AU8189798A - Method for recycling aromatic polycarbonates - Google Patents
Method for recycling aromatic polycarbonates Download PDFInfo
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- AU8189798A AU8189798A AU81897/98A AU8189798A AU8189798A AU 8189798 A AU8189798 A AU 8189798A AU 81897/98 A AU81897/98 A AU 81897/98A AU 8189798 A AU8189798 A AU 8189798A AU 8189798 A AU8189798 A AU 8189798A
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- AU
- Australia
- Prior art keywords
- polycarbonate
- solvent
- solution
- solid
- amorphous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/40—Post-polymerisation treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/04—Aromatic polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Polyesters Or Polycarbonates (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing Of Solid Wastes (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
r ~rr r,,r%-~~lcrum? Our Ref: 681630 P/00/011 Regulation 3:2
AUSTRALIA
Patents Act 1990
ORIGINAL
COMPLETE SPECIFICATION STANDARD PATENT i o r r e r r ii j..
Applicant(s): Address for Service: Invention Title: General Electric Company One River Road Schenectady New York 12345 UNITED STATES OF AMERICA DAVIES COLLISON CAVE Patent Trade Mark Attorneys Level 10, 10 Barrack Street SYDNEY NSW 2000 Method for recycling aromatic polycarbonates i_ ii I- 1 1: The following statement is a full description of this invention, including the best method of performing it known to me:- 5020 4.
I; '\a "'4w.
RD-25648 -1- METHOD FOR RECYCLING AROMATIC
POLYCARBONATES
SBACKGROUND OF THE INVENTION This invention relates to the recycling and reuse of aromatic polycarbonates.
Recycling of plastics is of increasing interest with the heightened environmental concerns currently felt. In addition, there is potential for recycle being more economical than disposal of used polymer and synthesis of new polymer to replace it.
10 Aromatic polycarbonates are in use in a wide variety of high volume areas. Among these are in the fabrication of transparent sheeting which may be used as a substitute for glass, and in the fabrication of optical disks used to transmit data.
Various methods for recycle of polycarbonate have been 15 described. However, most if not all of them involve chemical reactions which degrade the polycarbonate, optimally to monomeric bisphenol which can be purified and reconverted to polycarbonate.
j It would be more convenient to recycle the polycarbonate by simple purification means, which have the potential for being much dI 20 cheaper than conversion to monomer and repolymerization. Moreover, since some molecular weight degradation can take place during use, it would be desirable to increase the molecular weight during recycle. Such recycle operations would be useful for both end use polycarbonate and polycarbonate recovered as drips from extruders and the like.
SUMMARY OF THE INVENTION I The present invention provides a recycle method which may be used in connection with the above-described applications. It provides RD-25648 -2an easy method for recycle without substantial degradation, combined where necessary with increase in molecular weight.
The invention is a method for recycling an aromatic polycarbonate which comprises: dissolving a solid, amorphous aromatic precursor polycarbonate in a chlorinated hydrocarbon as solvent to form an amorphous polycarbonate solution, removing any insoluble materials from said amorphous polycarbonate solution, and S, 10 precipitating solid purified polycarbonate from said amorphous polycarbonate solution by addition of an organic non-solvent therefor.
DETAILED DESCRIPTION; PREFERRED EMBODIMENTS Precursor polycarbonates which may be recycled by the method of this invention typically comprise structural units of the formula: -0-R-o-Cwherein at least about 60% of the total number of R groups are aromatic organic radicals and the balance thereof are aliphatic, alicyclic, or aromatic radicals. Preferably, each R is an aromatic organic radical and more preferably a radical of the formula: (l1) -A 2 i wherein each A' and A 2 is a monocyclic divalent aryl radical and Y is a bridging radical in which one or two carbon atoms separate A 1 and A 2 S. Such radicals are derived from dihydroxyaromatic compounds of the formulas HO-R-OH and HO-A'-Y-A 2 -OH respectively. For example, A 1 and A 2 generally represent unsubstituted phenylene, especially RD-25648
I
p-phenylene which is preferred, or substituted derivatives thereof. The bridging radical Y is most often a hydrocarbon group and particularly a saturated group such as methylene, cyclohexylidene, or isopropylidene which is preferred. Thus, the most preferred polycarbonates are those derived entirely or in part from 2,2-bis(4-hydroxyphenyl)propane, also known as "bisphenol A".
The precursor polycarbonate may be a homopolycarbonate or a copolycarbonate. For the purpose of the invention, copolycarbonates include copolyestercarbonates, an art-recognized class of copolymers which contain both carbonate units and ester units derived, for example, from isophthalic or terephthalic acid.
The precursor polycarbonate may be in the form of an article or plurality of articles, such as optical disks or sections of polycarbonate sheeting. It may also be a waste material such as extruder drips or 15 wastes in solid form. The only requirements are that it be solid and Samorphous and have a molecular weight typical of a polymer. Illustrative weight average molecular weights (as determined by gel permeation chromatography) are in the range of about 5,000-300,000.
In step A of the method of this invention, the precursor polycarbonate is dissolved in a chlorinated hydrocarbon as solvent.
Illustrative chlorinated hydrocarbons are methylene chloride, chloroform, 1,2-dichloroethane, chlorobenzene and o-dichlorobenzene. The chloroaliphatic hydrocarbons are preferred, with methylene chloride and 1,2-dichloroethane being most preferred.
Dissolution of the precursor polycarbonate in the solvent may take place at any temperature. Typical temperatures are from about 0 C to the boiling point of the solvent, with about 20-100°C generally being preferred. So long as an amount of solvent effective to dissolve the polycarbonate is employed, its proportion is not critical.
Dissolution of the precursor polycarbonate generally leaves behind various insoluble materials, as illustrated by metallic coatings "iii' RD-25648 -4when the precursor polycarbonate is from optical disks, for example. In step B, said insoluble materials are removed from the polycarbonate solution. This may be achieved by such conventional operations as decantation, filtration and centrifugation.
The precursor polycarbonate is frequently associated with colored impurities, which may appear in the polycarbonate itself or in the solution thereof in the chlorinated solvent. Various embodiments of the invention, therefore, include a step of removing color from the amorphous polycarbonate solution following step B. One method for color discharge 10 is treatment while in solution with a mineral acid, preferably hydrochloric acid, said acid typically being in solution in an alkanol such as methanol.
Another is contact of said solution with a solid that absorbs color bodies, such as activated charcoal or a crosslinked resin, which may be neutral or q. may be an ion exchange resin. Another method of color discharge is washing of the resin, after precipitation as described hereinafter, with non-solvent in an amount sufficient to dissolve color bodies.
Many commercially employed polycarbonates are endcapped with a monohydroxyaromatic compound such as phenol or pcumylphenol. Such an endcapping agent, when present, can inhibit solid state polymerization. Therefore, it is frequently preferred to add during the dissolution step at least one dihydroxyaromatic or dihydroxyaliphatic compound as a modifying reagent to produce hydroxy end groups.
Suitable compounds include resorcinol, hydroquinone, catechol, bisphenols, ethylene glycol, propylene glycol, pentaerythritol, glycerol, glyceryl monopalmitate and glyceryl monostearate, with catechol and bisphenol A often being preferred.
The proportion of modifying reagent is generally a proportion at least theoretically effective to convert the amorphous polycarbonate in the solution to a material having about 20-80% (by number), preferably 40-60%, hydroxy end groups. A suitable proportion may be determined by simple experimentation.
l| i 3 RD-25648 E~as 1T14;-n-C1~~-Zll
IC~-TC~
F41 In step C, purified polycarbonate is precipitated from the amorphous polycarbonate solution by addition of an organic non-solvent therefor. Suitable non-solvents include aliphatic hydrocarbons such as nhexane, n-heptane and petroleum ether; aromatic hydrocarbons such as toluene and xylene; hydroxyaliphatic compounds such as methanol, ethanol, ethylene glycol and diethylene glycol; aliphatic kelones such as acetone and methyl ethyl ketone; and carboxylic acid esters such as ethyl acetate and n-butyl acetate. Upon addition of the non-solvent to the polycarbonate solution, the polycarbonate precipitates and may be separated by filtration or one of the other separation options described hereinabove. When removal of color bodies by washing is to be conducted after precipitation, one of the same non-solvents suggested for use in the precipitation step may be employed.
