AU683776B2 - Fuel cell plant with utilization of the cathode heat, and process for operating it - Google Patents

Fuel cell plant with utilization of the cathode heat, and process for operating it

Info

Publication number
AU683776B2
AU683776B2 AU36497/95A AU3649795A AU683776B2 AU 683776 B2 AU683776 B2 AU 683776B2 AU 36497/95 A AU36497/95 A AU 36497/95A AU 3649795 A AU3649795 A AU 3649795A AU 683776 B2 AU683776 B2 AU 683776B2
Authority
AU
Australia
Prior art keywords
exhaust gas
cathode exhaust
partial
cathodes
fuel cells
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU36497/95A
Other versions
AU3649795A (en
Inventor
Pavel Chmelik
Jurgen Lehmeier
Kurt Reiter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of AU3649795A publication Critical patent/AU3649795A/en
Application granted granted Critical
Publication of AU683776B2 publication Critical patent/AU683776B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M2008/147Fuel cells with molten carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0048Molten electrolytes used at high temperature
    • H01M2300/0051Carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/0071Oxides
    • H01M2300/0074Ion conductive at high temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H01M8/04022Heating by combustion
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074Heat exchange unit structures specially adapted for fuel cell
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Fuel Cell (AREA)

Abstract

It is current pratice in a high-temperature fuel cell plants to divide the cathode exhaust gas in particular into two partial streams, one of which is recirculated into the cathodes and the other used for heating, in which branching takes place by relatively sophisticated technical means directly a the gas outlets at about the operating temperature of the fuel cells. In order to simplify these means, all the cathode exhaust gas is to be taken via a heat exchanger to a branch with two partial lines, in which the first partial line opens into the cathodes via an air-mixing position and the heat exchanger and the second opens into means for raising the temperature. Thus the branching of the hot cathode exhaust gas is avoided and the heat of all the cathode exhaust gas is used to heat the partial cathode exhaust gas flow taken back into the cathodes. The invention is applicable especially and preferably to fuel cells with an operating temperature of over 600 DEG C. Such fuel cells are carbonate melt and solid electrolyte types.
AU36497/95A 1994-10-19 1995-10-06 Fuel cell plant with utilization of the cathode heat, and process for operating it Ceased AU683776B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4437413 1994-10-19
DE4437413 1994-10-19
PCT/DE1995/001388 WO1996013871A2 (en) 1994-10-19 1995-10-06 Fuel cell plant with utilization of the cathode heat, and process for operating it

Publications (2)

Publication Number Publication Date
AU3649795A AU3649795A (en) 1996-05-23
AU683776B2 true AU683776B2 (en) 1997-11-20

Family

ID=6531207

Family Applications (1)

Application Number Title Priority Date Filing Date
AU36497/95A Ceased AU683776B2 (en) 1994-10-19 1995-10-06 Fuel cell plant with utilization of the cathode heat, and process for operating it

Country Status (9)

Country Link
EP (1) EP0787367B1 (en)
JP (1) JPH10507867A (en)
AT (1) ATE165478T1 (en)
AU (1) AU683776B2 (en)
CA (1) CA2202984A1 (en)
DE (1) DE59502015D1 (en)
DK (1) DK0787367T3 (en)
ES (1) ES2116770T3 (en)
WO (1) WO1996013871A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1484814A2 (en) * 2002-12-27 2004-12-08 General Electric Company Fuel cell module, combined cycle power system, and power generation method

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19807878C2 (en) * 1998-02-25 2001-10-31 Xcellsis Gmbh Fuel cell system
WO2000016425A1 (en) * 1998-09-14 2000-03-23 Questor Industries Inc. Electrical current generation system
DE10042314B4 (en) * 2000-08-29 2010-06-17 Alstom Technology Ltd. Gas turbine arrangement with a fuel cell
DE102004002337A1 (en) * 2004-01-16 2005-08-11 Bayerische Motoren Werke Ag An energy conversion device and method of operating the energy conversion device
DE102004004914B4 (en) * 2004-01-31 2006-11-23 Forschungszentrum Jülich GmbH Method for generating electricity and heat
EP1804322B1 (en) * 2004-10-19 2011-12-14 Central Research Institute of Electric Power Industry Combined power generation equipment
DE102006003740B4 (en) * 2006-01-20 2011-06-30 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 Method and system for operating a high temperature fuel cell
AT502009B1 (en) * 2006-05-09 2007-09-15 Avl List Gmbh Fuel cell system, comprises recirculation device on cathode side, and separately adjustable respective recirculation line is provided for every component
AT501963B1 (en) * 2006-05-09 2007-09-15 Avl List Gmbh Process to fabricate decorative glass panel by bonding granite beads to horizontal surface followed by heating to glass melting point
GB201012775D0 (en) * 2010-07-30 2010-09-15 Rolls Royce Fuel Cell Systems Ltd A solid ovide fuel cell system
DE102010035727A1 (en) * 2010-08-28 2012-03-01 Daimler Ag Charging device for fuel cell device of motor vehicle, has recirculation device arranged downstream to compressor and upstream to another compressor at inlet point and recirculating exhaust gas of fuel cell
DE102017205704A1 (en) * 2017-04-04 2018-10-04 Robert Bosch Gmbh Turbocompressor, in particular for a fuel cell system

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3976506A (en) * 1975-02-12 1976-08-24 United Technologies Corporation Pressurized fuel cell power plant with air bypass
JPS61176075A (en) * 1985-01-30 1986-08-07 Hitachi Ltd Fuel battery cooling system
JPS63152878A (en) * 1986-12-17 1988-06-25 Mitsubishi Heavy Ind Ltd Solid electrolyte fuel cell power generating system
JPS63279576A (en) * 1987-05-11 1988-11-16 Ishikawajima Harima Heavy Ind Co Ltd Cathode recycle device for fused carbonate fuel cell
JPS63289774A (en) * 1987-05-22 1988-11-28 Ishikawajima Harima Heavy Ind Co Ltd Fused carbonate type fuel cell power generator
JP2942999B2 (en) * 1990-05-01 1999-08-30 石川島播磨重工業株式会社 Molten carbonate fuel cell power generator
DE4021097A1 (en) * 1990-07-02 1992-01-09 Siemens Ag FUEL CELL POWER PLANT

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1484814A2 (en) * 2002-12-27 2004-12-08 General Electric Company Fuel cell module, combined cycle power system, and power generation method
EP1484814A3 (en) * 2002-12-27 2009-12-09 General Electric Company Combined cycle fuel cell power system

Also Published As

Publication number Publication date
JPH10507867A (en) 1998-07-28
DE59502015D1 (en) 1998-05-28
WO1996013871A3 (en) 1996-06-13
CA2202984A1 (en) 1996-05-09
EP0787367B1 (en) 1998-04-22
EP0787367A2 (en) 1997-08-06
ES2116770T3 (en) 1998-07-16
WO1996013871A2 (en) 1996-05-09
AU3649795A (en) 1996-05-23
ATE165478T1 (en) 1998-05-15
DK0787367T3 (en) 1999-01-18

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Legal Events

Date Code Title Description
MK14 Patent ceased section 143(a) (annual fees not paid) or expired