AU627711B2

AU627711B2 - Process for providing polyamide materials with stain resistance

Info

Publication number: AU627711B2
Application number: AU29663/89A
Authority: AU
Inventors: John Cheng-Chung Chang; Imelda Agnes Muggli; Maynard Henry Olson
Original assignee: Minnesota Mining and Manufacturing Co
Current assignee: 3M Co
Priority date: 1988-03-11
Filing date: 1989-02-06
Publication date: 1992-09-03
Anticipated expiration: 2009-02-06
Also published as: DE68915189D1; EP0332342B1; CA1286555C; JP2744053B2; KR890014830A; JPH01280076A; AU2966389A; EP0332342A2; EP0332342A3; KR970001083B1; DK117789D0; ZA891862B; DE68915189T2; DK117789A

Description

627711 S F Ref: 85594 FORM COMMONWEALTH OF AUSTRALIA PATENTS ACT 1952 COMPLETE SPECIFICATION

(ORIGINAL)

FOR OFFICE USE: Class Int Class Complete Specification Lodged: Accepted: Published: Priority: Related Art: Name and Address of Applicant: Minnesota Mining and Manufacturing Company 3M Center Saint Paul Minnesota 55144-1000 UNITED STATES OF AMERICA Spruson Ferguson, Patent Attorneys Level 33 St Martins Tower, 31 Market Street Sydney, New South Males, 2000, Australia Address for Service: Complete Specification for the invention entitled: Process for Providing Polyamide Materials with Stain Resistance The following statement is a full description of this invention, including the best method of performing it known to me/us r fj 5845/3 (Il i -i ll( 43050 AUS 6A -1- PROCESS FOR PROVIDING POLYAMIDE MATERIALS WITH STAIN RESISTANCE This invention relates to a process for providing fibrous polyamide materials such as nylon carpet with stain resistance and to fibrous polyamide materials so treated.

Fibrous polyamide articles such as nylon carpets are particularly susceptible to staining by natural and artificial acid colorants such as are commonly found in many foods and beverages. A need has long been felt for processes for economically providing such fibrous polyamide articles with resistance to staining by acid colorants.

So Particularly desirable are processes by which durable stain SI 15 resistance can be imparted to fibrous polyamide articles tit$ t 9 during conventional processing and treating operations.

S' U.S. Patent No. 3,961,881 (Sumner et al.) discloses a process for coloring synthetic polyamide textile materials which comprises applying to the textile materials by a dyeing, padding or printing process, an aqueous dispersion of pH less than 7 of a disperse dyestuff containing at least one carboxylic acid group and in the presence of a tanning agent, whereby level colorations are obtained which have excellent wet fastness properties. As set forth by Sumner et al., examples of natural agents include tannic acid and the vegetable tannins, while S.i synthetic agents include condensation products of naphthols, naphthalene sulphonic acids and formaldehyde, condensation products of phenol, naphthalene, formaldehyde and sulphuric acid, condensation products of dihydroxydiphenylsulphone and formaldehyde, condensation products of I' dihydroxydiphenylsulphone sulphonic and aliphatic aldehydes, condensation products of sulphurized phenols, naphthalene and formaldehyde.

U.S. Patent No. 2,205,883 (Graves) discloses tanning agents which are the acidic polymerization products of the polymerization of methacrylic acid with itself as well as interpolymerization of methacrylic acid with other Ci r r Ir .9 99r .9, materials.

U.S. Patent No. 3,408,319 (Rau) discloses tanning compositions which are made by copolymerization of a mixture of methacrylic acid, acrylic acid or mixtures of such acids with a sulfated unsaturated oil. The unsaturated acid used is preferably 75 to 100% methacrylic acid and to 0% respectively of acrylic acid, and generally the use of methacrylic acid exclusively is most practical from the standpoint of cost and effectiveness. The amount of sulfonated oil is from 10 to 25% by weight of the acid monomer.

U.S. Patent No. 3,994,744 (Anderle et al.) discloses aqueous cleaning compositions having a minimum film-forming temperature of at least 30 0 C and comprising a polymer having a glass transition temperature of at least 0 C and a metal salt, form a tacky film after being applied to a soiled substrate. Soil adheres to the tacky film which, as a result of the drying of said composition, fractures to form a removable residue. The compositions contain polymers preferably derived from a carboxylic acid monomer and a soft monomer and/or a hard monomer. Preferred soft monomers are vinyl acetate and the alkyl esters of acrylic acid wherein the alkyl group contains from 1-12 carbon atoms. Suitable hard monomers include lower alkyl methacrylates wherein the lower alkyl group contains 1-3 carbon atoms, cycloalkyl acrylates and methacrylates wherein the cycloalkyl group contains 5-7 carbon atoms, and hard vinyl monomers, examples of acid monomer include acrylic, methacrylic, itaconic, maleic and crotonic acids and monoalkyl esters of itaconic and maleic acids wherein the alkyl group contains 1-8 carbon atoms.

U.S. Patent No. 4,081,383 (Warburton, Jr. et al.) discloses an anti-soiling treatment for carpets and carpet yarns. line carpets or carpet yarns prior to carpet manufacture are coated with a polymeric material containing either a blend of a methacrylic acid emulsion copolymer and an epoxy resin or a methacrylic acid emulsion copolymer having epoxy monomer units therein. The copolymer i -j -3in either case contains 40-75% by weight methacrylic acid and the glass transition temperature of cured coatings of the polymeric material is at least 50 0

C.

U.S. Patent No. 4,334,876 (Beier et al.) discloses a process for producing leather wherein leather stock it subjected to a multiple-stage tanning process involving a first treatment with an aqueous dispersion or solution of a synthetic polymeric composition made by polymerizing at least one member selected from the group consisting of acrylic acid and methacrylic acid and, optionally, one or more polymerizable compounds selected from the group of alkyl esters of acrylic acid, alkyl esters of methacrylic acid and sulfated unsaturated drying oils, followed by a second treatment with a zirconium tanning compound having a 0-45% basicity by the Schorlemmer scale.

U.S. Patent No. 4,388,372 (Champaneria et al.) discloses a durable antisoiling coating composition for textile filaments comprising a perfluoroalkyl ester of a citric acid urethane and fluorinated alcohols in combination with a modified epoxy resin which is the reaction product of Sa carboxyl-functional vinyl polymer, an epoxy resin and a tertiary amine. Preferred vinyl resins for use in making the modified epoxy resin reaction product are the j terpolymers of styrene/ethyl acrylate/methacrylic acid, and V 25 particularly such terpolymers wherein the monomers are in a i mol ratio to one another respectively of about 1:1:2.

SU.S. Patent No. 4,526,581 (Prentiss et al.) discloses a process for producing leather which employs a copolymer tanning agent comprising at least 60 mole percent residues of methacrylic acid and at least about 5 mole percent of residues of at least one alkyl acrylate selected 1 3 from methyl, ethyl, propyl, and butyl acrylates, the copolymer having a weight average molecular weight from about 3,500 to 9,000.

U.S. Patent No. 4,699,812 (Munk et al.) discloses a method for imparting stain resistance to fibers containing free amino groups, and especially polyamide fibers, by contacting the fiber with a solution of an aliphatic f 4 -4sulfonic acid containing 8 to 24 carbon atoms under acidic conditions.

The present invention, in one aspect, provides a method for imparting to fibrous polyamide materials stain resistance to acid colorants comprising contacting the fibrous polyamide materials with an aqueous treating solution comprising polymethacrylic acid, copolymers of methacrylic acid, or combinations thereof, and drying said substrate, said polymethacrylic acid, copolymers of methacrylic acid, or combinations thereof being provided in a sufficient amount and having a solubility and molecular weight such that said fibrous polyamide substrate has an I" improved acid colorant stain resistance. Generally, a o .rating of at least 5 is satisfactory, a rating of 7 is good, S 15 and a rating of 8 is excellent when the treated substrate is tested according to the test method set forth hereinafter, which test method challenges the substrate with an aqueous solution of FD&C Red Dye No. 40, a common stain test solution.

The present invention, in another aspect, provides o fibrous polyamide substrates treated with an aqueous *a treating solution comprising polymethacrylic acij, copolymers of methacrylic acid, or combinations thereof, said polymethacrylic acid, copolymers of methacrylic acid, or combinations thereof being provided in a sufficient amount and having a solubility and molecular weight such 0. that said fibrous polyamide substrate has an improved acid colorant stain resistance. Generally, a rating of at least is satisfactory, a rating of 7 is good, and a rating of 8 is excellent.

i The present invention, in a further aspect, provides an aqueous solution useful in imparting stain resistance to acid colorants to fibrous polyamide materials, the solution comprising polymethacrylic acid, copolymers of methacrylic acid, or combinations thereof,said polymethacrylic acid, copolymers of methacrylic acid, or combinations thereof being provided in a sufficient amount and having a solubility and molecular weight such that said

_I

I I i i t r 11111 solution is capable of providing said fibrous polyamide substrate with an improved acid colorant stain resistance.

Generally, a rating of at least 5 is satisfactory, a rating of 7 is good, and a rating of 8 is :cellent.

The FIG. shows a photograph of carpet samples tested for stain resistance according to the test method set forth hereinafter.

The polymethacrylic acid, copolymers of methacrylic acid, or combinations thereof useful in the present invention are preferably hydrophilic. As used herein, the term "methacrylic polymer", is intended to include the polymethacrylic acid homopolymer as well as polymers formed from methacrylic acid and one or more other monomers. The monomers useful for copolymerization with the methacrylic acid are monomers having ethylenic unsaturation. Such monomers include, for example, monocarboxylic acids, polycarboxylic acids, and anhydrides; substituted and unsubstituted esters and amides of carboxylic acids and anhydrides; nitriles; vinyl monomers; vinylidene monomers; monoolefinic and polyolefinic monomers; 'and heterocyclic monomers.

Representative monomers include, for example, acrylic acid, itaconic acid, citraconic acid, aconitic acid, maleic acid, maleic anhydride, fumaric acid, crotonic acid, cinnamic acid, oleic acid, palmitic acid, vinyl sulfonic acid, vinyl phosphonic acid, alkyl or cycloalkyl esters of the foregoing acids, the alkyl or cycloalkyl groups having 1 to 18 carbon atoms such as, for example, ethyl, butyl, 2-ethylhexyl, octadecyl, 2-sulfoethyl, acetoxyethyl, cyanoethyl, hydroxyethyl and hydroxypropyl acrylates and methacrylates, and amides of the foregoing acids, such as, for example, acrylamide, methacrylamide, methylolacrylamide, and 1,1-dimethylsulfoethylacrylamide, acrylonitrile, methc.crylonitrile, styrene, a-methylstyrene, p-hydroxystyrene, chlorostyrene, sulfostyrene, vinyl alcohol, N-vinyl pyrrolidone, vinyl acetate, vinyl chloride, vinyl ethers, vinyl sulfides, vinyl toluene, butadiene, isoprene, chloroprene, ethylene, isobutylene, vinylidene ft -6chloride, sulfated castor oil, sulfated sperm oil, sulfated soybean oil, and sulfonated dehydrated castor oil.

SParticularly useful monomers include, for example, alkyl acrylates having 1-4 carbon atoms, itaconic acid, sodium sulfostyrene, and sulfated castor oil. Of course, mixtures of the monomers, such as, for example, sodium sulfostyrene and styrene, and sulfated castor oil and acrylic acid, can be copolymerized with the methacrylic acid.

The methacrylic polymers useful in the present invention can be prepared using methods well-known in the art for polymerization of ethylenically unsaturated monomers.

i ji -i i 1 i i i i E f j

J

f itt t tI I Preferably, the methacrylic acid comprises about to 100 weight percent, more preferably 60 to 90 weight percent, of the methacrylic polymer. The optimum proportion of methacrylic acid in the polymer is dependent on the comonomer used, the molecular weight of the polymer, and the pH at which the material is applied. When water-insoluble comonomers, such as ethyl acrylate are copolymerized with 20 the methacrylic acid, they may comprise up to about weight percent of the methacrylic polymers. When water-soluble monomers, such as acrylic acid or sulfoethyl acrylate are copolymerized with the methacrylic acid, the water-soluble comonomers preferably comprise no more Than weight percent of the methacrylic polymer and preferably the methacrylic polymer also comprises up to about 50 weight percent water-insoluble monomer.

Generally, the methacrylic polymer should be sufficiently water-soluble that uniform application and 30 penetration of the polymer into the fiber surface can be achieved. However, when the polymer is excessively water soluble, acid colorant stain resistance and durability to cleaning may be reduced.

The glass transition temperature of the polymer can be as low as about 35 0 C, although higher glass transition temperatures are preferred. When polymer having high glass transition temperatures, as high as 230 0

C

or higher, are used, an additional benefit of improved soil ii 1 1

~-I

-7resistance of the fibrous polyamide substrate can be obtained.

The weight average molecular weight and the number average molecular weight of the methacrylic polymer should be such that satisfactory stain resistance is provided by the polymer. Generally, the lower 90 weight percent of the polymer material preferably has a weight average molecular weight in the range of about 2500 to 250,000, more preferably in the range of about 3000 to 100,000.

Generally, the lower 90 weight percent of the polymer material preferably has a number average molecular weight in the range of about 500 to 20,000, more preferably in the range of about 800 to 10,000. Generally, more water-soluble comonomers are preferred when the molecular weight of the polymer is high and less water-soluble or water-insoluble comonomers are preferred when the molecular weight of the Spolymer is low.

,r Commercially available methacrylic polymers generally useful in the present invention include Leukotan T M 970, Leukotan TM 1027, "Leukotan T M 1028, and Leukotan TM

QR

1083, available from Rohm and Haas Co.

The amount of the methacrylic polymer used should be sufficient to provide the desired degree of stain resistance to the polyamide substrate. Generally, when the substrate is nylon 66, lower application levels can be used than when the substrate is nylon 6 or wool. When the Spolyamide material is heat-set carpet yarn, yarn heat-set under moist conditions, in an autoclave, generally requires higher application levels than yarn heat-set under substantially dry conditions. Preferably, the amount of methacrylic polymer used is at least about 0.1 weight percent, more preferably at least about 0.5 weight percent, most preferably at least about 1 weight percent, based on the weight of the fiber when the fiber is nylon 66 carpet fiber. Preferably, the amount of methacrylic polymer used is at least about 0.5, more preferably at least about 1 weight percent, based on the weight of the fiber when treating nylon 6 carpet fiber.

-8- Generally, the methacrylic polymer is applied from an aqueous solution. The pH of the solution is preferably below about 7, more preferably below about 5. Generally, amounts of methacrylic polymer in excess of 3 weight percent on weight of fiber provide little added benefit and may cause the fiber to have a harsh hand.

The methacrylic polymer can be applied from an aqueous exhaust bath such as is used in beck dyeing of carpet. The methacrylic polymer can be added to the aqueous dye bath solution and exhausted concurrently with the dye. Generally, the dye bath is maintained at a temperature at or near the boiling point for a period of 10 to 90 minutes or more to effect exhuastion of the dye and the methacrylic polymer.

Alternatively, the methacrylic polymer can be added to the aqueous dye bath after exhaustion of the dye or the dye bath can be drained and fresh water added prior to the addition of the methacrylic polymer.

i: 15 Generally, the bath is maintained at a temperature at or near boiling for a period of time sufficient to exhaust the methacrylic polymer, usually 10 to 90 minutes.

The methacrylic polymer can be applied during continuous dyeing, such as with KusterTM or OttingTM carpet dyeing equipment. The methacrylic polymer can be added directly to the aqueous dye solution and the solution is conventionally applied to the polyamide carpet.

Alternatively, the methacrylic polymer can be applied during a wetting out step prior to application of the dye.

S, The methacrylic polymer can also be applied to polyamide material by a padding operation. This can be done as a separate step or in i conjunction with the application of various convention finishes such as S wetting agents, softeners, and leveling agents. After application of the solution, the polyamide material is conventionally dried.

SThe methacrylic polymer can also be applied by foam techniques which are well-known in the art. Generally, the methacrylic polymer is applied from an aqueous solution which may further contain a foaming f agent. The foaming agents used are those typically used in foam dyeing.

6h -9- The methacrylic polymer can also be applied to polyamide fabrics by other methods well known to those skilled in the art. Other suitable methods include application by padding, low-pressure padding such as can be accomplished with Kuster Flexnip TM equipment, spray applicators such as those available from Otting International, or dip boxes which need not be equipped with moisture reduction apparatus such as squeeze rolls. The methacrylic polymer is generally applied in these methods from an aqueous solution at ambient conditions followed by steaming for from 15 to 180 seconds, then drying or from an aqueous solution at elevated temperatures, 60 0 C to 900C, followed by skying for 15 to 180 seconds, then drying.

The methacrylic polymer can also be applied to nylon carpet during carpet shampooing. Useful techniques include the use of scrubbing machines and steam or hot water cleaning machines.

1 5 Fluorochemical compositions for providing oil and water repellency can also be applied in conjunction with the methacrylic polymer. The fluorochemical composition can be added in an appropriate amount to the treating solution.

The following non-.limiting examples serve to illustrate the invention. In the following examples, all ratios are by weight and ,,percentages are weight percent unless otherwise indicated.

In the examples, the following staining test was used: A 6.5 g test sample of carpet, which has been dyed using a blue disperse dye with a 45 minute beck dyeing cycle, is immersed in 40 g of an aqueous solution containing 0.008 weight percent FD&C Red Dye No. 40 and 0.04 weight percent citric acid. The solution is allowed to remain on the test sample for eight hours at room temperature, about 22 0 C, The sample is rinsed under running tap water, dried and then evaluated for staining using a graduated rating scale which ranges from a stain resistance of 1 to 8, as shown in the drawing where 1 represent O no discernible removal of the red dye stain and 8 represents ,;,plete removal of the red dye stain. In general, an eight-hour stain resistance of at least 5 is satisfactory, at least 7 is good, and 8 is excellent. In the RL 356h RL 356h specification and claims the term "stain resistance" means a stain resistance in accordance with this test. The term "resistance to staining" has a corresponding meaning. Preparation of methacrylic polymer (Polymer A): To a reaction vessel equipped with a reflux condenser, a mechanical stirrer, and a thermometer, were charged 14 g sulfated castor oil solids) and 95 g deionized water. This solution was heated to 90 0 C and 1.2 g ammonium persulfate were added. To this solution were added simultaneously dropwise 47.6 g methacrylic acid, 11.9 q acrylic acid, and 5 g ammonium persulfate in 55 g water over a period of about 1 hour. The reaction mixture was further stirred for 90 minutes at 90 0 C and then cooled to 50 0 C. The resultant copolymer solution was partially neutralized to pH 4.3 by the addition of 9.7 g 50% aqueous sodium hydroxide. The resultant product contained 39.3% copolymer solids.

Polymers B through K were prepared using a procedure similar to that used in the preparation of Polymer A using the monomers and reactant S. ratios set forth in Table 1.

i t t Table 1 Table 1 Polymer

A

00 00 OQ ft 00 0o 00 00 0 0 *;ooo a c c o 0 Dc o 00 e 0 o oC Reactant(s) methacrylic acid sulfonated castor oil acrylic acid methacrylic acid methacrylic acid ethyl acrylate methacrylic acid ethyl acrylate methacrylic acid ethyl acrylate methacrylic acid sulfated castor oil methacrylic acid sodium sulfostyrene styrene methacrylic acid sulfated castor oil ethyl acrylate methacrylic acid sulfated castor oil acrylic acid acrylic acid acrylic acid ethyl acrylate Reactant ratio 68 17 100 84 16 81 9 68 17 100 o o0 0 0 00 0 0 0 o 0 o3 o0 0 0 0 o Polymer L was prepared by placing in a bottle 46 Q water, 8 g methacrylic acid, 2 g sodium sulfostyrene, 0.3 g mercapto propionic acid, without regard to order, and finally 0.3 g potassium persulfate. The bottle was evacuated and purged three times with nitrogen. The bottle cap was tightened and the bottle placed in a weter bath having a temperature of 72°C under agitation for a period of 16 hours. The resulting polymer solution was clear and fluid with a polymer solids content of 19 weight percent.

Polymers M through Q were prepared using a procedure similar to that used in the preparation of Polymer -12- SL using the monomers and reactant ratios set forth in Table 2.

Table 2 Methacrylic Polymer

L

Reactant Reactants ratio methacrylic acid sodium sulfostyrene methacrylic acid sodium sulfostyrene methacrylic acid itaconic acid methacrylic acid vinyl acetate methacrylic acid 1,l-dimethylsulfoethylacrylamide methacrylic acid hydroxyethyl acrylate

I

,y

I

I, 4 *r 4 1$ I I e I i i 4* SIt 1 I Polymer R was prepared using the procedure used to prepare Polymer M except that the following ingredients were used: 92 g water, 16 g methacrylic acid, 2 g sodium sulfostyrene, 2 g styrene, 0.6 g mercapto propionic acid, 0.6 g sodium dodecyl benzene sulfonate, without regard to order, and finally 0.6 g ammonium persulfate. Polymer S was prepared according to the procedure set forth in Example 1 of U.S. Patent No. 4,081,383 The weight average molecular weight (Mw) and the number average molecular weight (Mn) of the lower 90 weight percent of various of the thus-prepared polymers were determined using a column bank having four Ultrahydrogel columns, linear, 1000, 500, and 250, available from Waters Assoc. and polyacrylic acid standards available from American Polymer Standards Company. The results are set forth in Table 3.

Table 3 ft i i -13- Polymer

B

C

D

E

F

H

J

K

S

Mw 8,100 85,500 58,000 2,920,000 5,820 8,470 5,830 36,611 532,000 Mn 2,680 3,380 3,430 414,000 2,460 3,410 1,331 5,490 47,634 t ,a 9 9w 99 9 99.9 9 99 9* 9 99 4 t 9 9 99i The weight average molecular weight and the number 15 average molecular weight of the lower 90 weight percent of several commercially available methacrylic acid-based polymers, Leukotan T M 970, Leukotan 1027, Leukotan M 1028, and Leukotan QR 1083, all available from Rohm and Haas Co.

and an acrylic acid-based polymer, Leukotan

T

LP 1042, also 20 available from Rohm and Haas Co., were also determined. The results are set forth in Table 4.

'9 9 I t Table 4 in

I

it Fi 1 ji ;1i r i Polymer Mw Leukotan

T

970 6,360 LeukotanT 1027 9,020 Leukotan T M 1028 9,460 Leukotan TM QR 1083 5,280 Leukotan T M LP 1042 2,560 Mn 2,320 2,910 5,592 1,410 1,400 9 9* st 4t -14- Examples 1-14 and Comparative Examples C1-C4 In Example 1, a treating solution was prepared containing 0.35 g Polymer A-solids in 92 g water with the pH adjusted to 4.0 using 20% aqueous formic acid. To simulate a continuous treatment process, the treating solution was poured into a dye press and heated to 80 0 C. A 23 g sample of dyed carpet prepared using nylon 6 fiber, available from BASF, which had been heat set under moist conditions was steamed for 2 minutes and then immersed in the treating solution for 1 minute with pressure being applied to ensure thorough penetration of the treating solution. The treated sample was put through squeeze rollers at 30 psi to remove excess liquid and then dried at 70 0 C for 45 minutes and 130°C for 10 minutes.

S, In Examples 2-14 and Comparative Examples Cl-C4, nylon 6 carpet samples were prepared and treated as in Example 1 except the polymers used were as set forth in Table Each sample was evaluated for stain resistance, the results being set forth in Table r -1 Table *t 4 p r*

I

II .9 p 9 9r 9r I 194* Stain Example Polymer resistance 1 A 7 2 B 6 3 C 7 4 D 7 F 7 6 G 7 7 H 8 8 I 7 9 L 6 N 6 15 11 12 Q 13 R 7 14 P C1 E 3 C2 J 2 C3 K 2 C4 M 4 As can be seen from the data in Table 5, the polymers of the invention (Examples 1-14) provide satisfactory to excellent stain resistance to the moist heat-set nylon 6 carpet samples. Of the Comparative Examples, Comparative Example Cl which was treated with a high molecular weight methacrylic acid-based copolymer and Comparative Examples C2 and C3 which were treated with polyacrylic acid and an acrylic acid copolymer, respectively exhibit particularly poor stain resistance.

Examole 15 and Comparative Examples C5 and C6 Carpet samples were prepared as in Example 1 using carpet prepared from the moist heat-set nylon 6 fiber exce'pt that the samples were treated with the following commercially available polymers: Example 15 Leukota,

R

-16- 970, a methacrylic acid-based polymer, available from Rohm and Haas Co.; Comparative Example C5 Leukotan T LP 1042, an acrylic acid-based polymer, available from Rohm and Haas Co.; and Comparative Example C6 Acrysol RM-5, an acrylic acid-based monomer, available from Rohm and Haas Company.

Each sample was tested for stain resistance. The results are set forth in Table 6.

Table 6 Stain Example resistance 7 3 C6 2 fit# As can be seen from the data in Table 6, the t TM methacrylic acid-based Leukotan™ 970 provided good stain resistance, while the acrylic acid-based Leukotan "LP 1042 and Acrysol RM-5 provided very little stain resistance.

Comparative Examples C7 and C8 In Comparative Example C7, a polymer of methacrylic acid, styrene, and methyl methacrylate was II prepared substantially following the teachings of U.S.

Patent No. 4,081,383 (Warburton, Jr. et Example 1.

A mixture of 69 parts methacrylic acid, 27 parts o. styrene and 5 parts methyl methacrylate was added to parts of water containing 0.07 parts of 80% active isopropylbenzenehydroperoxide, 1.13 parts sodium dodecylbenzenesolfonate, 0.0375 parts of the sodium salt of ethylene diamine tetraacetic acid, and 0.0135 parts if FeSO 4 .7H0. The resulting emulsion was degassed by stirring under nitrogen for 30 minutes. Then, 0.0104 parts of sodium sulfoxylate formaldehyde in 1.15 parts of water was added.

The temperature rose from 24 0 C to 50 0 C over 18 minutes.

Then 0.08 parts of 80% active isopropylbenzenehydroperoxide and 0.0104 parts of sodium sulfoxylate formaldehyde in 1.15 i4 -17parts water were added. The lower 90 weight percent of the resulting polymer had a weight average molecular weight of i| 532,000 and a number average molecular weight of 47,600.

SA carpet sample was prepared as in Example 1 using carpet prepared from the moist heat-set nylon 6 fiber except that the sample was treated with the above-prepared SWarburton, Jr. et al. polymer. The sample was tested for stain resistance and received a rating of only 2, showing poor stain resistance.

In Comparative Example C8, 200 parts of the above-prepared polymer as a 20% .olids aqueous solution were added to a WaringTm blender and agitated. Epoxy resin (DER 736, available from Dow Chemical Company) was then added (8 parts) slowly over several minutes. The blend was diluted to 23% solids.

A carpet sample was prepared as in Example 1 using carpet prepared from the moist heat-set nylon 6 fiber except that the sample was treated with the above-prepared copolymer/epoxy resin. The sample was tested for stain resistance and received a rating of only 2, showing poor stain resistance.

Examples 16-18 In Example 16, a solution containing 75 g/l j Leukotan

T

M 970, and 10 g/l Alkafoam D, a foaming agent available from Alkaril Chemicals, Inc., was prepared and foamed onto a sample of carpet prepared from nylon 66 yarn heat set under moist conditions using a Gaston County laboratory FFT model foam finishing machine, available from Gaston County Dyeing Machine Company, using a 60:1 blow ratio and a wet pickup rate of 20% to provide an application rate of 0.5% LeukotanTM 970 based on the weight of the carpet. The sample was dried at 10° 0 C for 20 minutes.

In Examples 17 and 18, carpet samples were treated as in Example 15 except Polymer H and Polymer C, respectively were substituted for the LeukotanTM 970.

The treated samples were tested for stain o. -18resistance. The results are set forth in Table 7.

Table 7 Stain Example resistance 16 17 7 18 As can be seen 'from the data in Table 7, the polymers of the invention provide adequate to good stain resistance to nylon carpet prepared from moist heat-set nylon 66 carpet fiber.

Examples 19-22 and Comparative Examples C9-C11 i i -i 'In Example 19, a treating bath was prepared containing 0.69 g Polymer B solids in 690 g water with the pH adjusted to 3.5 using 20% aqueous formic acid. A 23 g sample of dyed carpet prepared using nylon 6 fiber, available from BASF, which had been heat set under moist conditions was steamed for 2 minutes and then placed in the treating bath. Under agitation, the temperature was raised to 70 0 C over 30 minutes and held at 70°C for 15 minutes.

The sample was removed from the bath, put through squeeze rolls at 30 psi, and then dried at 70°C for 45 minutes and 130°C for 10 minutes.

In Examples 20-22 and Comparative Examples C9-Cll, samples of carpet were treated as in Example 19 except the polymer set forth in Table 8 were substituted for Polymer B.

The treated samples were tested for stain resistance. The results are set forth in Table 8.

Table 8 Example Polymer Stain resistance -19-

B

H

Leukotan T 970

C

Epoxy resin blend of Example C12

K

Acrysol RM-5 8 7 2 2 Cll As can be seen from the data in Table 8, the methacrylic polymers provide excellent stain resistance.

The polymer/epoxy resin blend of Warburton, Jr. et al. and the acrylic acid-based polymers provide little stain resistance.

Examples 23-25 i ;i i+i In Examples 23-25, carpet samples were treated as in Example 1 except that Leukotan T 1027, Leukotan 1028, and Leukotan" QR 1083, respectively, each a methacrylic acid-based polymer available from Rhom and Haas Co., were substituted for Polymer A. The treated samples were tested for stain resistance. The results are set forth in Table 9.

Table 9 tt t 1 Example 23 24 0 *t As can be seen from the data in Table 9, the Leukotan T M QR 1083 provided better than satisfactory stain resistance, while the Leukotan M 1027 and the Leukotan

T

1028 provided good stain resistance.

Examples 26-28 and Comparative Examples C12-C14 I- j 1 In Example 26, a treating bath was prepared containing 0.2 g Polymer B in 80 g water with pH adjusted to using 20% aqueous formic acid. A 20 g sample of dyed carpet prepared using nylon 66 fiber which had been heat set under dry conditions was steamed for 2 minutes and then placed in the treating bath. Under agitation, the temperature was raised to 70 0 C over 30 minutes and held at 0 C for 15 minutes. The sample was removed from the bath, rinsed, put through squeeze rolls at 30 psi, and then dried at 70°C for 45 minutes and 130 0 C for 10 minutes.

In Examples 27-28 and Comparative Examples C12-C14, samples of carpet were treated as in Example 26 except the polymers set forth in Table 10 were substituted for Polymer B.

The treated samples were tested for stain resistance. The results are set forth in Table Table Stain Example Polymer resistance 26 B 8 27 C 8 28 H 8 C12 Polymer of Example C8 4 Ci 13 J 2 C14 K 3 As can be seen from the data in Table methacrylic polymers of the invention provide greater stain resistance than do acrylic acid-based polymers (Comparative Examples C13 and C14) when applied on nylon 66 carpet fiber.

Further, the methac:ylic acid copolymer used in Comparative Example C12 performs unsatisfactorily d .P to its high molecular weight.

The various modifications and alterations of this invention will be apparent to those skilled in the art without departing from the scope and spirit of this invention and this invention should not be restricted to S-21that set forth herein for illustrative purposes.

i 1

Claims

1. A method for imparting to nylon carpet stain resistance to acid colorants comprising contacting the nylon carpet with an aqueous treating solution comprising polymethacrylic acid, copolymers of methacrylic acid or combinations thereof, and drying said nylon carpet, said copolymers of methacrylic acid comprise at least about 30 weight percent methacrylic acid and said polymethacrylic acid, copolymers of I methacrylic acid or combinations thereof having the lower 90 weight percent having a weight average molecular weight in the range of about 2500 to 250,000 and a number average molecular weight in the range of about 500 to 20,000 and being provided in a sufficient amount and having a solubility such that said nylon carpet has an acid colorant stain resistance (as defined herein) of at least

2. The method of claim 1 wherein said aqueous treating solution comprises polymethacrylic acid.

3. The method of claim 1 wherein copolymer is a copolymer of methacrylic acid and a comonomer which is a monocarboxylic acid, a polycarboxylic acid, an anhydride, a substituted or unsubstituted ester r or amide of a carboxylic acid or anhydride, a nitrile, a vinyl monomer, a S 20 vinylidene monomer, a monoolefinic or polyolefinic monomer, a heterocyclic monomer, or combination thereof.

4. The method of claim 3 wherein said comonomer is alkyl acrylate having 1-4 alkyl carbon atoms, itaconic acid, sodium sulfostyrene, or sulfated caster oil.

5. The method of claim 3 wherein said copolymer is a terpolymer of methacrylic acid, sodium sulfostyrene, and styrene; methacrylic acid, K sulfated caster oil, and acrylic acid; and methacrylic acid, ethyl acrylate, and sulfated castor oil.

6. The method of claim 1 wherein said nylon carpet is nylon 66 fiber and said polymethacrylic acid and/or said copolymers of methacrylic acid are present in an amount of at least about 0.1 weight percent based on the weight of the nylon carpet.

7. The method of claim 1 wherein said nylon carpet is nylon 6 fiber and said polymethacrylic acid and/or said copolymers of methacrylic acid are present In an amount of at least about 0.5 weight percent based on the weight of the nylon carpet. RLF/1356h i~lYiCCI~liylrXt--- ii i -23-

8. Nylon carpet treated with an aqueous treating solution comprising polymethacrylic acid, copolymers of methacrylic acid or combinations thereof, said copolymers of methacrylic acid comprise at least about 30 weight percent methacrylic acid and said polymethacrylic acid, copolymers of methacrylic acid or combinations thereof having the lower 90 weight percent having a weight average molecular weight in the range of about 2500 to 250,000 and a number average molecular weight in the range of about 500 to 20,000 and being provided in a sufficient amount and having a solubility such that said nylon carpet has an acid colorant stain resistance (as defined herein) of at least

9. An aqueous treating composition for imparting to nylon carpet resistance to staining by acid colorants, which comprises water-soluble polymer comprising about 30 to 100 weight percent polymerized methacrylic acid such that the lower 90 weight percent thereof has a weight average molecular weight in the range of about 2500 to 250,000 and a number average molecular weight in the range of about 500 to 20,000, in a sufficient amount to impart an acid colorant stain resistance (as defined herein) of at least 5 when applied from aqueous solution to nylon carpet fiber in an applied amount up to about 3 weight percent based on the weight of the fiber, and sufficient water to dissolve said polymeric component and provide an aqueous solution suitable for effective application to nylon carpet fiber.

The treating solution of claim 9 wherein the polymer is prepared by polymerizing methacrylic acid.

11. The treating solution of claim 10 wherein the methacrylic acid Sis copolymerized with up to 40 percent by weight of the polymer of a water-insoluble comonomer. i,

12. The treating solution of claim 10 wherein the methacrylic acid is copolymerized with up to 30 percent by weight of the polymer of a water-soluble comonomer.

13. A method for Imparting to fibrous polyamide materials stain resistance to acid colorants, said method being substantially as described herein with reference to any one of the Examples other than comparative examples. ?,AL 1 1 RF/1356h RLF/1356h -24- \4,15. A fibrous polyamide substrate treated with an aqueous treating solution to impart stain resistance (as defined herein) to acid colorants li substantially as described herein with reference to any one of the Examples other than comparative examples. An aqueous treating composition for imparting to nylon carpet resistance to staining (as defined herein) by acid colorants substantially as described herein with reference to any one of the Examples other than comparative examples. DATED this SEVENTH day of JUNE 1991 Minnesota Mining and Manufacturing Company Patent Attorneys for the Applicant SPRUSON FERGUSON I RLF/ RLF/1356h 4