AU658583B2 - Process for printing by marking a substrate based on glass fibers and novel substrate obtained - Google Patents
Process for printing by marking a substrate based on glass fibers and novel substrate obtained Download PDFInfo
- Publication number
- AU658583B2 AU658583B2 AU86714/91A AU8671491A AU658583B2 AU 658583 B2 AU658583 B2 AU 658583B2 AU 86714/91 A AU86714/91 A AU 86714/91A AU 8671491 A AU8671491 A AU 8671491A AU 658583 B2 AU658583 B2 AU 658583B2
- Authority
- AU
- Australia
- Prior art keywords
- substrate
- heat
- film
- imprints
- fusible material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000003365 glass fiber Substances 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 29
- 239000004753 textile Substances 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims description 5
- 230000004323 axial length Effects 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 description 4
- 239000003550 marker Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4479—Manufacturing methods of optical cables
- G02B6/4482—Code or colour marking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/08—Stamping or bending
- B44C3/085—Stamping or bending stamping
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F7/00—Signs, name or number plates, letters, numerals, or symbols; Panels or boards
- G09F7/16—Letters, numerals, or other symbols adapted for permanent fixing to a support
- G09F7/165—Letters, numerals, or other symbols adapted for permanent fixing to a support obtained by a treatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/0029—Translucent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
- Y10T156/1039—Surface deformation only of sandwich or lamina [e.g., embossed panels]
- Y10T156/1041—Subsequent to lamination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24628—Nonplanar uniform thickness material
- Y10T428/24736—Ornamental design or indicia
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Manufacturing & Machinery (AREA)
- Theoretical Computer Science (AREA)
- Laminated Bodies (AREA)
- Printing Methods (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Glass Compositions (AREA)
- Moulding By Coating Moulds (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
- Marking of products based on glass fibres. - The process consists in coating, at least partially, at least one of the faces of the said substrate of a film of heat-meltable material and in producing, on the surface of the said film, matt impressions, at least by localised hot plastic flow of the said heat-meltable material. - Application to ribbon-like textile sheets used both as diffuser screens and/or attenuators of light.
Description
i I i Our Ref: 411187 P/00/011 Regulation 3:2
AUSTRALIA
658583 Patents Act 1990
ORIGINAL
COMPLETE SPECIFICATION STANDARD PATENT 41S4 4 4 44 4 494 4 *44 4 4* *0 e 4* Applicant(s): 44.4.4 4 4 4 44 4* 4 44 4 s 44 4 4 44 4 4 4 Societe Anonyme Hexcel-Genin 3, Avenue Condorcet B.P. 1208 69608 VILLEURBANNE
FRANCE
ARTHUR S. CAVE CO.
Patent Trade Mark Attorneys Level 10, 10 Barrack Street SYDNEY NSW 2000 Address for Service: Invention Title: Process for printing by marking a substrate based on glass fibers and novel substrate obtained The following statement is a full description of this invention, including the best method of performing it known to me:- 5020 FIELD OF THE INVENTION The present invention relates to a process for printing on a face of a substrate.
The invention concerns more specifically, by way of preferred but non-limiting application, substrates in the form of a textile web more or less translucent by the nature of the material, its internal coloration or its texture, on which decorative prints are to be applied as a function of their future applications by way of light screen, attenuation, diffusion or decorative coating.
Substrates of the above type are frequently used in the form of sheets, webs or bands to constitute screens, curtains or light-diffusing or -attenuating panels or decorative coatings.
With a view to breaking up the uniformity presented by such products, it has been envisaged to colour them in uniform shades. Such coloration cannot be considered as contributing a decorative print which is particularly sought-after.
In order to overcome this drawback, it has been recommended to weave these 20 textile webs so as to show either weaves or patterns resulting from a particular, localized, specific interlacing of certain fibers or strands.
A large variety of patterns have thus been obtained, but the aesthetic and 0 °decorative appearance procured does not appear certain, clear, distinct and in any case the S•o 25 possible patterns are limited by the technicality of interlacing of the strands, filaments or fibers.
In order to obtain varied patterns, such problems of technicality in production, and feasibility, is translated by a considerable increase in the cost price per surface unit or length.
'It is an object of the present invention to overcome the above drawbacks by Sproposing a novel process for printing substrates, the novel process making it possible to p:\wpdocs\sab\411187.spc\sb 1 -2obtain, at an advantageous cost price, a considerable richness and variety of patterns or prints, decoration, identifications or personalizations capable of presenting, in addition, a certain aesthetic and decorative appearance.
SUMMARY OF THE INVENTION In accordance with the present invention there is provided a process for printing on a face of a substrate, comprising the steps of coating at least in part at least one of the faces of said substrate with a film of heat-fusible material, and applying heat and pressure via a marking tool to a location on the surface of said film whereby to form imprints in said heat-fusible material.
I.i Preferably the substrate includes glass fibres.
S, 5 Preferably the imprints have a smooth matt surface.
S In another aspect there is provided a substrate having on at least part of at least one of its faces, a film of heat-fusible material having imprints on the surface thereof.
The process of the invention is described hereinafter in its preferred, non-binding j ;20 application to the printing of substrates in the form of a textile web made from glass fibers, in accordance with a known technique which does not form part of the invention.
Such textile webs present, generally by the choice of the constituent material or the weave, a more or less great translucenp:\wpdocs\sab\411187.spc\sb -3- 4 cy, with a view to being used principally as lightdiffusing or -attenuating panel or screen.
It goes without saying that the object of the invention can be implemented for any other type of substrate, at least in part based on glass fibers, whether it be supple, flexible, compact, of small or large thickness.
The process according to the invention consists in coating, at least in part, at least one of the faces .of the substrate with a film of heat-fusible tk i s fI r e erck6 1 materialof transparent, translucent or slightly coloured nature. The film is deposited in any suitable manner compatible with the nature of the substrate.
on A particularly suitable process in the case of sub- 15 strates in the form of a supple or relatively supple textile web is the deposit by coating, by continuously o: advancing passage in a coating bath or vat containing *000 o. a liquid solution of the heat-fusible material chosen.
Deposit by lining may also be envisaged. Among the numerous possibilities offered by the technique of plastics materials, a particularly suitable material for coating or for constituting the film is polyvinyl chloride, although an acrylic material may also be satisfactorily employed.
The addition or deposit of the film of heat-fusible ~material is effected at a rate of at least 6% by weight of dry extracts of said material with respect to the .o weight of the substrate, and preferably from 8 to u 30 Deposit of the film is effected according to the conventional conditions for the film to adhere firmly and in resistant manner to the substrate on which it is fixed by polymerization or hardening, generally by heat.
After the above preparatory phase has been accom- 6 plished, the substrate is subjected to hot marking ii -4- Poe 6 0.0t tta *944* 44s 90 4, tt~ (C C C C C I CC
SC*
tt so as to produce marks, on the surface of the film, at least by localized hot creeping of the heat-fusible material which, after cooling, leaves smooth, matt imprints apparent, corresponding exactly in shapes and contours to the positive impression or impressions of the marking tool used which, of course, may be plane or of revolution.
Hot marking is effected.by temporarily applying a temperature of between 6.0 and 200 0 C and by exerting, by the marking tool, a pressure close to 5.105 Pon the film of heat-fusible material.
The hot marking operation may be carried out via a press or by a process of continuous advance of the substrate between a heating marker cylinder 15 and a support cylinder whose periphery is in that case advantageously provided with a compressible coating such as elastomer presenting a Shore hardness of to 90. In such a case, the cylinders are driven synchronously in opposite rotations so as to cause the substrate to advance at a speed which may be included between 2 and 20 metres per minute. In such a case, the pressure exerted on the substrate by the two cylinders is adjusted so that about 5 to 15 tons intervene over the axial length of contact between the generatrices of the cylinders.
In all cases, the operational conditions of pressure and of temperature are retained as a function of the heat-fusible material constituting the film, so that hot marking produces, by the impression of 30 the marking tool, at least a softening of the surface of the heat-fusible material, promoting at least a surface creeping, translated, after cooling, by the indelible existence of a mark, generally of opacifying character, presenting a smooth surface state which 35 may thus be easily appreciated visually with respect >1 may thus be easily appreciated visually with respect 4 F;i* i rZ '4 f.:i to the general state of the film, whether the latter be visually perceptible directly or indirectly, by reason of its translucency, its small thickness or the absence of contrasts that it presents with respect to the glass fibers constituting the subjacent substrate.
The imprints thus made are visually perceptible directly and even more so by the effect of transparency when the substrate, preferably of the type retained hereinbefore, is interposed between an observer and a source of light.
Experiments carried out have enabled very good results to be obtained on webs of coloured, woven textile fabric worked for the purpose of constituting light-diffusing or attenuating screens, implementing the parameters set forth hereinbelow.
EXAMPLE 1 A substrate of the textile sheet type, based on glass fibers of 165 g/m 2 woven in a cloth weave, was coated on at least one of its faces with a film
'V
Fo 4I 4% of polyvinyl chloride, at a rate of 30% by weight of dry extracts with respect to the weight of the substrate.
Such a substrate was treated by continuously F advancing between support and heating/printing cylinders 25 rotating in opposite directions at synchronous speeds, at 10 metres per minute.
9 The heating marker cylinder was maintained at a temperature equal to 130 0 C and exerted on the substrate a pressure of 10 tons over 160 centimetres 30 of axial length of cylinder.
Long-lasting imprints of continuous and/or discontinuous patterns were obtained on the surface of the film without altering the latter nor distorting or degrading the substrate, such imprints being characterized by a smooth surface and a partial localized iI
'I
(h~ 4* h 4 4( 4ie eu r -6opacification limited exactly to the contours of the imprint or imprints of the heating marker cylinder.
EXAMPLE 2 The same substrate was treated as in Example 1, but employing a temperature of 80 0 C, the same pressure and a speed of 5.5 metres per minute.
In both cases, imprints of generally matt appearance comprising a smooth surface and a generally opacifying character were made precisely, in extremely varied patterns, presenting a resistance to ageing without any alteration of the film or of the substrate having been considered or ascertained.
The invention also relates to the novel product obtained which is characterized by a substrate based 15 on glass fibers whether it be compact, supple or flexible or made in the form of a textile fabric, of any weave, whose texture gives a more or less accentuated character of transparency. Such a novel product is characterized by the existence on the surface, on at least one of the faces of the substrate, of imprints resulting from a hot marking having modified the state of the heat-fusible material, to the point of showing smooth, matt marks of opacifying character in the more particular case of employing a heat-fusible 25 material of translucent character added to a substrate of transparent character.
The invention is not limited to the examples described, as various modifications may be made thereto without departing from its scope.
C
I Ae L Zt If I I 41
Claims (14)
1. A process for printing on a face of a substrate which includes glass fibres, comprising the steps of coating at least in part at least one of the faces of said substrate with a film of heat-fusible material, and applying heat and pressure via a marking tool to a location on the surface of said film whereby to form imprints in said heat-fusible material.
2. The process of Claim 1, wherein the film of heat fusible material is formed from a dry extract which weighs at least 6% by weight of the substrate.
3. The process of Claim 1 or 2, wherein the film of heat-fusible material is translucent and the imprints formed by the marking tool are opacified.
4. The process of Claim 1 or 3, wherein the imprints are made during application of a temperature of between 60°C and 200 0 C.
5. The process of Claim 4, wherein a pressure of approximately 5 x 10 S Pa is applied 20 to the marking tool during application of the tool to the surface of said film.
6. The process of one of Claims 1 to 5, wherein the marking tool is in the form of a heated cylinder and the imprints are made by continuously advancing the substrate between the cylinder and a support cylinder and the cylinders are driven synchronously S: 25 in opposite directions to cause the substrate to advance at a speed of between 2 to Smetres per minute.
7. The process of Claim 6, wherein the cylinders exert on the substrate a pressure of between 5 and 15 tons applied over an axial length of cylinder in the order of 160 centimetres. S8 A .prn css s cimrned in auny ne nf th preceding claims wherein the ubtrat p includes glass fibres. p:\wpdocs\sab\411 187.spe\sb -8-
8. A process as claimed in any one of the preceding claims wherein the imprints have a smooth matt surface.
9. A process as claimed in any one of the preceding claims wherein the imprints are at least partially formed by a process of hot creeping.
A substrate including glass fibers and having on at least part of at least one of its i faces, a film of heat-fusible material having imprints on the surface thereof formed by i application to the heat-fusible material of heat and pressure via a marking tool.
11. The substrate of Claim 10, wherein the film of heat-fusible material is at least partially translucent.
12. The substrate of Claim 10 or 11, wherein the substrate itself is constituted by a 15 textile fabric of translucent character, and the imprints are in the form of localized opacifying matt imprints.
13. A printing process substantially as herein described with reference to any one of the Examples.
14. A substrate substantially as herein described with reference to any one of the Examples. i• DATED this 13th day of February 1995 SOCIETE ANONYME HEXCEL-GENIN By Its Patent Attorneys DAVIES COLLISON CAVE p:\wpdo\ab\4 8spe\s S"LS p:\wpdocs\sab\411187.spe\sb substrate with a film of heat-fusible material and 4 v *at least in part at least one of the faces of said substrate with a film of heat-fusible material and in making matt imprints on the surface of said film 1 at least by localized hot creeping of said heat-fusible r"yi material. The invention is more particularly applicable to webs of textile cloth used as light-diffusing and/or S'E attenuating screens. 6 6V t'I Thsivn.nrltst h akn fsbtae bai ongasfbr.Tepocs osssi otn
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9013415A FR2668423B1 (en) | 1990-10-24 | 1990-10-24 | METHOD OF PRINTING BY MARKING OF A SUBSTRATE BASED ON FIBERGLASS AND NEW SUBSTRATE OBTAINED. |
| FR9013415 | 1990-10-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU8671491A AU8671491A (en) | 1992-04-30 |
| AU658583B2 true AU658583B2 (en) | 1995-04-27 |
Family
ID=9401680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU86714/91A Ceased AU658583B2 (en) | 1990-10-24 | 1991-10-22 | Process for printing by marking a substrate based on glass fibers and novel substrate obtained |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5360640A (en) |
| EP (1) | EP0483031B1 (en) |
| JP (1) | JPH04263921A (en) |
| AT (1) | ATE115908T1 (en) |
| AU (1) | AU658583B2 (en) |
| BR (1) | BR9104584A (en) |
| CA (1) | CA2054040A1 (en) |
| DE (1) | DE69106107T2 (en) |
| ES (1) | ES2068548T3 (en) |
| FR (1) | FR2668423B1 (en) |
| IL (1) | IL99813A0 (en) |
| MX (1) | MX9101739A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPM787994A0 (en) * | 1994-09-06 | 1994-09-29 | University Of Queensland, The | A printable flexible sheet |
| AU690744B2 (en) * | 1994-09-06 | 1998-04-30 | University Of Queensland, The | A printable flexible sheet |
| FR2807772B1 (en) * | 2000-04-12 | 2002-07-26 | Porcher Ind | PRINTABLE FIRE RESISTANT MEDIUM |
| FR2853333B1 (en) * | 2003-04-01 | 2006-01-13 | Arjo Wiggins | PRIMARY GLASS SAIL |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1482151A (en) * | 1966-04-13 | 1967-05-26 | Plastiques De Roubaix | Improvement to plastic sheets |
| US4395263A (en) * | 1977-04-21 | 1983-07-26 | Davis R Elbert | Unitary laminate with permanent indicia pattern: transfer printings onto plastic-coated rigid panels |
| DE3436065A1 (en) * | 1984-10-02 | 1986-04-17 | Hoechst Ag, 6230 Frankfurt | Opaque polypropylene film having light-transparent areas, process for the production thereof, and the use thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE816805C (en) * | 1950-02-12 | 1951-10-11 | Anorgana | Process and device for the production of surface-refined plastic films |
| US3776751A (en) * | 1968-08-06 | 1973-12-04 | Ici Ltd | Method of producing reinforced thermoplastic materials |
| DE2621141A1 (en) * | 1976-05-13 | 1978-04-06 | Freudenberg Carl Fa | PROCESS FOR PRODUCING A REFINED AREA |
| US4229400A (en) * | 1978-09-18 | 1980-10-21 | Fiberite Corporation | Mold component comprising a mat impregnated with a reaction product of an aminoplast resin and a polyalkylene glycol |
| US4268577A (en) * | 1978-12-29 | 1981-05-19 | Ppg Industries, Inc. | Elastomeric coating composition for glass fibers and coated glass fibers made from same |
| JPS60141526A (en) * | 1983-12-28 | 1985-07-26 | Konsaisu:Kk | Method of matting |
| US5093158A (en) * | 1988-11-28 | 1992-03-03 | Allied-Signal Inc. | Method to make fiber/polymer composite with nonuniformly distributed polymer matrix |
-
1990
- 1990-10-24 FR FR9013415A patent/FR2668423B1/en not_active Expired - Fee Related
-
1991
- 1991-10-22 AU AU86714/91A patent/AU658583B2/en not_active Ceased
- 1991-10-22 IL IL99813A patent/IL99813A0/en unknown
- 1991-10-23 DE DE69106107T patent/DE69106107T2/en not_active Expired - Fee Related
- 1991-10-23 BR BR919104584A patent/BR9104584A/en not_active IP Right Cessation
- 1991-10-23 ES ES91420378T patent/ES2068548T3/en not_active Expired - Lifetime
- 1991-10-23 AT AT91420378T patent/ATE115908T1/en not_active IP Right Cessation
- 1991-10-23 EP EP91420378A patent/EP0483031B1/en not_active Expired - Lifetime
- 1991-10-23 CA CA002054040A patent/CA2054040A1/en not_active Abandoned
- 1991-10-24 JP JP3277604A patent/JPH04263921A/en not_active Withdrawn
- 1991-10-24 MX MX9101739A patent/MX9101739A/en unknown
- 1991-10-24 US US07/780,989 patent/US5360640A/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1482151A (en) * | 1966-04-13 | 1967-05-26 | Plastiques De Roubaix | Improvement to plastic sheets |
| US4395263A (en) * | 1977-04-21 | 1983-07-26 | Davis R Elbert | Unitary laminate with permanent indicia pattern: transfer printings onto plastic-coated rigid panels |
| DE3436065A1 (en) * | 1984-10-02 | 1986-04-17 | Hoechst Ag, 6230 Frankfurt | Opaque polypropylene film having light-transparent areas, process for the production thereof, and the use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0483031A1 (en) | 1992-04-29 |
| CA2054040A1 (en) | 1992-04-25 |
| US5360640A (en) | 1994-11-01 |
| FR2668423B1 (en) | 1993-03-19 |
| MX9101739A (en) | 1992-06-05 |
| ATE115908T1 (en) | 1995-01-15 |
| BR9104584A (en) | 1992-06-09 |
| ES2068548T3 (en) | 1995-04-16 |
| FR2668423A1 (en) | 1992-04-30 |
| IL99813A0 (en) | 1992-08-18 |
| DE69106107D1 (en) | 1995-02-02 |
| AU8671491A (en) | 1992-04-30 |
| DE69106107T2 (en) | 1995-05-18 |
| JPH04263921A (en) | 1992-09-18 |
| EP0483031B1 (en) | 1994-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3741851A (en) | Embossed foamed sheet materials | |
| US5994264A (en) | Transfer printing of metal using protective overcoat | |
| EP4273348A1 (en) | Digitally printed plate, manufacturing method, and application | |
| CA2357710A1 (en) | Surface covering having differential gloss-in-register and method of making | |
| US5985416A (en) | Coating and transfer printing metal substrates | |
| EP0313979A3 (en) | Method for producing extruded plastic sheets with scratch resistant coating | |
| US5856267A (en) | Transfer printing metal substrates | |
| AU658583B2 (en) | Process for printing by marking a substrate based on glass fibers and novel substrate obtained | |
| JP3900321B2 (en) | Decorative sheet adherend | |
| US6015469A (en) | Process for the production of a support for sublimable color transfer for decorating items or artifacts from metal, plastic materials and the like | |
| CN205498283U (en) | Phragmoid production facility of rainbow film and rainbow film | |
| US5895705A (en) | Awning and backlit sign fabric having a selectively eradicable ink layer and a process for producing same | |
| GB2249994A (en) | Colour printing on coated woven flexible glass fibres | |
| CN1148116A (en) | Method for printing plastic film | |
| US20090214829A1 (en) | Method of Applying a Decorative Film to a Support and Method of Preparing Articles for Said Purpose | |
| JP3161053B2 (en) | Cloth-like makeup material | |
| KR20030067042A (en) | Printing method for leather and the printed leather thereof | |
| KR101768023B1 (en) | Method for manufacturing color embossing fabric | |
| CN215512822U (en) | Printing decorative material production line with simulated texture effect | |
| KR100364692B1 (en) | Apparatus for making transfer paper and thereof method | |
| CN2158798Y (en) | Holographic glass artistic decorative painting | |
| KR20030073609A (en) | Treatment methods for obtaining leather with various patterns thereon and the leather manufactured by the same | |
| CN1162525A (en) | Manufacture of velvet wall carpets | |
| KR100316377B1 (en) | Banner-pet and the method thereof | |
| KR200211972Y1 (en) | Apparatus for making transfer paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |