BR112012021120A2 - processo para a conversão do composto nitro aromático em aminas - Google Patents
processo para a conversão do composto nitro aromático em aminasInfo
- Publication number
- BR112012021120A2 BR112012021120A2 BR112012021120A BR112012021120A BR112012021120A2 BR 112012021120 A2 BR112012021120 A2 BR 112012021120A2 BR 112012021120 A BR112012021120 A BR 112012021120A BR 112012021120 A BR112012021120 A BR 112012021120A BR 112012021120 A2 BR112012021120 A2 BR 112012021120A2
- Authority
- BR
- Brazil
- Prior art keywords
- reactor
- aromatic
- stream
- aromatic nitro
- providing
- Prior art date
Links
- -1 aromatic nitro compound Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 150000001412 amines Chemical class 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 150000004982 aromatic amines Chemical class 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
- C07C209/365—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst by reduction with preservation of halogen-atoms in compounds containing nitro groups and halogen atoms bound to the same carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
processo para a conversão do composto nitro aromático em aminas. um processo para hidrogenar um composto nitro aromático de acordo com a invenção compreende: - prover uma corrente gasosa de hidrogênio e uma corrente de composto nitro aromático líquido; - prover um reator catalítico de leito fixo tendo um lado de fluxo de entrada e um lado de fluxo de saída; - alimentar ao lado de fluxo de entrada, a corrente gasosa de hidrogênio e a corrente de composto nitro aromático líquido; - converter o gás de hidrogênio e o composto nitro aromático em uma amina aromática, por esse meio provendo um efluente de reator compreendendo a amina aromática e água; evacuar o efluente de reator do reator no lado de fluxo de saída do reator; em que um solvente inerte ou água são alimentados ao lado de fluxo de entrada do reator em que uma relação molar de moles de solventes inerte ou água para moles de hidrogênio seja de mais do que 1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2010/053529 WO2011113491A1 (en) | 2010-03-18 | 2010-03-18 | Process for the conversion of aromatic nitro compound into amines |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112012021120A2 true BR112012021120A2 (pt) | 2016-05-17 |
Family
ID=43466561
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012021120A BR112012021120A2 (pt) | 2010-03-18 | 2010-03-18 | processo para a conversão do composto nitro aromático em aminas |
Country Status (13)
Country | Link |
---|---|
US (1) | US9533939B2 (pt) |
EP (1) | EP2547647B1 (pt) |
JP (1) | JP5711768B2 (pt) |
KR (1) | KR101797255B1 (pt) |
CN (1) | CN102811996B (pt) |
AU (1) | AU2010348909A1 (pt) |
BR (1) | BR112012021120A2 (pt) |
CA (1) | CA2789032A1 (pt) |
ES (1) | ES2444967T3 (pt) |
MX (1) | MX2012010496A (pt) |
PT (1) | PT2547647E (pt) |
RU (1) | RU2518110C1 (pt) |
WO (1) | WO2011113491A1 (pt) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2757088B1 (de) * | 2013-01-22 | 2016-08-03 | Covestro Deutschland AG | Verfahren zur Herstellung von aromatischen Aminen |
EP2968624B1 (en) * | 2013-03-14 | 2017-11-01 | Teleflex Medical Incorporated | Optical fiber based antimicrobial ultraviolet radiation system |
WO2018187812A1 (en) * | 2017-04-07 | 2018-10-11 | Arizona Board Of Regents On Behalf Of The University Of Arizona | High-rate treatment of 3-nitro-1,2,4-triazol-5-one (nto) and other munitions compounds |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB596287A (en) * | 1944-01-28 | 1948-01-01 | Standard Oil Dev Co | Improvements in the production of aromatic amines |
GB508024A (en) | 1936-12-23 | 1939-06-23 | Chem Ind Basel | Production and purification of compounds of the suprarenal cortical hormone series |
US2458214A (en) * | 1944-06-26 | 1949-01-04 | Shell Dev | Hydrogenation of nitro compounds |
BE754868A (fr) | 1969-08-16 | 1971-02-15 | Basf Ag | Procede pour la mise en oeuvre de reactions exothermiques entreun gaz et un liquide |
DE4428017A1 (de) * | 1994-08-08 | 1996-02-15 | Bayer Ag | Verfahren zur Herstellung von aromatischen Aminen |
DE19528781A1 (de) * | 1995-08-04 | 1997-02-06 | Bayer Ag | Verfahren zur Herstellung von Toluylendiisocyanat, spezielle Gemische aus Toluylendiamin und Wasser und deren Verwendung zur Herstellung von Toluylendiisocyanat |
FR2741877B1 (fr) | 1995-12-01 | 1998-02-13 | Rhone Poulenc Chimie | Procede d'hydrogenation de composes nitres aromatiques |
US6479704B1 (en) * | 2001-04-20 | 2002-11-12 | Air Products And Chemicals, Inc. | Hydrogenation with monolith reactor under conditions of immiscible liquid phases |
DE102006035203A1 (de) | 2006-07-29 | 2008-01-31 | Bayer Materialscience Ag | Verfahren zur Herstellung von aromatischen Aminen |
-
2010
- 2010-03-18 ES ES10709724.8T patent/ES2444967T3/es active Active
- 2010-03-18 EP EP10709724.8A patent/EP2547647B1/en not_active Not-in-force
- 2010-03-18 JP JP2012557419A patent/JP5711768B2/ja not_active Expired - Fee Related
- 2010-03-18 RU RU2012144330/04A patent/RU2518110C1/ru not_active IP Right Cessation
- 2010-03-18 CA CA2789032A patent/CA2789032A1/en not_active Abandoned
- 2010-03-18 KR KR1020127027079A patent/KR101797255B1/ko active IP Right Grant
- 2010-03-18 BR BR112012021120A patent/BR112012021120A2/pt not_active IP Right Cessation
- 2010-03-18 PT PT107097248T patent/PT2547647E/pt unknown
- 2010-03-18 WO PCT/EP2010/053529 patent/WO2011113491A1/en active Application Filing
- 2010-03-18 CN CN201080065496.0A patent/CN102811996B/zh not_active Expired - Fee Related
- 2010-03-18 MX MX2012010496A patent/MX2012010496A/es active IP Right Grant
- 2010-03-18 AU AU2010348909A patent/AU2010348909A1/en not_active Abandoned
- 2010-03-18 US US13/583,941 patent/US9533939B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
RU2012144330A (ru) | 2014-04-27 |
RU2518110C1 (ru) | 2014-06-10 |
EP2547647B1 (en) | 2014-01-08 |
AU2010348909A1 (en) | 2012-08-23 |
US20130006018A1 (en) | 2013-01-03 |
KR101797255B1 (ko) | 2017-11-13 |
JP2013522247A (ja) | 2013-06-13 |
ES2444967T3 (es) | 2014-02-27 |
KR20130059332A (ko) | 2013-06-05 |
MX2012010496A (es) | 2012-10-09 |
PT2547647E (pt) | 2014-01-16 |
CN102811996B (zh) | 2014-10-01 |
JP5711768B2 (ja) | 2015-05-07 |
CA2789032A1 (en) | 2011-09-22 |
WO2011113491A1 (en) | 2011-09-22 |
US9533939B2 (en) | 2017-01-03 |
CN102811996A (zh) | 2012-12-05 |
EP2547647A1 (en) | 2013-01-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AR066572A1 (es) | Un sistema reactor y un proceso para la reaccion de una fuente | |
BR112012014084A2 (pt) | processo de conversão de hidrocarboneto em fase líquida. | |
BRPI0703617A2 (pt) | reator para a preparaÇço de cianeto de hidrogÊnio pelo processo de andrussow | |
BR112012022818A2 (pt) | remoção otimizada de mutrientes de águas servidas | |
AR090777A1 (es) | Un proceso para la aromatizacion de una corriente de gas que contiene metano | |
BRPI0812874A2 (pt) | " processos para introdução de uma parte retirada de pelo menos uma carga de produção de catalisadores e para preparação de catalisadores anulares revestidos, uso de catalisadores anulares revestidos, e, embalagem ". | |
MX2012007043A (es) | Proceso para el arranque de epoxidacion. | |
BR112012014485A2 (pt) | processo contínuo para a carbonilação de etileno em uma fase líquida | |
EP2585195A4 (en) | SMOKE GAS CLEANING AND RECYCLING SYSTEM AND METHOD THEREFOR | |
AR066574A1 (es) | Un sistema reactor, un proceso de produccion de oxido de olefina 1,2-diol 1,2-diol eter , 1,2-carbonato o alcanolamina | |
RU2016105803A (ru) | Способ получения пропиленоксида | |
BR112012012033A2 (pt) | processo para preparar ácido fórmico | |
FR2971248B1 (fr) | Preparation de diamine via la preparation d'aminonitrile | |
BR112013022589A2 (pt) | processo para reciclar solvente e sistema para reciclar solvente | |
BR112012021120A2 (pt) | processo para a conversão do composto nitro aromático em aminas | |
BR112018012143A2 (pt) | ?processo contínuo para preparação de óxido de propileno, sistema catalítico, e, uso de um sistema catalítico? | |
BRPI0607322A2 (pt) | método e aparelho para adição de soluções aquosas a processos de altas temperaturas | |
BR112014007126A2 (pt) | processo para fornecer hidrogênio para uma reação de conversão de gás de síntese | |
EA201170726A1 (ru) | Способ получения этилбензола | |
BR112012033462A2 (pt) | processo para preparar ácido fórmico | |
IN2012DN01937A (pt) | ||
RU2015152849A (ru) | Применение нержавеющей стали, выплавленной дуплекс-процессом, при отпарке аммиаком на установках для синтеза мочевины | |
WO2010042315A3 (en) | Process for producing cumene | |
MX346341B (es) | Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones. | |
GB201207716D0 (en) | Catalyst treatment process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 7A ANUIDADE. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |