CA1102777A - Traduction non-disponible - Google Patents
Traduction non-disponibleInfo
- Publication number
- CA1102777A CA1102777A CA297,355A CA297355A CA1102777A CA 1102777 A CA1102777 A CA 1102777A CA 297355 A CA297355 A CA 297355A CA 1102777 A CA1102777 A CA 1102777A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- support
- phosphoric acid
- acid
- hydration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 103
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 26
- 230000036571 hydration Effects 0.000 title claims abstract description 25
- 238000006703 hydration reaction Methods 0.000 title claims abstract description 25
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 19
- 229910052751 metal Inorganic materials 0.000 title description 12
- 239000002184 metal Substances 0.000 title description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 63
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000000463 material Substances 0.000 claims abstract description 42
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 31
- 229910052742 iron Inorganic materials 0.000 claims abstract description 31
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 230000000887 hydrating effect Effects 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 19
- 238000001354 calcination Methods 0.000 claims description 19
- 239000005909 Kieselgur Substances 0.000 claims description 15
- 239000000440 bentonite Substances 0.000 claims description 14
- 229910000278 bentonite Inorganic materials 0.000 claims description 14
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 10
- 239000012766 organic filler Substances 0.000 claims description 10
- 238000005470 impregnation Methods 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 abstract description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 24
- 229960004838 phosphoric acid Drugs 0.000 description 23
- 239000008188 pellet Substances 0.000 description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000002386 leaching Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 238000010306 acid treatment Methods 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910021654 trace metal Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 241000206761 Bacillariophyta Species 0.000 description 1
- 101710200331 Cytochrome b-245 chaperone 1 Proteins 0.000 description 1
- 102100037186 Cytochrome b-245 chaperone 1 Human genes 0.000 description 1
- 101710119396 Cytochrome b-245 chaperone 1 homolog Proteins 0.000 description 1
- 241001505295 Eros Species 0.000 description 1
- ULGZDMOVFRHVEP-RWJQBGPGSA-N Erythromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=O)[C@H](C)C[C@@](C)(O)[C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 ULGZDMOVFRHVEP-RWJQBGPGSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- -1 ethylene, propylene Chemical group 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77466877A | 1977-03-04 | 1977-03-04 | |
| US774,668 | 1977-03-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1102777A true CA1102777A (fr) | 1981-06-09 |
Family
ID=25101901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA297,355A Expired CA1102777A (fr) | 1977-03-04 | 1978-02-21 | Traduction non-disponible |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS53108889A (fr) |
| BE (1) | BE864540R (fr) |
| CA (1) | CA1102777A (fr) |
| DE (1) | DE2809309B2 (fr) |
| ES (1) | ES467522A1 (fr) |
| FR (1) | FR2382423A2 (fr) |
| GB (1) | GB1598150A (fr) |
| IT (1) | IT1094172B (fr) |
| NL (1) | NL7802397A (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2578448B1 (fr) * | 1985-01-31 | 1990-11-16 | Manville Corp | Procede de production de supports de catalyseurs et produits obtenus |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2694048A (en) * | 1950-03-18 | 1954-11-09 | Universal Oil Prod Co | Manufacture of improved solid catalysts |
| DE1156772B (de) * | 1961-02-21 | 1963-11-07 | Bergwerksgesellschaft Hibernia | Verfahren zur Herstellung eines Katalysators fuer die Herstellung von Alkoholen durch katalytische Hydratation von Olefinen |
| GB981237A (en) * | 1961-02-21 | 1965-01-20 | Hibernia Chemie G M B H | Process for the production of a catalyst for the catalytic hydration of olefins intoalcohols |
| GB1075895A (en) * | 1964-06-21 | 1967-07-12 | Nii Sint Spirtov I Orch Produk | Improvements relating to catalysis |
| FR1531086A (fr) * | 1966-07-12 | 1968-06-28 | Scholven Chemie Ag | Procédé de fabrication d'alcools par hydratation catalytique d'oléfines, ainsi que produits conformes à ceux obtenus |
| CA1076095A (fr) * | 1976-09-28 | 1980-04-22 | Charles E. Moyer (Jr.) | Procede et catalyseur pour l'hydratation d'olefines |
| JPS5721250A (en) * | 1980-07-07 | 1982-02-03 | Shiyuukou Seimitsu Kk | Method of presetting tool position in metal machining device and setting jig used therefor |
-
1978
- 1978-02-21 CA CA297,355A patent/CA1102777A/fr not_active Expired
- 1978-03-03 JP JP2371578A patent/JPS53108889A/ja active Pending
- 1978-03-03 ES ES467522A patent/ES467522A1/es not_active Expired
- 1978-03-03 DE DE2809309A patent/DE2809309B2/de not_active Withdrawn
- 1978-03-03 IT IT20876/78A patent/IT1094172B/it active
- 1978-03-03 FR FR7806151A patent/FR2382423A2/fr active Pending
- 1978-03-03 BE BE185651A patent/BE864540R/fr active
- 1978-03-03 NL NL7802397A patent/NL7802397A/xx not_active Application Discontinuation
- 1978-03-03 GB GB8455/78A patent/GB1598150A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2809309A1 (de) | 1978-09-07 |
| NL7802397A (nl) | 1978-09-06 |
| JPS53108889A (en) | 1978-09-22 |
| FR2382423A2 (fr) | 1978-09-29 |
| DE2809309B2 (de) | 1981-05-21 |
| BE864540R (fr) | 1978-09-04 |
| IT1094172B (it) | 1985-07-26 |
| ES467522A1 (es) | 1979-08-01 |
| IT7820876A0 (it) | 1978-03-03 |
| GB1598150A (en) | 1981-09-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |