AU2021340009A1 - Lubricating oil containing alkyl phosphonic acid - Google Patents
Lubricating oil containing alkyl phosphonic acid Download PDFInfo
- Publication number
- AU2021340009A1 AU2021340009A1 AU2021340009A AU2021340009A AU2021340009A1 AU 2021340009 A1 AU2021340009 A1 AU 2021340009A1 AU 2021340009 A AU2021340009 A AU 2021340009A AU 2021340009 A AU2021340009 A AU 2021340009A AU 2021340009 A1 AU2021340009 A1 AU 2021340009A1
- Authority
- AU
- Australia
- Prior art keywords
- lubricating oil
- oil composition
- wear
- lubricating
- succinimide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000010687 lubricating oil Substances 0.000 title claims abstract description 53
- -1 alkyl phosphonic acid Chemical compound 0.000 title claims description 39
- 239000000203 mixture Substances 0.000 claims abstract description 75
- 239000003921 oil Substances 0.000 claims abstract description 31
- 230000001050 lubricating effect Effects 0.000 claims abstract description 12
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 69
- 229960002317 succinimide Drugs 0.000 claims description 39
- 239000000654 additive Substances 0.000 claims description 24
- 239000002270 dispersing agent Substances 0.000 claims description 24
- 239000012530 fluid Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 230000005540 biological transmission Effects 0.000 claims description 17
- 239000003112 inhibitor Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 229920002367 Polyisobutene Polymers 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 239000006078 metal deactivator Substances 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 5
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 5
- 239000007866 anti-wear additive Substances 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 239000012208 gear oil Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims 3
- 125000000101 thioether group Chemical group 0.000 claims 3
- 235000019198 oils Nutrition 0.000 description 27
- 229920000768 polyamine Polymers 0.000 description 17
- 239000002199 base oil Substances 0.000 description 14
- 229910052698 phosphorus Inorganic materials 0.000 description 12
- 239000011574 phosphorus Substances 0.000 description 12
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 9
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 8
- 229940014800 succinic anhydride Drugs 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
- 235000010338 boric acid Nutrition 0.000 description 5
- 229960002645 boric acid Drugs 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 239000010705 motor oil Substances 0.000 description 5
- 229920001281 polyalkylene Polymers 0.000 description 5
- 229920013639 polyalphaolefin Polymers 0.000 description 5
- 231100000241 scar Toxicity 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003879 lubricant additive Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- NJGCRMAPOWGWMW-UHFFFAOYSA-N octylphosphonic acid Chemical compound CCCCCCCCP(O)(O)=O NJGCRMAPOWGWMW-UHFFFAOYSA-N 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 239000010775 animal oil Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- UOKRBSXOBUKDGE-UHFFFAOYSA-N butylphosphonic acid Chemical compound CCCCP(O)(O)=O UOKRBSXOBUKDGE-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000005676 cyclic carbonates Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- FTMKAMVLFVRZQX-UHFFFAOYSA-N octadecylphosphonic acid Chemical compound CCCCCCCCCCCCCCCCCCP(O)(O)=O FTMKAMVLFVRZQX-UHFFFAOYSA-N 0.000 description 2
- 150000005677 organic carbonates Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical class OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- FPYLHOQPWCQAIJ-UHFFFAOYSA-N 1-dimethoxyphosphoryloctadecane Chemical compound CCCCCCCCCCCCCCCCCCP(=O)(OC)OC FPYLHOQPWCQAIJ-UHFFFAOYSA-N 0.000 description 1
- PAOXFRSJRCGJLV-UHFFFAOYSA-N 2-[4-(2-aminoethyl)piperazin-1-yl]ethanamine Chemical compound NCCN1CCN(CCN)CC1 PAOXFRSJRCGJLV-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- NPRQLWMILWHEDI-UHFFFAOYSA-N 3-[bis(2-methylpropoxy)phosphinothioylsulfanyl]-2-methylpropanoic acid Chemical compound CC(C)COP(=S)(OCC(C)C)SCC(C)C(O)=O NPRQLWMILWHEDI-UHFFFAOYSA-N 0.000 description 1
- IMVDOKODXPATSJ-UHFFFAOYSA-N 4,4,6-trimethyl-1,3-dioxan-2-one Chemical compound CC1CC(C)(C)OC(=O)O1 IMVDOKODXPATSJ-UHFFFAOYSA-N 0.000 description 1
- PSBYIASEOIPONS-UHFFFAOYSA-N 4,4-diethyl-1,3-dioxolan-2-one Chemical compound CCC1(CC)COC(=O)O1 PSBYIASEOIPONS-UHFFFAOYSA-N 0.000 description 1
- CBMUUDZXMOBDFC-UHFFFAOYSA-N 4,4-dimethyl-1,3-dioxan-2-one Chemical compound CC1(C)CCOC(=O)O1 CBMUUDZXMOBDFC-UHFFFAOYSA-N 0.000 description 1
- PUEFXLJYTSRTGI-UHFFFAOYSA-N 4,4-dimethyl-1,3-dioxolan-2-one Chemical compound CC1(C)COC(=O)O1 PUEFXLJYTSRTGI-UHFFFAOYSA-N 0.000 description 1
- UAUBPLHWJOYCHE-UHFFFAOYSA-N 4,5-diethyl-1,3-dioxolan-2-one Chemical compound CCC1OC(=O)OC1CC UAUBPLHWJOYCHE-UHFFFAOYSA-N 0.000 description 1
- LWLOKSXSAUHTJO-UHFFFAOYSA-N 4,5-dimethyl-1,3-dioxolan-2-one Chemical compound CC1OC(=O)OC1C LWLOKSXSAUHTJO-UHFFFAOYSA-N 0.000 description 1
- UHIIHYFGCONAHB-UHFFFAOYSA-N 4,6-dimethyl-1,3-dioxan-2-one Chemical compound CC1CC(C)OC(=O)O1 UHIIHYFGCONAHB-UHFFFAOYSA-N 0.000 description 1
- JFMGYULNQJPJCY-UHFFFAOYSA-N 4-(hydroxymethyl)-1,3-dioxolan-2-one Chemical compound OCC1COC(=O)O1 JFMGYULNQJPJCY-UHFFFAOYSA-N 0.000 description 1
- LSUWCXHZPFTZSF-UHFFFAOYSA-N 4-ethyl-5-methyl-1,3-dioxolan-2-one Chemical compound CCC1OC(=O)OC1C LSUWCXHZPFTZSF-UHFFFAOYSA-N 0.000 description 1
- OVDQEUFSGODEBT-UHFFFAOYSA-N 4-methyl-1,3-dioxan-2-one Chemical compound CC1CCOC(=O)O1 OVDQEUFSGODEBT-UHFFFAOYSA-N 0.000 description 1
- OLIXNCIBAPPVBV-UHFFFAOYSA-N 5,5-bis(hydroxymethyl)-1,3-dioxan-2-one Chemical compound OCC1(CO)COC(=O)OC1 OLIXNCIBAPPVBV-UHFFFAOYSA-N 0.000 description 1
- JJCRWNPMISIXJF-UHFFFAOYSA-N 5,5-diethyl-1,3-dioxan-2-one Chemical compound CCC1(CC)COC(=O)OC1 JJCRWNPMISIXJF-UHFFFAOYSA-N 0.000 description 1
- JRFXQKZEGILCCO-UHFFFAOYSA-N 5,5-dimethyl-1,3-dioxan-2-one Chemical compound CC1(C)COC(=O)OC1 JRFXQKZEGILCCO-UHFFFAOYSA-N 0.000 description 1
- PLUWZRLTLOFZTP-UHFFFAOYSA-N 5-(hydroxymethyl)-5-methyl-1,3-dioxan-2-one Chemical compound OCC1(C)COC(=O)OC1 PLUWZRLTLOFZTP-UHFFFAOYSA-N 0.000 description 1
- DQIGFEWVGQCCTN-UHFFFAOYSA-N 5-hydroxy-1,3-dioxan-2-one Chemical compound OC1COC(=O)OC1 DQIGFEWVGQCCTN-UHFFFAOYSA-N 0.000 description 1
- FIURNUKOIGKIJB-UHFFFAOYSA-N 5-methyl-1,3-dioxan-2-one Chemical compound CC1COC(=O)OC1 FIURNUKOIGKIJB-UHFFFAOYSA-N 0.000 description 1
- QPAWSFWKAUAJKW-UHFFFAOYSA-N 5-methyl-5-propyl-1,3-dioxan-2-one Chemical compound CCCC1(C)COC(=O)OC1 QPAWSFWKAUAJKW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WSNMPAVSZJSIMT-UHFFFAOYSA-N COc1c(C)c2COC(=O)c2c(O)c1CC(O)C1(C)CCC(=O)O1 Chemical compound COc1c(C)c2COC(=O)c2c(O)c1CC(O)C1(C)CCC(=O)O1 WSNMPAVSZJSIMT-UHFFFAOYSA-N 0.000 description 1
- 208000032544 Cicatrix Diseases 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- OTRAYOBSWCVTIN-UHFFFAOYSA-N OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N Chemical compound OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N OTRAYOBSWCVTIN-UHFFFAOYSA-N 0.000 description 1
- BKIFLZBXPJKAJF-UHFFFAOYSA-N OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N Chemical compound OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N BKIFLZBXPJKAJF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- NTBYNMBEYCCFPS-UHFFFAOYSA-N azane boric acid Chemical class N.N.N.OB(O)O NTBYNMBEYCCFPS-UHFFFAOYSA-N 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- NOXNXVPLDITALF-UHFFFAOYSA-N butoxyboronic acid Chemical compound CCCCOB(O)O NOXNXVPLDITALF-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- DZQISOJKASMITI-UHFFFAOYSA-N decyl-dioxido-oxo-$l^{5}-phosphane;hydron Chemical compound CCCCCCCCCCP(O)(O)=O DZQISOJKASMITI-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- AUTNMGCKBXKHNV-UHFFFAOYSA-P diazanium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [NH4+].[NH4+].O1B([O-])OB2OB([O-])OB1O2 AUTNMGCKBXKHNV-UHFFFAOYSA-P 0.000 description 1
- GTYLWUZKRJYAJZ-UHFFFAOYSA-N dibutoxyborinic acid Chemical compound CCCCOB(O)OCCCC GTYLWUZKRJYAJZ-UHFFFAOYSA-N 0.000 description 1
- 239000010710 diesel engine oil Substances 0.000 description 1
- VLSJPRHEVMZIII-UHFFFAOYSA-N diethoxyborinic acid Chemical compound CCOB(O)OCC VLSJPRHEVMZIII-UHFFFAOYSA-N 0.000 description 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 1
- CXVAUNIKYTWEFC-UHFFFAOYSA-N dimethoxyborinic acid Chemical compound COB(O)OC CXVAUNIKYTWEFC-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical group 0.000 description 1
- VBMSSIXNKVFLAJ-UHFFFAOYSA-N dipropoxyborinic acid Chemical compound CCCOB(O)OCCC VBMSSIXNKVFLAJ-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- KUGSJJNCCNSRMM-UHFFFAOYSA-N ethoxyboronic acid Chemical compound CCOB(O)O KUGSJJNCCNSRMM-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920006213 ethylene-alphaolefin copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010699 lard oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- UYVXZUTYZGILQG-UHFFFAOYSA-N methoxyboronic acid Chemical compound COB(O)O UYVXZUTYZGILQG-UHFFFAOYSA-N 0.000 description 1
- WBIWIXJUBVWKLS-UHFFFAOYSA-N n'-(2-piperazin-1-ylethyl)ethane-1,2-diamine Chemical compound NCCNCCN1CCNCC1 WBIWIXJUBVWKLS-UHFFFAOYSA-N 0.000 description 1
- LPOUQGUYVMSQOH-UHFFFAOYSA-N n'-[2-(2-piperazin-1-ylethylamino)ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCN1CCNCC1 LPOUQGUYVMSQOH-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- JMVWCCOXRGFPJZ-UHFFFAOYSA-N propoxyboronic acid Chemical compound CCCOB(O)O JMVWCCOXRGFPJZ-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000037387 scars Effects 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000010689 synthetic lubricating oil Substances 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 150000003568 thioethers Chemical group 0.000 description 1
- LGQXXHMEBUOXRP-UHFFFAOYSA-N tributyl borate Chemical compound CCCCOB(OCCCC)OCCCC LGQXXHMEBUOXRP-UHFFFAOYSA-N 0.000 description 1
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 1
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 1
- YFHICDDUDORKJB-UHFFFAOYSA-N trimethylene carbonate Chemical compound O=C1OCCCO1 YFHICDDUDORKJB-UHFFFAOYSA-N 0.000 description 1
- LTEHWCSSIHAVOQ-UHFFFAOYSA-N tripropyl borate Chemical compound CCCOB(OCCC)OCCC LTEHWCSSIHAVOQ-UHFFFAOYSA-N 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/14—Electric or magnetic purposes
- C10N2040/16—Dielectric; Insulating oil or insulators
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
This disclosure describes a zinc-free lubricating oil composition. The composition includes a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm
Description
LUBRICATING OIL CONTAINING ALKYL PHOSPHONIC ACID
TECHNICAL FIELD
[001] This disclosure relates to lubricating oil additives and lubricating oil compositions containing the same. More specifically, this disclosure describes zinc- free additives that impart anti-wear properties to lubricating oil compositions.
BACKGROUND
[002] Zinc dialkyldithiophosphate (ZnDTP) has long been used as a wear inhibitor in various lubricating fluids such as automotive engine oil. At least one drawback is that ZnDTP can decompose due to high temperature, oxidative deterioration, or hydrolysis in the presence of water. The result of the decomposition is a sludge that decreases friction coefficient and/or clogs important moving parts.
[003] When ZnDTP is used in automatic transmission fluids (ATF), the decomposition products can accumulate in the pores of the paper material that forms the wet clutch, which can lead to clogging. Consequently, the cooling performance and durability of the clutch are significantly reduced.
[004] Thus, there exists a need for alternative zinc-free wear inhibitors that can be used in various lubricating fluids.
SUMMARY
[005] In one aspect, there is provided a lubricating oil composition comprising: a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm2/s; and an anti-wear mixture comprising: one or more ashless dispersants and an alkyl phosphonic acid having a structure given by
wherein R is a C3-C20 hydrocarbyl group; initial pH of the anti-wear mixture is between 5.0-9.5 as measured by ASTM D664; and wherein the lubricating oil composition is free of zinc.
[006] In another aspect, there is provided a lubricating oil composition comprising: a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm2/s; and an anti-wear mixture comprising: one or more polyisobutenyl succinimide dispersants and an alkyl phosphonic acid having a structure given by
wherein R is a C3-C20 hydrocarbyl group; initial pH of the anti-wear mixture is between 5.0 - 9.5 as measured by ASTM D664; and wherein the lubricating oil composition is free of zinc.
[007] In yet another aspect, there is provided a method of reducing wear of a transmission or gear comprising: lubricating the transmission or gear with a lubricating oil composition comprising: a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm2/s; and an antiwear mixture comprising: one or more ashless dispersants and an alkyl phosphonic acid of the following formula:
wherein R is a C3-C20 hydrocarbyl group; wherein the initial pH of the anti-wear mixture is between 5.0 - 9.5 when measured by the ASTM D664 method; and wherein the lubricating oil composition is free of zinc.
DETAILED DESCRIPTION
Definitions
[008] The term "succinimide" is understood in the art to indude many of the amide, imide, and amidine species which may be formed by the reaction of a succinic anhydride with an amine. The predominant product, however, is a succinimide and this term has been generally accepted as meaning the product of a reaction of an alkenyl- or alkyl-substituted succinic acid or anhydride with an amine. Alkenyl or alkyl succinimides are disclosed in numerous references and are well known in the art. Certain fundamental types of succinimides and related materials encompassed by the term of art "succinimide" are taught in U.S. Patent Nos. 2,992,708; 3,018,291; 3,024,237; 3,100,673; 3,219,666; 3,172,892; and 3,272,746.
[009] The term "hydrocarbyl" refers to a chemical group or moiety derived from hydrocarbons including saturated and unsaturated hydrocarbons. Examples of hydrocarbyl groups include alkenyl, alkyl, polyalkenyl, polyalkyl, phenyl, and the like.
[010] The terms 'oil-soluble' or 'oil-dispersible' as used herein do not necessarily indicate that the compounds or additives are soluble, dissolvable, miscible or capable of being suspended in the oil in all proportions. These do mean, however, that they are, for instance, soluble or stably dispersible in oil to an extent sufficient to exert their intended effect in the environment in which the oil is employed. Moreover, the additional incorporation of other additives may also permit incorporation of higher levels of a particular additive, if desired.
[011] It is understood that when combinations, subsets, groups, etc. of elements are disclosed (e.g., combinations of components in a composition, or combinations of steps in a method), that while specific reference of each of the various individual and collective combinations and permutations of these elements may not be explicitly disclosed, each is specifically contemplated and described herein.
[012] A dispersant is an essential lubricant additive, particularly in engine oil and automatic transmission fluid, for preventing sludge generation and increasing friction coefficient of wet clutch. However, dispersants can often reduce the effects of
anti-wear agents (e.g., ZnDTP) and extreme pressure (EP) additives particularly in sulfur phosphorus (S-P) type gear oils and automatic transmission fluids.
[013] The present invention describes wear inhibitors (or anti-wear agents) that can impart anti-wear properties to lubricating oil compositions. In some embodiments, the present invention describes a wear inhibitor system comprising a succinimide and a phosphonic acid. The wear inhibitor system of the present invention is zinc-free (present in less than about 10 ppm) and therefore avoids at least some of the performance issues associated with conventional zinc anti-wear agents.
[014] The wear inhibitor system of the present invention may be added to any compatible lubricating oil such as engine oil, hydraulic fluid, slide way lubricant, automatic transmission fluid (ATF), continuously variable transmission (CVT) fluid, battery electric vehicle (BEV), hybrid electric vehicle (HEV) transmission fluid, and gear oil.
Succinimide Dispersants
[015] The succinimide dispersant can be prepared by any known method such as those described in, for example, U.S. Patent Publication No. 20180034635 and U.S. Patent No. 7,091,306, which are hereby incorporated by reference.
[016] In accordance with the present invention, the succinimide is a hydrocarbyl succinimide obtained as the product of a reaction of alkyl -substituted succinic anhydrides with a polyamine. In lubricating oil applications, the succinic anhydrides are typically substituted in alpha position by an alkyl chain such as polyisobutylene (PIBSA) or PIBSA-type moiety. However, any alkyl group compatible with the present invention may be contemplated.
[017] For lubricating oil application, polyalkylene polyamine is commonly used as the polyamine. However, any polyamine compatible with the present invention may be contemplated.
[018] The polyamine can react with the alkyl-substituted succinic anhydride to produce, according to their molar ratio, mono-succinimides, bis-succinimides, trissuccinimides or mixtures of thereof.
[019] In one embodiment, a hydrocarbyl bis-succinimide can be obtained by reacting a hydrocarbyl-substituted succinic anhydride of structure II
(wherein R is a hydrocaryl substituent is derived from a polyalkene group having a number average molecular weight of from about 500 to about 3000) with a polyamine.
[020] In one embodiment, R is a hydrocarbyl substituent is derived from a polyalkene group having a number average molecular weight of from about 1000 to about 2500. In one embodiment, R is a polyisobutenyl substituent derived from a polyisobutene having a number average molecular weight of from about 500 to about 3000 (such as from 850 to 1700). In another embodiment, R is a polyisobutenyl substituent derived from a polyisobutene having a number average molecular weight of from about 1000 to about 2500.
[021] Suitable polyamines can have a straight- or branched-chain structure and may be cyclic, acylic, or combinations thereof.
[022] In some embodiments, polyalkylene polyamines may be used to prepare the bis-succinimide dispersants. Such polyalkylene polyamines will typically contain about 2 to about 12 nitrogen atoms and about 2 to 24 carbon atoms. Particularly suitable polyalkylene polyamines include those having the formula: H2N — (R'NH)x — H wherein R' is a straight- or branched-chain alkylene group having 2 or 3 carbon atoms and x is 1 to 9. Representative examples of suitable polyalkylene polyamines include
diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), pentaethylene hexamine (PEHA), and heavier poly-alkylene-amines (HPA).
[023] In some embodiments, the polyamine may contain cyclic groups. Specific examples include N, N'-bis-(2-aminoethyl)piperazine) (Bis AEP), N-[(2- aminoethyl) 2-aminoethyl]piperazine) (PEEDA), 1-(2-aminoethyl)-4-[(2- aminoethyl)amino]ethyl]- piperazine) (AEPEEDA) and 1 -[2-[[2-[(2-aminoethyl)amino]ethyl]amino]ethyl]- piperazine) (PEDETA).
[024] Many of the polyamines suitable for use in the present invention are commercially available and others may be prepared by methods which are well known in the art. For example, methods for preparing amines and their reactions are detailed in Sidgewick's "The Organic Chemistry of Nitrogen", Clarendon Press, Oxford, 1966; Noller's "Chemistry of Organic Compounds", Saunders, Philadelphia, 2nd Ed., 1957; and Kirk-Othmer's "Encyclopedia of Chemical Technology", 2nd Ed., especially Volume 2, pp. 99 116.
[025] Generally, the hydrocarbyl-substituted succinic anhydride is reacted with the polyamine at a temperature of about 130°C to 220°C (e.g., 140°C to 200°C, 145°C to 175°C, etc.). The reaction can be carried out under an inert atmosphere, such as nitrogen or argon. Generally, a suitable molar charge of polyamine to polyalkenylsubstituted succinic anhydride is from about 0.35:1 to about 1 :1 (e.g., 0.4:1 to 0.75:1). As used herein, the "molar charge of polyamine to polyalkenyl-substituted succinic anhydride" means the ratio of the number of moles of polyamine to the number of succinic groups in the succinic anhydride reactant.
[026] One class of suitable hydrocarbyl succinimides may be represented by the following structure:
wherein R and R' are as described herein above and y is 1 to 11.
[027] In some embodiments, the succinimide dispersant may be post-treated by a reactive boron compound or organic carbonate.
[028] Suitable boron compounds that can be used as a source of boron include, for example, boric acid, a boric acid salt, a boric acid ester, and the like. Representative examples of a boric acid include orthoboric acid, metaboric acid, paraboric acid, and the like. Representative examples of a boric acid salt include ammonium borates, such as ammonium metaborate, ammonium tetraborate, ammonium pentaborate, ammonium octaborate, and the like. Representative examples of a boric acid ester include monomethyl borate, dimethyl borate, trimethyl borate, monoethyl borate, diethyl borate, triethyl borate, monopropyl borate, dipropyl borate, tripropyl borate, monobutyl borate, dibutyl borate, tributyl borate, and the like.
[029] Suitable organic carbonates include, for example, cyclic carbonates such as 1,3-dioxolan-2-one (ethylene carbonate); 4-methyl-1,3-dioxolan-2-one(propylene carbonate); 4-ethyl-1,3-dioxolan-2-one(butylene carbonate); 4-hydroxymethyl-1,3- dioxolan-2-one; 4,5-dimethyl-1,3-dioxolan-2-one; 4-ethyl-1,3-dioxolan-2-one; 4,4- dimethyl-1,3-dioxolan-2-one; 4-methyl-5-ethyl-1,3-dioxolan-2-one; 4,5-diethyl-1 ,3- dioxolan-2-one; 4,4-diethyl-1,3-dioxolan-2-one; 1,3-dioxan-2-one; 4,4-dimethyl-1,3- dioxan-2-one; 5,5-dimethyl-1,3-dioxan-2-one; 5,5-dihydroxymethyl-1,3-dioxan-2- one; 5-methyl-1,3-dioxan-2-one; 4-methyl-1,3-dioxan-2-one; 5-hydroxy-1,3-dioxan-
2-one; 5-hydroxymethyl-5-methyl-1,3-dioxan-2-one; 5,5-diethyl-1,3-dioxan-2-one; 5- methyl-5-propyl-1,3-dioxan-2-one; 4,6-dimethyl-1,3-dioxan-2-one; 4,4,6-trimethyl- 1,3-dioxan-2-one and spiro[1,3-oxa-2-cyclohexanone-5,5'-1',3'-oxa-2'- cyclohexanone]. Other suitable cyclic carbonates may be prepared from saccharides such as sorbitol, glucose, fructose, galactose and the like and from vicinal diols prepared from C1 to C30 olefins by methods known in the art.
Alkyl Phosphonic Acid
[030] Alkyl phosphonic acid may be described as a hydrocarbyl substituted derivative of a phosphonic acid. Phosphonic acids including alkyl phosphonic acids are generally insoluble in base oil due to their diacid structure. This has limited the use of phosphonic acids in lubricating oils.
[031] Mixing alkyl phosphonic acids with a basic compound such as the succinimide dispersant of the present invention neutralizes the alkyl phosphonic acid which in turn enhances the oil solubility of the mixture including the alkyl phosphonic acid and/or the alkyl phosphonate.
[032] In accordance with the present invention, the alkyl phosphonic acid is a monoalkyl phosphonic acid that can be described by the following formula:
wherein R is a C3-C20 hydrocarbyl group. R may be saturated or unsaturated. R may be linear, branched, or cyclic. In some embodiments, R is aliphatic. In some embodiments, R is aromatic. R may be an alkyl, aryl, or alkaryl group. In some embodiments, R may include a heteroatom. In some embodiments, R may include an ether or thioether moiety.
[033] The phosphonic acid may be obtained by any known compatible method. For example, phosphonic acid may be obtained via oxidation of phosphinic acid. Another synthetic pathway involves hydrolysis of dialkyl phosphonate to phosphonic acid under acidic conditions. A more detailed discussion can be found in Beilstein J. Org. Chem. 2017, 13, 2186-2213, which is hereby incorporated by reference.
[034] Suitable examples of compatible alkyl phosphonic acids include butyl phosphonic acid, octyl phosphonic acid, decyl phosphonic acid, octadecyl phosphonic acid, and the like.
[035] In some embodiments, the alkyl phosphonic acid may be pre-mixed with the succinimide dispersant prior to blending with the base oil. The initial pH of such a mixture is between about 5.0 to about 9.5 as measured by ASTM D664. In other embodiments, no pre-mixing is required.
Lubricating Oil
[036] When employed as lubricant additives, the succinimide is usually present in the lubricating oil composition in concentrations ranging from about 0.001 to about 20 wt. % (including, but not limited to, 0.01 to 5 wt. %, 0.2 to 4 wt. %, 0.5 to 3 wt. %, 1 to 2 wt. %, and so forth), based on the total weight of the lubricating oil composition.
[037] The phosphonic acid may be present in concentrations ranging from about 0.001 to about 20 wt. % (including, but not limited to, 0.01 to 5 wt. %, 0.02 to 4 wt. %, 0.05 to 3 wt. %, 0.1 to 2 wt. %, and so forth), based on the total weight of the lubricating oil composition.
[038] Oils used as the base oil will be selected or blended depending on the desired end use and the additives in the finished oil to give the desired grade of engine oil, e.g. a lubricating oil composition having an Society of Automotive Engineers (SAE) Viscosity Grade of 0W, 0W-8, 0W-16, 0W-20, 0W-30, 0W-40, 0W-50, 0W-60, 5W, 5W- 20, 5W-30, 5W-40, 5W-50, 5W-60, 10W, 10W-20, 10W-30, 10W-40, 10W-50, 15W, 15W-20, 15W-30, or 15W-40.
[039] The oil of lubricating viscosity (sometimes referred to as "base stock" or "base oil") is the primary liquid constituent of a lubricant, into which additives and
possibly other oils are blended, for example to produce a final lubricant (or lubricant composition). A base oil, which is useful for making concentrates as well as for making lubricating oil compositions therefrom, may be selected from natural (vegetable, animal or mineral) and synthetic lubricating oils and mixtures thereof.
[040] Definitions for the base stocks and base oils in this disclosure are the same as those found in American Petroleum Institute (API) Publication 1509 Annex E ("API Base Oil Interchangeability Guidelines for Passenger Car Motor Oils and Diesel Engine Oils," December 2016). Group I base stocks contain less than 90% saturates and/or greater than 0.03% sulfur and have a viscosity index greater than or equal to 80 and less than 120 using the test methods specified in Table E-1. Group II base stocks contain greater than or equal to 90% saturates and less than or equal to 0.03% sulfur and have a viscosity index greater than or equal to 80 and less than 120 using the test methods specified in Table E-1. Group III base stocks contain greater than or equal to 90% saturates and less than or equal to 0.03% sulfur and have a viscosity index greater than or equal to 120 using the test methods specified in Table E-1. Group IV base stocks are polyalphaolefins (PAO). Group V base stocks include all other base stocks not included in Group I, II, III, or IV.
[041] Natural oils include animal oils, vegetable oils (e.g., castor oil and lard oil), and mineral oils. Animal and vegetable oils possessing favorable thermal oxidative stability can be used. Of the natural oils, mineral oils are preferred. Mineral oils vary widely as to their crude source, for example, as to whether they are paraffinic, naphthenic, or mixed paraffinic-naphthenic. Oils derived from coal or shale are also useful. Natural oils vary also as to the method used for their production and purification, for example, their distillation range and whether they are straight run or cracked, hydrorefined, or solvent extracted.
[042] Synthetic oils include hydrocarbon oil. Hydrocarbon oils include oils such as polymerized and interpolymerized olefins (e.g., polybutylenes, polypropylenes, propylene isobutylene copolymers, ethylene-olefin copolymers, and ethylenealphaolefin copolymers). Polyalphaolefin (PAO) oil base stocks are commonly used
synthetic hydrocarbon oil. By way of example, PAOs derived from C8 to C14 olefins, e.g., C8, C10, C12, C14 olefins or mixtures thereof, may be utilized.
[043] Other useful fluids for use as base oils include non-conventional or unconventional base stocks that have been processed, preferably catalytically, or synthesized to provide high performance characteristics.
[044] Non-conventional or unconventional base stocks/base oils include one or more of a mixture of base stock(s) derived from one or more Gas-to-Liquids (GTL) materials, as well as isomerate/isodewaxate base stock(s) derived from natural wax or waxy feeds, mineral and or non-mineral oil waxy feed stocks such as slack waxes, natural waxes, and waxy stocks such as gas oils, waxy fuels hydrocracker bottoms, waxy raffinate, hydrocrackate, thermal crackates, or other mineral, mineral oil, or even nonpetroleum oil derived waxy materials such as waxy materials received from coal liquefaction or shale oil, and mixtures of such base stocks. Other base oils include Coal to liquid (CTL) products and alkyl-naphthalene.
[045] Base oils for use in the lubricating oil compositions of present disclosure are any of the variety of oils corresponding to API Group I, Group II, Group III, Group IV, and Group V oils, and mixtures thereof, preferably API Group II, Group III, Group IV, and Group V oils, and mixtures thereof, more preferably the Group III to Group V base oils due to their exceptional volatility, stability, viscometric and cleanliness features.
[046] Typically, the base oil will have a kinematic viscosity at 100°C (ASTM D445) in a range of 1.5 to 35 mm2/s (e.g., 1.5 to 25 mm2/s, 2.0 to 20 mm2/s, or 2.0 to 15 mm2/s).
[047] The present lubricating oil compositions may also contain conventional lubricant additives for imparting auxiliary functions to give a finished lubricating oil composition in which these additives are dispersed or dissolved. For example, the lubricating oil compositions can be blended with antioxidants, ashless dispersants, anti-wear agents, detergents such as metal detergents, rust inhibitors, dehazing agents, demulsifying agents, friction modifiers, metal deactivating agents, pour point depressants, viscosity modifiers, antifoaming agents, co-solvents, package
compatibilizers, corrosion-inhibitors, dyes, extreme pressure agents and the like and mixtures thereof. A variety of the additives are known and commercially available. These additives, or their analogous compounds, can be employed for the preparation of the lubricating oil compositions of the invention by the usual blending procedures.
[048] Each of the foregoing additives, when used, is used at a functionally effective amount to impart the desired properties to the lubricant. Thus, for example, if an additive is an ashless dispersant, a functionally effective amount of this ashless dispersant would be an amount sufficient to impart the desired dispersancy characteristics to the lubricant. Generally, the concentration of each of these additives, when used, may range, unless otherwise specified, from about 0.001 to about 20 wt. %, such as about 0.01 to about 10 wt. %.
[049] The following non-limiting examples are illustrative of the present invention.
EXAMPLES
[050] Lubricating oil samples (i.e., examples and comparative examples) were evaluated for anti-wear performance. Each sample includes succinimide dispersant, a phosphorus additive (optional in some comparative examples), other lubricating oil additives (friction modifiers, ashless anti-wear additives, antioxidants, metal deactivators, seal swell additives, foam inhibitors, and viscosity modifiers), and base oil.
Succinimide Dispersant
[051] Borated Succinimide 1 is a boron-modified polyisobutenyl succinimide with a polyisobutylene number average molecular weight of 950 (N: 1.95 wt%; B: 0.63 wt%).
[052] Borated Succinimide 2 is a boron-modified polyisobutenyl succinimide with a polyisobutylene number average molecular weight of 1,300 (N: 1.88 wt%; B: 0.36 wt%).
[053] Succinimide 1 is a polyisobutenyl succinimide with a polyisobutylene number average molecular weight of 950 (N: 2.15 wt%).
[054] Succinimide 2 is a polyisobutenyl succinimide with a polyisobutylene number average molecular weight of 950 (N: 2.0 wt%).
[055] Succinimide 3 is a low molecular weight alkenyl succinimide (N: 4.6 wt%).
Phosphorus Additive
[056] Phosphorus additive is a phosphorus-containing compound.
[057] Monoalkyl phosphonic acid includes butyl phosphonic acid (P: 22.4 wt%), octyl phosphonic acid (P: 15.7 wt%), and octadecyl phosphonic acid (P: 9.3 wt%).
[058] Phosphorus compound 1 is inorganic phosphoric acid H3PO4 (P: 27.0 wt%).
[059] Phosphorus compound 2 is 2-ethylhexyl phosphate ester (P: 11.1 wt%).
[060] Phosphorus compound 3 is 3-bis(2- methylpropoxy)phosphinothioylthio-2-methyl-propanoic acid, commercially available from BASF under the trade name Irgalube® 353 (P: 9.3 wt%).
[061] Phosphorus compound 4 is trilauryl trithiophosphite (P: 4.9 wt%)
[062] Phosphorus compound 5 is a mixture of C12, C14, and C18 phosphate ester (P: 8.3 wt%).
[063] Phosphorus compound 6 is isotridecyl phosphate ester (P: 8.2 wt%).
[064] Phosphorus compound 7 is dimethyl octadecyl phosphonate (P: 8.6 wt%)
[065] The examples and comparative examples were prepared from the above- mentioned additives in the ratios described in Table 1 and Table 2. The initial pH of the mixture of succinimide dispersant (A) and phosphorus additive (B) was measured by ASTM D664 method and reported in Table 1.
Wear Test
[066] The anti-wear performance of each lubricating oil compositions was determined using the 4 ball wear scar test (ASTM D4172) at 1200 rpm and 1800 rpm, oil temperature of 80°C, and load of 392N for 60 min. After testing, the test balls were removed and the wear scars were measured. The wear scar diameters are reported in
mm in Table 1 and Table 2. A smaller wear scar diameter indicates better anti-wear performance.
Table 1
Table 1 cont.
[067] Comparative examples 1-8 which contain succinimide but do not contain alkyl phosphonic acid showed poor anti-wear performance. By contrast, inventive examples 1-4 which contain succinimide and C4-C18 alkyl phosphonic acids showed superior anti-wear performance.
[068] The anti-wear property of alkyl phosphonic acid was also evaluated with different succinimide mixtures. Table 2 below shows the 4-ball wear scar results for comparative examples 9-10 and inventive examples 5-6.
Table 2
[069] Inventive examples 5 and 6 which contain octyl phosphonic acid in addition to succinimide, exhibited superior performance compared to comparative examples 9-10, further demonstrating the antiwear capabilities of alkyl phosphonic acids.
Volume Resistivity
[070] The electrical insulating ability of the lubricating oil compositions was determined in accordance with JIS C2101-1999-24. The volume resistivity values of several examples were measured at an applied voltage of 250 V and reported in units of Ω·cm in Table 3. A volume resistivity of greater than 1 x 108 Ω·cm at 80°C is preferred for adequate insulating properties in transmission fluids.
Table 3
[071] All documents described herein are incorporated by reference herein, including any priority documents and/or testing procedures to the extent they are not inconsistent with this text. As is apparent from the foregoing general description and the specific embodiments, while forms of the present disclosure have been illustrated and described, various modifications can be made without departing from the spirit and scope of the present disclosure. Accordingly, it is not intended that the present disclosure be limited thereby.
[072] For the sake of brevity, only certain ranges are explicitly disclosed herein. However, ranges from any lower limit may be combined with any upper limit to recite a range not explicitly recited, as well as, ranges from any lower limit may be combined with any other lower limit to recite a range not explicitly recited, in the same way, ranges from any upper limit may be combined with any other upper limit to recite a range not explicitly recited. Additionally, within a range includes every point or individual value between its end points even though not explicitly recited. Thus, every point or individual value may serve as its own lower or upper limit combined with any other point or individual value or any other lower or upper limit, to recite a range not explicitly recited.
[073] Likewise, the term "comprising" is considered synonymous with the term "including." Likewise, whenever a composition, an element or a group of elements is preceded with the transitional phrase "comprising," it is understood that we also contemplate the same composition or group of elements with transitional phrases "consisting essentially of," "consisting of," "selected from the group of consisting of," or "is" preceding the recitation of the composition, element, or elements and vice versa.
[074] The terms "a" and "the" as used herein are understood to encompass the plural as well as the singular.
[075] Various terms have been defined above. To the extent a term used in a claim is not defined above, it should be given the broadest definition persons in the pertinent art have given that term as reflected in at least one printed publication or issued patent. Furthermore, all patents, test procedures, and other documents cited in this application are fully incorporated by reference to the extent such disclosure is not inconsistent with this application and for all jurisdictions in which such incorporation is permitted.
[076] The foregoing description of the disclosure illustrates and describes the present disclosure. Additionally, the disclosure shows and describes only the preferred embodiments but, as mentioned above, it is to be understood that the disclosure is capable of use in various other combinations, modifications, and environments and is capable of changes or modifications within the scope of the concept as expressed herein, commensurate with the above teachings and/or the skill or knowledge of the relevant art. While the foregoing is directed to embodiments of the present disclosure, other and further embodiments of the disclosure may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
[077] It is understood that when combinations, subsets, groups, etc. of elements are disclosed (e.g., combinations of components in a composition, or combinations of steps in a method), that while specific reference of each of the various individual and collective combinations and permutations of these elements may not be explicitly disclosed, each is specifically contemplated and described herein.
[078] The embodiments described hereinabove are further intended to explain best modes known of practicing it and to enable others skilled in the art to utilize the disclosure in such, or other, embodiments and with the various modifications required by the particular applications or uses. Accordingly, the description is not intended to limit it to the form disclosed herein. Also, it is intended that the appended claims be construed to include alternative embodiments.
Claims (20)
1. A lubricating oil composition comprising: a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm2/s; and an anti-wear mixture comprising: one or more ashless dispersants and an alkyl phosphonic acid having a structure given by
wherein R is a C3-C20 hydrocarbyl group; initial pH of the anti-wear mixture is between 5.0 - 9.5 as measured by ASTM D664; and wherein the lubricating oil composition is free of zinc.
2. The lubricating oil composition of claim 1, wherein the one or more ashless dispersants include a hydrocarbyl succinimide.
3. The lubricating oil composition of claim 1, wherein the one or more ashless dispersant include a borated hydrocarbyl succinimide.
4. The lubricating oil composition of claim 1, wherein the volume resistivity is greater than 1 x 108 Ω·cm at 80°C.
5. The lubricating oil composition of claim 1, wherein the lubricating oil composition is a hydraulic fluid, a slide way lubricant, automatic transmission fluid, continuously variable transmission fluid, battery electric vehicle, hybrid electric vehicle transmission fluid, or gear oil.
6. The lubricating oil composition of claim 1, further comprising:
a friction modifier, ashless anti-wear additive, antioxidant, metal deactivator, seal swell additive, foam inhibitor, or viscosity modifier.
7. The lubricating oil composition of claim 1, wherein R is a linear alkyl group optionally containing an ether or thioether moiety.
8. A lubricating oil composition comprising: a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm2/s; and an anti-wear mixture comprising: one or more polyisobutenyl succinimide dispersants and an alkyl phosphonic acid having a structure given by
wherein R is a C3-C20 hydrocarbyl group; initial pH of the anti-wear mixture is between 5.0 - 9.5 as measured by ASTM D664; and wherein the lubricating oil composition is free of zinc.
9. The lubricating oil composition of claim 8, wherein the one or more polyisobutenyl succinimide is borated.
10. The lubricating oil composition of claim 8, wherein at least one of the one or more polyisobutenyl succinimide has a polyisobutylene group with a number average molecular weight of about 850 or greater.
11. The lubricating oil composition of claim 8, wherein the volume resistivity is greater than 1 x 108 Ω·cm at 80°C.
12. The lubricating oil composition of claim 8, wherein the lubricating oil composition is a hydraulic fluid, slide way lubricant, automatic transmission fluid, continuously variable transmission fluid, battery electric vehicle, hybrid electric vehicle transmission fluid, or gear oil.
13. The lubricating oil composition of claim 8, further comprising: a friction modifier, ashless anti-wear additive, antioxidant, metal deactivator, seal swell additive, foam inhibitor, or viscosity modifier.
14. The lubricating oil composition of claim 8, wherein R is a linear alkyl group optionally containing an ether or thioether moiety.
15. A method of reducing wear of a transmission or gear comprising: lubricating the transmission or gear with a lubricating oil composition comprising: a major amount of an oil of lubricating viscosity having a kinematic viscosity at 100°C in a range of about 1.5 to about 35 mm2/s; and an anti-wear mixture comprising: one or more ashless dispersants and an alkyl phosphonic acid of the following formula:
wherein R is a C3-C20 hydrocarbyl group; wherein the initial pH of the anti-wear mixture is between 5.0 - 9.5 when measured by the ASTM D664 method; and wherein the lubricating oil composition is free of zinc.
16. The method of claim 15, wherein the one or more ashless dispersants include a hydrocarbyl succinimide.
17. The method of claim 15, wherein the one or more ashless dispersants include a borated hydrocarbyl succinimide.
18. The method of claim 15, wherein the volume resistivity is greater than 1 x 108Ω ·cm at 80°C.
19. The method of claim 15, wherein the lubricating oil composition further comprises: a friction modifier, ashless anti-wear additive, antioxidant, metal deactivator, seal swell additive, foam inhibitor, or viscosity modifier.
20. The method of claim 15, wherein R is a linear alkyl group optionally containing an ether or thioether moiety.
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US63/078,009 | 2020-09-14 | ||
PCT/IB2021/058338 WO2022054023A1 (en) | 2020-09-14 | 2021-09-14 | Lubricating oil containing alkyl phosphonic acid |
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US (1) | US20240101923A1 (en) |
EP (1) | EP4211210A1 (en) |
JP (1) | JP2023541435A (en) |
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AU (1) | AU2021340009A1 (en) |
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US3100673A (en) | 1963-08-13 | Dyeings and prints possessing fastness | ||
US2992708A (en) | 1954-01-14 | 1961-07-18 | Lyon George Albert | Air circulating wheel structure |
DE1248643B (en) | 1959-03-30 | 1967-08-31 | The Lubrizol Corporation, Cleveland, Ohio (V. St. A.) | Process for the preparation of oil-soluble aylated amines |
NL255193A (en) | 1959-08-24 | |||
NL255194A (en) | 1959-08-24 | |||
US3272746A (en) | 1965-11-22 | 1966-09-13 | Lubrizol Corp | Lubricating composition containing an acylated nitrogen compound |
US3779928A (en) * | 1969-04-01 | 1973-12-18 | Texaco Inc | Automatic transmission fluid |
DE2200661A1 (en) * | 1972-02-01 | 1973-07-19 | Texaco Development Corp | LUBRICATING OIL FORMULATION |
US6528458B1 (en) * | 2002-04-19 | 2003-03-04 | The Lubrizol Corporation | Lubricant for dual clutch transmission |
US7091306B2 (en) | 2003-05-09 | 2006-08-15 | Chevron Oronite Company Llc | Process for preparing polyalkenylsuccinimides |
US20060264340A1 (en) * | 2005-05-20 | 2006-11-23 | Iyer Ramnath N | Fluid compositions for dual clutch transmissions |
JP5779376B2 (en) * | 2011-03-29 | 2015-09-16 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition |
WO2016161583A1 (en) | 2015-04-08 | 2016-10-13 | 华为技术有限公司 | Gprs system key enhancement method, sgsn device, ue, hlr/hss and gprs system |
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