemical conversion of materials | |
| US12253176B2 (en) | Pressure valve processing | |
| US20120184721A1 (en) | Method for separating carbohydrate from lignocellulosic solid | |
| WO2013041298A1 (en) | Device for heating a feedstock | |
| US20250327521A1 (en) | Pressure valve assembly | |
| AU712027B2 (en) | Improved concentrated sulfuric acid hydrolysis of lignocellulosics | |
| US9422663B1 (en) | Apparatus and process for treatment of biocomponents | |
| CN116723776A (zh) | 用于挤出机设备的注射器系统 | |
| CN115746342A (zh) | 一种亚临界水协同纳米纤维素解构与原位重构的方法 | |
| CS274522B1 (en) | Method of lignocellulosic material treatment with formation of pentoses,lignite and cellulose mixture | |
| AU9234798A (en) | Improved concentrated sulfuric acid hydrolysis of lignocellulosics | |
| CS246905B1 (cs) | Způsob a zařízení ke zpracování odpadů dřeva a jednoletých rostlin na krmivo | |
| JPH11255546A (ja) | 植物繊維の低糖化処理装置及び該装置を組み込んだ植物繊維含有セメント成形体の製造装置 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |