AU701741B1 - Methods and apparatus for making glass - Google Patents

Description

METHODS AND APPARATUS FOR MAKING GLASS The present invention relates to methods and apparatus for making glass, in particular, curved and heat-toughened (tempered) glass.

The term "shaped" is intended to include curving, bending or any alteration of a planar to non-planar configuration.

Tempered bent, curved or shaped glass has many uses and the demand for this material is increasing. Some examples of uses are: architectural, vehicles, ships and boats, furniture, retail and wholesale display, home appliances, and fencing.

In order to heat-temper glass, the glass is heated in a gas furnace and then cooled rapidly. The types of furnaces, methods of heat application and methods to cool the glass are many and varied.

ooA known method for producing tempered curved glass comprises the 2 following steps.

i) a glass sheet is advanced on ceramic rollers through a gas furnace with heating elements arranged above and below the rollers; ii) the heated glass is transported to a bending device which includes a plurality of adjustable rollers arranged to cooperate above and below the heated glass to bend the heated glass to the desired radius; S. iii) the bent glass is then cooled rapidly.

0. 0: t A considerable problem with the above method is that small surface imperfections on the bending rollers are transferred onto the surface of the glass. Thus, the curved glass produced has an unsatisfactory optical quality.

In addition, the above method is problematical because the glass has to be heated far in excess of its melting point, to around 660-670'C, so that it reaches the bending device at a suitable temperature. At such temperatures the glass is very molten and is readily distorted. To maintain a suitable glass temperature for bending the glass the bending device is provided with a series of gas flame heads which heat the glass until it has been curved by the rollers. Thereafter, the gas flame heads are closed and cool air is blown onto the glass via a plurality of air nozzles. It will be appreciated that the above method is complicated and extremely inefficient in terms of energy usage.

It is also known to use a rigid mould for bending the glass. As the glass is o heated it bends or sags under gravity, or a vacuum, to conform to the radius of the mould. However, a problem with known moulds is that the 20 area of the mould in contact with the glass causes surface marking of the glass and, more importantly, differences in temperature between the glass and the mould material can give rise to cracks or "chill vents" in the glass produced which can cause the glass to shatter after cooling. Such Sshattering can occur weeks after manufacture and is therefore potentially S hazardous. To address the problem of chill-venting it is known to direct hot air around the mould beneath the glass. However, chill-venting and surface marking of curved tempered glass produced by known methods and apparatus are still major problems.

The present invention seeks to avoid or mitigate the problems of known methods and apparatus for producing shaped and tempered glass.

According to a first aspect of the invention there is provided apparatus for producing shaped tempered glass comprising: a mould constructed from a thermally inert material and including a frame arranged to support outer portions of a glass sheet to be shaped and tempered; wherein a metallic heat transfer material is sandwiched between the frame and an anti-marking material to prevent the frame from contacting the glass directly in use.

Preferably, the frame comprises two curved side members arranged substantially parallel to one another.

Alternatively, the heat transfer material and an anti-marking material are supported on an adjustable structure mounted to the frame.

S The metallic heat transfer material prevents or reduces the development of 20 a temperature difference between the frame of the mould and the supported glass, thereby preventing or substantially reducing the likelihood of chill-venting when the glass is cooled after heating and shaping.

a. *.Q The presence of an anti-marking material between the glass and the metallic heat transfer material reduces the likelihood of marking of the *surface of the glass during the shaping procedure.

Preferably, the frame supports the glass sheet by means of a plurality of spaced apart support heads. This arrangement is preferred because it minimizes the area of contact between the glass sheet and the frame of the mould.

The mould is made from a thermally inert material, that is, a material which undergoes substantially no expansion or contraction at the temperatures involved in the glass shaping method. For example, a preferred material would withstand repeated exposure to high temperature (eg. up to 700-1000°C).

Preferably, the mould material can be machined easily to make a mould of any desired shape. Preferred mould materials include those comprising calcium silicate and materials produced by Cape Industrial Products Limited, Glasgow, Scotland under the trade names Monolux 500, Monalite Ml and G3, Monalite 1000, Duratec 750 and Duractec 1000 and 'combinations of these materials.

Preferably, the metallic heat transfer material is constructed from metals 20 that are able to withstand the tempering process, for example, by having a melting point above 550° centigrade such as mild steel, tin, stainless steel, iron, chrome and vanadium, being especially preferred.

Conveniently, the metallic heat transfer material has a thickness of approximately Preferably a ceramic or stainless steel material having a relatively smooth flat surface, such as stainless steel woven cloth is used as the anti-marking material.

Preferably, the anti-marking material is ceramic paper. A preferred ceramic paper for use in the invention comprises 85-97% by weight of synthetic ceramic fibre and 3 to 15% by weight of an organic binder.

Such material is commercially available from Warren Bestobell of Chesterfield, England under the product name Ceramic Paper 1260 C- 10901A 10901B KOTHERM 1260°C.

The anti-marking material can be any material which conducts heat and prevents or substantially reduces marking of the surface of the glass at the temperatures involved in the glass shaping process. In this context, whether or not the material substantially reduces marking can be determined by comparing the degree of marking produced on the surface of the glass in the presence or absence of the material when using the apparatus of the invention to make shaped tempered glass.

Conveniently, the thickness of the anti-marking material is from approximately 0.1mm to approximately 3mm, preferably from lmm to 3mm.

Preferably the anti-marking material is mounted on the heat transfer material by means of an adhesive. When the anti-marking material is ceramic paper, it is preferred that the adhesive is a ceramic paste such as Carborundum Fiberfrax (Carborundum Co Ltd, St Helens, England).

Alternatively, the anti-marking material can be freely mounted or fixed mechanically into place.

Preferably, the thickness of the glass sheet to be curved and tempered is from approximately 3mm to approximately 25mm, more preferably from 6mm to Preferably, the surface area of the support heads is as small as possible to reduce the contact area with the glass to a minimum. Preferably the 2 2 surface area of the support heads is from 6mm to 18mm 2 and more preferably 6mm 2 to 12mm 2 The minimum surface area will vary depending on the thickness of the glass sheet to be bent. For example, when the glass sheet thickness is approximately 6mm, it is preferred that the surface area of each support head is less than 10mm 2 If the anti-marking material is in the form of a strip or band, it is preferable for the width of the strip to be 15mm or less. For example, when using 6mm glass, it is preferred that the strip of anti-marking material is 4mm or less. Of course, a skilled worker will be able to determine the minimum support head surface area or anti-marking material strip width required for a given thickness of glass sheet using routine tests involving nothing more than trial and error.

To date, the apparatus of the invention has been used successfully to shape and temper every type of glass which has been tested, including glass formed from sodalime silica.

S

In use, the apparatus of the invention is provided in combination with heating and cooling means, which may be conventional.

555555 S A glass sheet is transported to a shaping station comprising apparatus according to the first aspect of the invention. The glass is supported on the support frame and heated rapidly using a suitable heater, such as Infra- Red (IR) heating elements emitting medium wave IR radiation, whereby the glass sheet sags under gravity to conform to the shape of the mould.

Typically, the glass as heated to more than 600'C, preferably approximately 625 C, until it emits infra red radiation.

The shaped glass and mould are then subject to rapid cooling so as to cause the glass to become tempered or heat strengthened as required.

This can be carried out in the furnace chamber or by moving the glass to a cooling zone separate from the furnace chamber.

Typically this is carried out by rapidly cooling the glass by application of volumes of moving air to both surfaces of the shaped glass by air blowers arranged so as to effect even cooling to both surfaces of the glass. The air is at ambient temperatures, though "chilled" air at lower temperatures could be used if desired.

The air application method is essentially the same as known methods for tempering (toughening) of flat or shaped glass.

The tempered shaped glass sheet obtained is of an excellent quality, being too*substantially free of surface marks or blemishes and having a uniform *stress distribution pattern which is vital if spontaneous breakage is not to occur.

7 In a second aspect the invention provides a method of making shaped and tempered glass comprising: i) providing a mould in accordance with the first aspect of the invention; ii) supporting a sheet of glass to be shaped on the frame of the mould; iii) heating the glass so that it sags and conforms to the shape of the frame; iv) subsequently cooling the glass to obtain a shaped tempered sheet of glass.

Preferably the glass is heated rapidly to temperatures exceeding 6000C, preferably 625 C, by means of one or more IR heating elements.

It is preferred that the heating means comprises an IR oven having a S' curved roof and floor so that infra-red heat can be focused into the centre •of the oven.

20 Preferably a plurality of IR heating elements are arranged on either side of the sheet of glass to be shaped and tempered. Such an arrangement improves the uniformity of heating. Advantageously, the heating elements are independently controllable so that the heating of different areas of the glass sheet can be controlled precisely.

Preferably, the heating means is arranged to heat the outer portions of the glass sheet before or more than the central portion. Such heating improves the uniformity of bending of the outer portions of the glass sheet.

Preferably, cooling of the shaped glass reduces the temperature of the glass to 400'C or less as quickly as possible without breaking the glass.

The air blowing and therefore the glass cooling time clearly depends on the thickness of the curved heated glass sheet.

It is preferred that cooling of the glass is achieved using a air blower device comprising an air fan connected to a plurality of air nozzles or air holes for directing the air onto the bent glass. Advantageously the nozzles or air holes are arranged above and below the glass sheet to ensure uniform application of air to the glass. Conveniently, the nozzles or air holes are mounted on a plurality of blast heads which can be moved relative to the glass sheet whereby each nozzle is a predetermined distance from the surface of the bent glass sheet to ensure a uniform application of air.

oo 9 a third aspect the invention provides a method of making a mould for 20 making shaped tempered glass, the method comprising: providing a thermally inert material; constructing a mould having a frame from the thermally inert material, the frame providing a support surface to support the outer portions of a sheet of glass to be shaped and tempered; and sandwiching a metallic heat transfer material between the support ";2"surfaceof the frame; and an anti-marking material to prevent the frame from contacting the glass directly in use.

/0 Preferably, the thermally inert material can withstand repeated exposure to high temperature without altering its shape. Preferred thermally inert materials include those comprising calcium silicate and materials produced by Cape Industrial Products Limited, Glasgow, Scotland under the trade names Monolux 500, Monalite M1 and G3, Monalite 1000, Duratec 750 and Duratec 1000 and combinations of these materials.

Advantageously, the preferred thermally inert materials can be shaped easily by standard known machining methods, such as cutting, sawing, planing, sanding and pressing, to make a mould of any desired shape.

It will be appreciated that the present method of producing a mould, in comparison to known methods, is extremely cost effective as a mould may be produced in a relatively short time period using standard machining techniques without the need for further complicated engineering and construction stages.

Preferably, the method further includes the step of shaping the frame to "*"form two curved side members arranged substantially parallel to one S. 20 another.

Preferably, the method further includes the step of forming a plurality of spaced apart support heads on the support surface.

a Preferably, the metallic heat transfer material is mounted on the support surface.

ft Alternatively, the metallic heat transfer material and anti-marking material may be supported on an adjustable structure mounted to the frame.

Preferably, the anti-marking material is freely mounted, fixed mechanically or mounted by means of an adhesive to the heat transfer material.

Preferably, the metallic heat transfer material is selected from mild steel, tin, stainless steel, iron, chrome and vanadium.

Preferably, the anti-marking material is ceramic paper.

Preferred embodiments of the invention will now be described, by way of example, with reference to the accompanying drawings in which: Figure 1 is a schematic end elevation of a mould and heating means of apparatus of the invention; Ose: Figure 2 is an side elevation of the apparatus of Figure 1; C**Figure 3 is a plan view of the apparatus of Figures 1 and 2; 20 Figure 4 is a schematic showing the incorporation of apparatus of the invention into a shaped tempered glass manufacturing plant; 5a is an enlarged cross-sectional elevation showing the arrangement of supporting head, heat transfer material and anti-marking IC"C*material according to a preferred embodiment of the apparatus of the invention; "o ~Figures 5b and 5c are plan and side views of the arrangement 0:i shown in Figure 0 0 -shown in Figure Figures 6a and 6b show end elevations of a preferred air blowing unit for use in the method of the invention; and Figures 7a, 7b and 7c illustrate end elevations of a preferred method of the invention.

As shown in Figures 1 to 3 a preferred apparatus of the invention is a mould 1 comprising a frame la having two curved side members 2a, 2b arranged substantially parallel to one another.

The presence of an anti-marking material 3 between the glass 4 and the heat transfer material 5 reduces the likelihood of marking of the surface of the glass during the shaping procedure.

Preferably, the frame supports the glass sheet by means of a plurality of spaced apart support heads 6. This arrangement is preferred because it minimizes the area of contact between the glass sheet and the support frame of the mould.

Preferably, the mould is made from an insulation material which can 20 withstand repeated exposure to high temperature without altering its shape. Preferred mould materials include those comprising calcium silicate and materials produced by Cape Industrial Products Limited, Glasgow, Scotland under the trade names Monolux 500, Monalite M1 and Monalite 1000, Duratec 750 and Duratec 1000. These materials can be machined easily to make a mould of any desired shape.

As shown in Figures 5a to 5c, a 0.5 mm thick tin heat transfer material is sandwiched between the support heads 6 and an anti-marking material 3 e I comprising a 1-2 mm thick layer of ceramic paper obtained from Warren Blastobell, Chesterfield, UK, which is adhered to the tin by means of a ceramic paste adhesive, Carborundum Fiberfrax.

The surface area of each support head with tin and ceramic paper mounted thereon is approximately 6mm 2 The mould material is porous and the tin is preferably mounted on the mould by fitting it over a support head and pressing it into the surface of the mould material. It will be appreciated that an adhesive could be used to mount the tin on the support head, but this is not preferred.

A preferred embodiment of a method of making shaped and tempered glass according to a second aspect of the invention comprises providing a mould 1 as described previously and supporting a sheet of glass 4 on top of the support heads 6.

As shown in Figure 4, the mould is attached to a stainless steel cable or mild steel chain and pulled along a mild steel track T on U-shaped cast iron wheels W into the centre of an IR oven 7 having a curved roof 8 and floor 9. The door of the IR oven is preferably opened and closed by means of a pneumatic ram arrangement (not shown) which can be operated rapidly to minimize heat loss.

A plurality of IR heating elements 10 are arranged on both sides of the glass sheet 4. Preferred IR heating elements and the IR oven can be obtained from Mike Lockwood Furnaces, R D Fabrications, and Overtons Electrical Contractors, all of Nottinghamshire, England. The IR I elements 10 are conventional coiled resistant wires for emitting medium wave IR radiation. The heating elements 10 are operated independently by means of Eurotherm thyristor controllers so that outer portions of the glass sheet are heated before or more quickly than the central portion.

This ensures a smooth bending of the heated glass sheet under gravity against the mould. The glass sheet is heated to 625°C. Temperature sensors (not shown) are preferably provided to monitor the temperature of the glass and control heating via the Eurotherm controllers.

The IR oven may also include an optional air inlet a which serves to circulate air in the oven to ensure uniform heating.

Figures 7a, 7b and 7c show a preferred method in which the outer portion O of the glass sheet is heated Figure 7a, before or more than the central portion C, Figure 7b, to produce a shaped tempered glass sheet having excellent optical quality.

Figure 7c shows a possible product of a method in which the glass is heated uniformly, ie there is no earlier or preferential heating of the outer 20 portion of the glass sheet. As shown the outer portion of the glass sheet produced is not curved.

After heating and shaping, the glass is pulled through into an air blower unit 11, as depicted in Figure 6a, comprising an air fan (not shown) connected to a plurality of air nozzles 1 la mounted on blast heads 12 in a chamber 13. The nozzles 1 la are arranged on both sides of the glass sheet and are movable independently by means of a adjustable height control 14 so that they can maintain a predetermined distance from the glass surface oooe• as the shape of the glass changes on cooling. Preferably the distance is approximately 50mm. The air fan is operated to blow air at ambient temperatures through the nozzles and this cools the glass rapidly. If the distance from the glass surface is greater than 50mm the speed of the fan can be increased to compensate.

A preferred adjustable height control 14 is shown in Figure 6b. It comprises a pair of upright members 15 on which respective sides of a blast head 12 are mounted. Each side of the blast head can be moved along its member 15 to alter the distance between the glass surface and the nozzles 1 la and the attitude of the nozzles as desired for any given sheet of glass. The position of the side of the blast head 12 on the member 15 is preferably fixed by means of a slide ring and locking bolt arrangement 16 as shown in Figure 6b.

The arrangement of the nozzles also permits glass of different thicknesses to be cooled effectively.

A 45 kW 1450rpm fan unit capable of delivering 50,000 cubic feet per 20 minute (23.3 m3s 1 of air is provided with a variable speed drive, such as a Danfoss HV-AC Drive Type 3562. Suitable fan units can be obtained from Metrico Industrial Fans Ltd, Cheshire, England.

*"Preferably, the air blower unit comprises two square chambers with a fan unit at each end of each chamber. The fans are preferably connected to the nozzles of the blast heads by means of known ducting such as a Tico M bellow (James Walker, UK).

IC

The speed of cooling should be controlled so that the glass temperature is reduced from approximately 625'C to 400'C as quickly as possible without breaking the glass. It will be appreciated that the rate of cooling will vary depending on the thickness of the glass sheet, but a skilled person will be able to determine the optimum rate of cooling for a given thickness of glass using routine tests involving nothing more than trial and error.

The air blower unit is preferably arranged so that a plurality of cooling zones are formed whereby the glass can be subjected to different rates of cooling, as desired.

A preferred embodiment of a method of making a mould for making shaped and tempered glass according to a third aspect of the invention comprises providing an insulating material which can withstand repeated exposure to high temperature without altering shape and constructing a mould 1 as described previously.

Preferred insulating materials include those as described previously and may be obtained in various forms such as a block, sheet, plank or strip.

The insulating materials can be easily shaped to provide a mould 1 using known machining techniques, for example: cutting; sawing; planing; shaving; sanding; and pressing.

Preferably, a rectangular sheet of insulating material of uniform thickness Sis machined to form four planks of material having identical widths.

If it is desired to form a square frame then the planks are machined so that they all are identical in length. Alternatively, if it is desired to form a rectangular frame, then the planks are machined to form two planks of identical length which are longer than the two other planks, each of which are identical in length.

The planks are then connected and secured in an end-to-end fashion to form a square or rectangular shaped frame.

Preferably, the end of one plank is secured to the end of another plank by "means of an adhesive.

Alternatively, a rectangular or square frame la is formed by clamping a rectangular or cubic shaped block of mould material, respectively in a i: stationary position and then removing a central core of insulating material from the block.

Preferably, two perpendicular opposing sides of the frame la are shaped to form two curved side members 2a, 2b arranged substantially parallel to one another.

Preferably, a number of "tooth" like shaped portions of insulating material are removed from the support surface of the frame la to form a plurality of spaced apart support heads 6 extending around the perimeter of the frame la.

The support heads are machined further to provide a flat surface, having a 2 surface area of approximately 6mm 2 to receive the glass sheet.

The heat transfer material 5 is preferably mounted on the mould 1 by fitting it over a support head 6 and pressing it into the insulation material.

It will be appreciated that an adhesive could be used to mount the heat transfer material 5 on the support head 6, but this is not preferred.

As mentioned previously, preferred heat transfer materials 5 include mild steel, tin, stainless steel, iron, chrome and vanadium.

The anti-marking material 3, preferably a ceramic paper obtained from Warren Bestobell as mentioned previously, is adhered to the heat transfer material 5 by means of a ceramic paste adhesive, Carborundum Fiberfrax.

In order to test the quality of the glass produced a skilled person may employ the common fragmentation test and particle count.

20 The test involves piercing the shaped glass sheet with a centre punch to release its inherent stress and counting the number of particles per 50 mm square. The particle count is related to the potential hazard should the glass sheet be broken. Preferably, the glass sheet should break into a **large number of small glass particles. Larger particles are potentially more hazardous than smaller particles if they should hit a person.

a. .a Using methods and apparatus according to the invention, shaped tempered glass has been produced which has an average particle count of 50-55 per 2 to satisfy the requirements of British Standard BS6206:1981, Class A.

The glass produced by the invention has an excellent optical quality, making it suitable for use in architectural applications.

The above test can be used by a skilled person to optimise the air fan speed and thereby the speed of cooling for a given thickness of glass, It will be appreciated that the degree of bending is dependent on the mould shape and also the thickness of the glass sheet to be shaped. Successful shaping and tempering using the method and apparatus of the invention has been achieved using sodalime silica glass ("float glass") with the following range of sizes: Table 1 a.

S

Glass Type Thickness Glass Sheet Size Drop (mm) (mm) (mm) Float Glass 6 2000x1800 to 100x100 360 to Float Glass 8 2000x1800 to 100x100 360 to Float Glass 10 2000x1800 to 100x200 360 to Float Glass 12 2000x1800 to 300x300 360 to Float Glass 15 1800x1800 to 300x300 360 to Float Glass 19 1800x1500 360 Float Glass 25 1200x1200 200 m

AO

In Table 1 the radius of curvature or "drop" which can be obtained is also indicated.

The preferred dimensions A to D indicated on the figures are: A =2.3 metres B =2m; C =1.5m; D THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS: 1. Apparatus for making shaped tempered glass comprising: a mould constructed from a thermally inert material and including a frame arranged to support outer portions of a sheet of glass to be shaped and tempered; wherein a metallic heat transfer material is sandwiched between the support surface of the frame and an anti-marking material to prevent the frame from contacting the glass directly in use.

2. Apparatus as claimed in Claim 1 wherein the frame comprises two curved side members arranged substantially parallel to one another.

3. Apparatus as claimed in Claim 1 or 2 wherein the support surface of the frame comprises a plurality of spaced apart support heads.

4. Apparatus as claimed in Claim 3 wherein the surface area of the support heads is from 6mm to 12mm 2 Apparatus as claimed in any preceding claim wherein the metallic 20 heat transfer material is selected from mild steel, tin, stainless steel, iron, chrome and vanadium.

6. Apparatus as claimed in any preceding claim wherein the thickness of the metallic heat transfer material is approximately a a o 7. Apparatus as claimed in any one of the preceding claims wherein the anti-marking material is ceramic paper.

Claims (11)

1. 8. Apparatus as claimed in any one of the preceding claims wherein the anti-marking material has a thickness of from 0. 1mm to 3mm.
2. 9. Apparatus as claimed in anyone of the preceding claims wherein the thermally inert material is calcium silicate, Monolux 500, Monalite Ml and G3, Monalite 1000, Duratec 750, Duratec 1000 and combinations thereof. A method of making shaped tempered glass comprising: i) providing apparatus as defined in any one of Claims 1 to 9; ii) supporting a sheet of glass to be shaped and tempered on the frame of the mould; iii) heating the glass so that it sags and conforms to the shape of the frame; iv) subsequently cooling the glass to obtain a shaped tempered sheet of glass.
3. 11. A method as claimed in Claim 10 wherein, initially, the outer portions of the sheet of glass are heated before or more than the central 20 portion. p
4. 12. A method of making a mould for making shaped tempered glass, the method comprising the steps of: providing a thermally inert material; constructing a mould having a frame from the thermally inert material, the frame providing a support surface to support the outer portions of a sheet of glass to be shaped and tempered; and «o* sandwiching a metallic heat transfer material between the support surface and an anti-marking material to prevent the frame from contacting the glass directly in use.
5. 13. A method as claimed in Claim 12 wherein the thermally inert material is calcium silicate, Monolux 500, Monalite M1 and G3, Monalite 1000, Duratec 750, Duratec 1000 and combinations thereof.
6. 14. A method as claimed in Claim 12 or 13 further including the step of shaping the frame to form two curved side members arranged substantially parallel to one another. A method as claimed in any one of Claims 12 to 14 further including the step of forming a plurality of spaced apart support heads on the support surface.
7. 16. A method as claimed in any one of Claims 12 to 15 wherein the metallic heat transfer material is mounted on the support surface.
8. 17. A method as claimed in any one of Claims 12 to 16 wherein the metallic heat transfer material and anti-marking material are supported on an adjustable structure mounted to the frame. 9 9
9. 18. A method as claimed in any one of Claims 12 to 17 wherein the anti-marking material is freely mounted, fixed mechanically or mounted by means of a adhesive to the heat transfer material. 4
10. 19. Apparatus for making curved tempered glass substantially as described herein with reference to one or more of Figures 1 to A method of making curved tempered glass substantially as described herein, with reference to one or more of Figures 7a and 7b.
11. 21. A method of making a mould for making shaped tempered glass substantially as described herein. DATED THIS 10TH DAY OF MARCH 1998 Design-A-Glass Limited By its Patent Attorneys: GRIFFITH HACK Fellows Institute of Patent Attorneys of Australia 9SSS @6 S 6S S *5 S S *r @9 9 6 0 S 9 S 9 S 1 -1 I ABSTRACT Method and apparatus for making glass In a first aspect, the invention relates to apparatus for making shaped tempered glass comprising: a mould comprising a frame arranged to support outer portions of a sheet of glass to be shaped and tempered; wherein a heat transfer material is provided on a support surface of the frame to prevent the frame from contacting the glass directly in use. The invention also relates to a method of using the apparatus of the invention to make shaped tempered glass. (Figure No. 1) C 5 S. a