It is often preferred, particularly when solid state polyme.ization is subsequently to be employed, to employ a non-solvent which produces a crystalline polycarbonate. The presence of crystallinity may be detected by treatment under conditions which afford a polycarbonate film; a cloudy film indicates some degree of crystallinity in the polycarbonate. Among the non-solvents which produce crystallinity in 20 combination with 1,2-dichloroethane, for example, are alkyl carboxylate esters such as ethyl acetate.
ft 1 1 When a purified polycarbonate having an enhanced crystallinity is desired, a crystallinity in the range of about 10-30% and especially about 10-20% is generally preferred. Crystallinity values higher than about 30% are generally not preferred when solid state polymerization is to be performed, since polymerization may be very slow at such high crystallinity values. Crystallinity proportions may be determined by powder X-ray diffraction, comparing a completely amorphous polymer and a crystallized polymer as described, for example, in U.S. Patent 4,948,871 with reference to drawings not forming part of the patent but present in its file. The disclosures of said patent and said drawings are incorporated by reference herein.
N .s K RD-25648 ,I-n -~-V-~IIDILL~- PII~IL-CF~C CV rr~ZIC The proportion of crystallinity in the purified polycarbonate will depend to some extent on the identities of the solvent and non-solvent employed. More particularly, a specific group of non-solvents may impart crystalinity when employed with a specific solvent but not with another solvent. When 1,2-dichloroethane is employed as a solvent, for example, ethyl acetate is particularly effective as a crystallinity enhancing non-solvent. The identities of suitable non-solvents for this purpose and for use with any other suitable solvent can be determined by simple experimentation.
The purified polycarbonate obtained by the method of this invention most often has an intrinsic viscosity in the range of about 0.35- 0.45 dl/g, as determined in chloroform at 25°C. If a product with higher intrinsic viscosity is desired, the purified polycarbonate may be subjected to solid state polymerization.
a 1 Solid state polymerization may be effected at a temperature between the glass transition temperature and the melting temperature of the crystalline purified polycarbonate, most often about 10-50°C below its melting temperature. In general, temperatures in the range of about 150- 2700 and especially about 180-250oC are suitable. As disclosed in US Patents 4,948,971, 5,204,377 and 5,266,659 and in copending, commonly owned application Serial No. 08/787,740, the disclosures of which are incorporated by reference herein, the solid state polymerization step may be achieved in the absence or presence of catalysts. Suitable catalysts include basic salts, transition metal oxides and alkoxides, quaternary ammonium bioxyanion salts and tetraalkylammonium and tetraalkylphosphonium carboxylates. Catalysts proportions are usually about 10-200 ppm based on purified polycarbonate.
Solid state polymerization may be conducted in a mixer capable of producing intimate gas-solid contact, such as a fixed bed, fluidized bed or paddle mixer, in contact with an inert gas such as nitrogen or argon which serves as the fluidizing gas if a fluidized bed is employed. Said inert gas may serve one or both of the purposes of r'j ~di i i RD-25648 -7fluidizing the mixture and volatilizing and removing volatile by-products, including water and any volatile carbonate formed. Programmed heating may be advantageously employed. As an alternative to conditions of intimate gas-solid contact, the polymerization may be conducted at reduced pressure, typically less than about 100 torr, preferably with Sefficient mixing.
The method of this invention is illustrated by the following examples. Intrinsic viscosities were determined in methylene chloride at 0
C.
10 EXAMPLE 1 A 100-g sample of bisphenol A polycarbonate recovered S- from extruder drips was dissolved in 700 ml of 1,2-dichloroethane at with vigorous stirring. The solution was centrifuged and the solid residue was removed and discarded. Ethyl acetate was added to the S 15 polycarbonate solution to precipitate the polycarbonate as a crystalline olid, which was separated, washed with ethyl acetate until colorless and dried in vacuum at 80 0 C. The product had an intrinsic viscosity of 0.43 dl g, a glass transition temperature of 143oC, a melting temperature of 226 0 C and a crystallinity of EXAMPLE 2 A 10-g sample of polycarbonate-containing regrind material from optical disks was dissolved in 100 ml of 1,2-dichloroethane at 80 0
C,
with vigorous stirring. The solution was filtered and purified polycarbonate was precipitated from the filtrate by the addition of methanol. The precipitated polycarbonate was separated by filtration, washed twice with methanol and vacuum dried at 80 0 C. The recycled polycarbonate thus obtained had an intrinsic viscosity of 0.36 dl/g, a glass transition temperature of 1430C, a melting temperature of 223 0 C and a crystallinity of 24%.
i i
IT
RD-25648 -8- Example 3 A 10-g sample of a recovered polycarbonate similar to the product of Example 1 is dissolved in 100 ml of ethyl acetate and 100 mg of catechol and 1 mg of tetramethylammonium maleate are added. The mixture is heated under reflux for 2 hours, after which the ethyl acetate is removed by distillation and the material is dried at 80 0 C. The resulting crystallized polycarbonate is heated in a fluidized bed reactor in a nitrogen flow of 3 !min. at 180 0 C for 30 minutes, 210°C for 2 hours and 230°C for 4 hours. The resulting polycarbonate has an intrinsic viscosity of 0.76 dl/g, a glass transition temperature of 156 0 C, a melting temperature of 264°C and a crystallinity of 34%.
Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
~r r i OT-
Claims (17)
1. A method for recycling an aromatic polycarbonate which comprises: dissolving a solid, amorphous aromatic precursor polycarbonate in a chlorinated hydrocarbon as solvent to form an amorphous polycarbonate solution, removing any insoluble materials from said amorphous polycarbonate solution, and precipitating solid purified polycarbonate from said amorphous polycarbonate solution by addition of an organic non-solvent therefor.
2. A method according to claim 1 wherein the precursor polycarbonate is a homopolycarbonate o ~r r 1
3. A method according to claim 2 wherein the 15 homopolycarbonate is a bisphenol A polycarbonate.
4. A method according to claim 1 wherein the precursor polycarbonate is a copolycarbonate. A method according to claim 1 wherein the precursor polycarbonate is a copolyestercarbonate.
6. A method according to claim 1 wherein step A is performed at a temperature in the range of about 20-100 C.
7. A method according to claim 6 wherein the chlorinated hydrocarbon is methylene chloride or 1,2-dichloroethane.
8. A method according to claim 6 wherein step B comprises decantation, filtration or centrifugation. ;1; P 3Dj~I:;~q I' CPi9 i .i Y: r I r I~l: [rr~ ~;P"Mq RD-25648
9. A method according to claim 6 which further comprises the step of removing color from said amorphous polycarbonate solution following step B. A method according to claim 9 wherein color is removed by treatment with a mineral acid while in solution. S11. A method according to claim 10 wherein the mineral acid is hydrochloric acid in solution in an alkanol.
12. A method according to claim 9 wherein color is removed by contact with a solid that absorbs color bodies. 10
13. A method according to claim 12 wherein said solid is activated charcoal or a crosslinked resin.
14. A method according to claim 5 wherein step A is performed in the presence of at least one dihydroxyaromatic or dihydroxyaliphatic compound as a modifying reagent.
15. A method according to claim 14 wherein the modifying reagent is a dihydroxyaromatic compound.
16. A method according to claim 15 wherein the modifying reagent is catechol or bisphenol A.
17. A method according to claim 6 wherein the non-solvent employed in step C is an aliphatic hydrocarbon, aromatic hydrocarbon hydroxyaliphatic compound, aliphatic ketone or carboxylic acid ester.
18. A method according to claim 17 wherein the non-solvent is an organic compound which, when employed in combination with said 2 olvent, produces a purified polycarbonate having a crystallinity of at least about 10%.
19. A method according to claim 18 wherein the non-solvent is an alkyl carboxylate ester. i lS i. P-:WPDOCSPAT1CLAIMS6163D.WFD-26/I&S -11- A method according to claim 18 further comprising the step of polymerizing said solid purified polycarbonate by solid state polymerization. rl~ r; or I ro r- r r r~ o I or r 1
21. A method for recycling an aromatic polycarbonate substantially as hereinbefore described with reference to the Examples. DATED this 26th day of August 1998 GENERAL ELECTRIC COMPANY 0 By Its Patent Attorneys DAVIES COLLISON CAVE
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN1619/97 | 1997-09-02 | ||
IN1619CA1997 | 1997-09-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
AU8189798A true AU8189798A (en) | 1999-03-18 |
Family
ID=11086794
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU81897/98A Abandoned AU8189798A (en) | 1997-09-02 | 1998-08-26 | Method for recycling aromatic polycarbonates |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPH11152371A (en) |
KR (1) | KR19990029426A (en) |
AU (1) | AU8189798A (en) |
BR (1) | BR9802294A (en) |
SG (1) | SG81227A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114644776A (en) * | 2022-04-29 | 2022-06-21 | 聊城鲁西聚碳酸酯有限公司 | System and method for recycling polycarbonate powder |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040016514A (en) * | 2002-08-17 | 2004-02-25 | 에쓰대시오일 주식회사 | Pretreatment methods for polycarbonate solid state polymerization |
JPWO2021132419A1 (en) | 2019-12-27 | 2021-07-01 | ||
WO2024111541A1 (en) * | 2022-11-25 | 2024-05-30 | 三菱瓦斯化学株式会社 | Method for producing reclaimed polycarbonate resin |
WO2024143359A1 (en) * | 2022-12-26 | 2024-07-04 | 三菱ケミカル株式会社 | Method for producing reclaimed polycarbonate resin |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1173250B (en) * | 1958-06-12 | 1964-07-02 | Pittsburgh Plate Glass Co | Process for the production of pure, grainy polycarbonates with a high bulk weight |
DE4009308A1 (en) * | 1990-03-23 | 1991-09-26 | Bayer Ag | Recycling scrap polymers - by filtering soln. of the polymer through sand to remove insol. impurities |
DE4009496A1 (en) * | 1990-03-24 | 1991-09-26 | Goeppinger Kaliko Gmbh | Recovering pure-grade plastics from impure scrap - by dissolving in a suitable solvent and reprecipitating with a non-solvent |
DE4112786A1 (en) * | 1991-04-19 | 1992-10-22 | Bayer Ag | METHOD FOR SEPARATING INORGANIC PIGMENTS FROM THERMOPLASTIC POLYCONDENSATES |
US5717056A (en) * | 1996-05-24 | 1998-02-10 | General Electric Company | Method for preparing polycarbonate by solid state polymerization |
-
1998
- 1998-04-13 SG SG9800724A patent/SG81227A1/en unknown
- 1998-06-26 BR BR9802294A patent/BR9802294A/en not_active Application Discontinuation
- 1998-08-26 AU AU81897/98A patent/AU8189798A/en not_active Abandoned
- 1998-09-01 KR KR1019980035899A patent/KR19990029426A/en not_active Application Discontinuation
- 1998-09-01 JP JP24752798A patent/JPH11152371A/en not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114644776A (en) * | 2022-04-29 | 2022-06-21 | 聊城鲁西聚碳酸酯有限公司 | System and method for recycling polycarbonate powder |
CN114644776B (en) * | 2022-04-29 | 2023-09-01 | 聊城鲁西聚碳酸酯有限公司 | System and method for recycling polycarbonate powder |
Also Published As
Publication number | Publication date |
---|---|
JPH11152371A (en) | 1999-06-08 |
BR9802294A (en) | 1999-12-14 |
KR19990029426A (en) | 1999-04-26 |
SG81227A1 (en) | 2001-06-19 |
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MK1 | Application lapsed section 142(2)(a) - no request for examination in relevant period |