AU2011237496B2

AU2011237496B2 - Methods for heating with slots in hydrocarbon formations

Info

Publication number: AU2011237496B2
Application number: AU2011237496A
Authority: AU
Inventors: John Michael Karanikas; Duncan Charles Macdonald; Ernesto Rafael Ocampos
Original assignee: Shell Internationale Research Maatschappij BV
Current assignee: Shell Internationale Research Maatschappij BV
Priority date: 2010-04-09
Filing date: 2011-04-07
Publication date: 2015-02-05
Anticipated expiration: 2031-04-07
Also published as: CA2793673A1; AU2011237496A1; RU2012147634A; CA2736672A1; CN102834586A; WO2011127292A1

Abstract

Systems and methods for treating a subsurface formation are described herein. Some embodiments generally relate to systems, methods, and/or processes for treating fluid produced from the subsurface formation. Some methods include forming at least one wellbore in a hydrocarbon containing formation; forming one or more slots in a portion of the hydrocarbon containing formation; providing heat to a portion of the hydrocarbon containing formation from one or more heaters placed in at least a portion of the slot; allowing the heat to transfer from the heaters to the portion of the hydrocarbon containing formation; and producing hydrocarbons from the hydrocarbon containing formation. One or more of the heaters includes one or more insulated electrical conductors.

Description

WO 2011/127292 PCT/US2011/031591 METHODS FOR HEATING WITH SLOTS IN HYDROCARBON FORMATIONS BACKGROUND 5 1. Field of the Invention [0001] The present invention relates generally to methods and systems for production of hydrocarbons, hydrogen, methane, and/or other products from various subsurface formations such as hydrocarbon containing formations. 10 2. Description of Related Art [0002] Hydrocarbons obtained from subterranean formations are often used as energy resources, as feedstocks, and as consumer products. Concerns over depletion of available hydrocarbon resources and concerns over declining overall quality of produced hydrocarbons have led to development of processes for more efficient recovery, processing and/or use of available 15 hydrocarbon resources. In situ processes may be used to remove hydrocarbon materials from subterranean formations that were previously inaccessible and/or too expensive to extract using available methods. Chemical and/or physical properties of hydrocarbon material in a subterranean formation may need to be changed to allow hydrocarbon material to be more easily removed from the subterranean formation and/or increase the value of the hydrocarbon material. 20 The chemical and physical changes may include in situ reactions that produce removable fluids, composition changes, solubility changes, density changes, phase changes, and/or viscosity changes of the hydrocarbon material in the formation. [0003] Large deposits of heavy hydrocarbons (heavy oil and/or tar) contained in relatively permeable fonnations (for example in tar sands) are found in North America, South America, 25 Africa, and Asia. Tar can be surface-mined and upgraded to lighter hydrocarbons such as crude oil, naphtha, kerosene, and/or gas oil. Surface milling processes may further separate the bitumen from sand. The separated bitumen may be converted to light hydrocarbons using conventional refinery methods. Mining and upgrading tar sand is usually substantially more expensive than producing lighter hydrocarbons from conventional oil reservoirs. Some processes 30 to produce hydrocarbons from low permeability formations include hydro-fracturing and/or using slot drilling to increase permeability in the formation. [0004] Oil shale formations may be heated and/or retorted in situ to increase permeability in the formation and/or to convert the kerogen to hydrocarbons having an API gravity greater than 10'. In conventional processing of oil shale formations, portions of the oil shale formation containing 35 kerogen are generally heated to temperatures above 370 'C to form low molecular weight hydrocarbons, carbon oxides, and/or molecular hydrogen. Some processes to produce bitumen from oil shale formations include heating the oil shale to a temperature above the natural 1 WO 2011/127292 PCT/US2011/031591 temperature of the oil shale until some of the organic components of the oil shale are converted to bitumen and/or fluidizable material. [0005] U.S. Patent No. 3,515,213 to Prats describes circulation of a fluid heated at a moderate temperature from one point within the formation to another for a relatively long period of time 5 until a significant proportion of the organic components contained in the oil shale formation are converted to oil shale derived fluidizable materials. [0006] U.S. Patent No. 7,011,154 to Maher et al. describes in situ treatment of a kerogen and liquid hydrocarbon containing fonnation using heat sources to produce pyrolyzed hydrocarbons. Maher also describes an in situ treatment of a kerogen and liquid hydrocarbon containing 10 formation using a heat transfer fluid such as steam. In an embodiment, a method of treating a kerogen and liquid hydrocarbon containing formation may include injecting a heat transfer fluid into a formation. Heat from the heat transfer fluid may transfer to a selected section of the formation. The heat from the heat transfer fluid may pyrolyze a substantial portion of the hydrocarbons within the selected section of the formation. The produced gas mixture may 15 include hydrocarbons with an average API gravity greater than about 25'. [0007] U.S. Patent No. 7,017,661 to Vinegar et al. describes in situ thermal treatment of a coal formation. A mixture of hydrocarbons, H 2 , and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas producing fluid may be 20 introduced into the formation to generate synthesis gas. Synthesis gas may be produced from the formation in a batch manner or in a substantially continuous manner. [0008] International Patent Application Publication No. WO 2010/074980 to Carter describes methods and apparatus to cut an extended slot connecting a well to a substantial cross section of a desired producing formation to increase well productivity. U.S. Patent No. 7,647,967 to 25 Coleman et al. describes a system and method for increasing hydrocarbon production from a subsurface reservoir by creating a fissure between two wellbores. [0009] As discussed above, there has been a significant amount of effort to produce hydrocarbons from oil shale. At present, however, there are still many hydrocarbon containing formations cannot be economically produced. Thus, there is a need for improved methods for 30 heating of a hydrocarbon containing formation that contains coal, heavy hydrocarbons and/or bitumen, and production of hydrocarbons having desired characteristics from the hydrocarbon containing formation are needed. 2 3 Summary [0010] According to a first aspect of the present invention, there is provided a method of treating a hydrocarbon containing formation, comprising: forming at least one wellbore in a hydrocarbon containing formation, the wellbore 5 comprising at least two substantially horizontal or inclined portions and at least a first opening at a first position of the earth's surface, wherein at least two of the substantially horizontal or inclined portions are substantially parallel; forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or [0 inclined portions of the wellbore; providing heat to a portion of the hydrocarbon containing formation from one or more heaters placed in at least a portion of the slot, wherein one or more of the heaters comprise one or more insulated electrical conductors; allowing the heat to transfer from the heaters to the portion of the hydrocarbon [5 containing formation; and producing hydrocarbons from the hydrocarbon containing formation. [001 Oa] According to a second aspect of the present invention, there is provided a method of treating a hydrocarbon containing formation, comprising: allowing the heat to transfer from a plurality of heaters to the first section of the Zo formation; producing hydrocarbons from the hydrocarbon containing formation; forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to a least two substantially horizontal or inclined portions of a wellbore positioned in the hydrocarbon containing formation, and wherein 25 at least two of the substantially horizontal or inclined portions are substantially parallel; providing heat to a second section of the hydrocarbon containing formation from one or more additional heaters placed in the slot; allowing the heat to transfer from the heaters to the second section of the formation; and producing additional hydrocarbons from the hydrocarbon containing formation. 30 [001 Ob] According to a third aspect of the present invention, there is provided a method of producing methane from a hydrocarbon containing formation, comprising: 3a forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions and at least a first opening at a first position of the earth's surface, and wherein at least two of the substantially horizontal or inclined portions are substantially parallel; 5 forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; providing heat to a portion of the hydrocarbon containing formation from one or more heaters placed in at least a portion of the slot, wherein one or more of the heaters comprise one [0 or more insulated electrical conductors; maintaining an average temperature in the portion of the formation below a pyrolyzation temperature of hydrocarbons in the section; and removing methane from the hydrocarbon formation. [001 Oc] According to a fourth aspect of the present invention, there is provided a method of [5 treating a hydrocarbon containing formation, comprising: forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions and at least a first opening at a first position of the earth's surface, and wherein at least two of the substantially horizontal or inclined portions are substantially parallel; Zo forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; providing a drive fluid to at least one of the slots; and producing hydrocarbons from the hydrocarbon formation. 25 [001 Od] According to a fifth aspect of the present invention, there is provided a method of producing methane from a hydrocarbon containing formation, comprising: providing heat the formation from a plurality of heaters located in the hydrocarbon containing formation, wherein one or more of the heaters comprise one or more insulated electrical conductors; 30 allowing the heat to transfer from the heaters to at least a portion of the hydrocarbon containing formation comprising methane; 3b maintaining an average temperature in the portion of the hydrocarbon containing formation below a pyrolyzation temperature of hydrocarbons in the hydrocarbon containing formation comprising methane; and removing methane from the portion of the hydrocarbon containing formation. 5 [001 Oe] According to a sixth aspect of the present invention, there is provided a method of producing methane from a hydrocarbon containing formation, comprising: providing heat to a first section of the hydrocarbon containing formation from a plurality of heaters located in the formation, wherein one or more of the heaters comprise one or more insulated electrical conductors; [0 allowing the heat to transfer from the heaters to the first section of the hydrocarbon containing formation, producing hydrocarbons from the first section; providing one or more heaters from the first section to a second section of the hydrocarbon containing formation, wherein the second section of the formation comprises [5 methane; maintaining an average temperature in the second section of the hydrocarbon containing formation below a pyrolyzation temperature of hydrocarbons in the second section; and removing methane from the hydrocarbon containing formation. [001 Of] The disclosure herein generally relate to systems and methods for treating a subsurface formation. In certain embodiments, the invention provides one or more systems 20 and/or methods for treating a subsurface formation. [0011] In the disclosure herein a method of treating a hydrocarbon containing formation includes forming at least one wellbore in a hydrocarbon containing formation, the wellbore including at least two substantially horizontal or inclined portions, a first opening at a first position of the earth's surface and the second a second opening is at a second position of the earth's surface; forming one or more slots in a portion of the hydrocarbon containing formation. wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of 3c the wellbore; providing heat to a portion of the hydrocarbon containing formation from one or more heaters placed in at least a portion of the slot, wherein one or more of the heaters includes one or more insulated electrical conductors; allowing the heat to transfer from the heaters to the portion of the hydrocarbon containing formation; and producing hydrocarbons from the hydrocarbon containing formation. [0012] In the disclosure herein a method of treating a hydrocarbon containing formation includes allowing the heat to transfer front a plurality of heaters to the first section of the formation; producing hydrocarbons from the hydrocarbon containing formation; forcing one or more slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to a least two substantially horizontal or inclined portions of a wellbore positioned in the hydrocarbon containing formation; providing heat to a second section of the hydrocarbon containing formation from one or more additional heaters placed in the slot; allowing the heat to transfer from the heaters to the second section of the formation; and producing additional hydrocarbons from the hydrocarbon containing formation. [0013] In the disclosure herein a method of treating a hydrocarbon containing formation includes formation, includes forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions, a first opening at a first position of the earth's surface and the second a second opening is at a second position of the earth's surface; forming one or more slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; providing heat to a portion of the hydrocarbon containing formation from one or more heaters placed in at least a portion of the slot, wherein one or more of the heaters include one or more insulated electrical conductors; maintaining an average temperature in the portion of the formation below a pyrolyzation temperature of hydrocarbons in the section; and removing methane from the hydrocarbon formation.

WO 2011/127292 PCT/US2011/031591 [0014] In some embodiments, a method of treating a hydrocarbon containing formation, includes forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions, a first opening at a first position of the earth's surface and the second a second opening is at a second position of the earth's surface; 5 forming one or more slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; providing a drive fluid to at least one of the slots; and producing hydrocarbons from the hydrocarbon formation. [0015] In further embodiments, features from specific embodiments may be combined with 10 features from other embodiments. For example, features from one embodiment may be combined with features from any of the other embodiments. [0016] In further embodiments, treating a subsurface formation is performed using any of the methods, systems, power supplies, or heaters described herein. [0017] In further embodiments, additional features may be added to the specific embodiments 15 described herein. BRIEF DESCRIPTION OF THE DRAWINGS [0018] Advantages of the present invention may become apparent to those skilled in the art with the benefit of the following detailed description and upon reference to the accompanying 20 drawings in which: [0019] FIG. 1 depicts a schematic view of an embodiment of a portion of an in situ heat treatment system for treating a hydrocarbon containing formation. [0020] FIG. 2 depicts a perspective view of an end portion of an embodiment of an insulated conductor. 25 [00211 FIG. 3 depicts an embodiment of three insulated conductors in an opening in a subsurface formation coupled in a wye configuration. [0022] FIG. 4 depicts an embodiment of three insulated conductors that are removable from an opening in the formation. [0023] FIGS. 5A and 5B depict cross-sectional representations of an embodiment of the 30 insulated conductor heater with the temperature limited heater as the heating member. [0024] FIGS. 6A and 6B depict representations of embodiments of heating a hydrocarbon containing formation containing a hydrocarbon layer and a coal containing layer. [0025] FIG. 7 depicts a perspective representation of an embodiment of forming a slot in a hydrocarbon containing formation. 35 [0026] FIG. 7A depicts a cross-sectional view of slots along section 7A-7A of FIG. 7. 4 WO 2011/127292 PCT/US2011/031591 [0027] FIG. 8 depicts a perspective representation of treating a hydrocarbon containing formation after formation of slots. [0028] FIG. 9 depicts a perspective representation of an embodiment of forming slots in a hydrocarbon layer using a 2 well system. 5 [0029] FIG. I GA depicts a perspective representation of a symmetric arch formed between two wellbores. [0030] FIG. 10B depicts a perspective representation of a polygon formed between two wellbores. [0031] FIG. 1 1A depicts a perspective representation of radial pattern having a central well and 10 eight surrounding wells. [0032] FIG. 1 lB depicts a perspective representation of radial pattern having a central well and seven surrounding wells. [0033] FIGS. 12A-C depict perspective representations of embodiments of repositioning positioning wellbores in a hydrocarbon formation. 15 [0034] While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and may herein be described in detail. The drawings may not be to scale. It should be understood, however, that the drawings and detailed description thereto are not intended to limit the invention to the particular form disclosed, but on the contrary, the intention is to cover all modifications, equivalents and 20 alternatives falling within the spirit and scope of the present invention as defined by the appended claims. DETAILED DESCRIPTION [0035] The following description generally relates to systems and methods for treating hydrocarbons in the formations. Such formations may be treated to yield hydrocarbon products, 25 hydrogen, and other products. [0036] "API gravity" refers to API gravity at 15.5 'C (60 F). API gravity is as determined by ASTM Method D6822 or ASTM Method D1298. [0037] "ASTM" refers to ASTM International. [0038] In the context of reduced heat output heating systems, apparatus, and methods, the term 30 "automatically" means such systems, apparatus, and methods function in a certain way without the use of external control (for example, external controllers such as a controller with a temperature sensor and a feedback loop, PID controller, or predictive controller). [0039] "Asphalt/bitumen" refers to a semi-solid, viscous material soluble in carbon disulfide. Asphalt/bitumen may be obtained from refining operations or produced from subsurface 35 formations. 5 WO 2011/127292 PCT/US2011/031591 [0040] Boiling range distributions for the formation fluid and liquid streams described herein are as determined by ASTM Method D5307 or ASTM Method D2887. [0041] "Carbon number" refers to the number of carbon atoms in a molecule. A hydrocarbon fluid may include various hydrocarbons with different carbon numbers. The hydrocarbon fluid 5 may be described by a carbon number distribution. Carbon numbers and/or carbon number distributions may be determined by true boiling point distribution and/or gas-liquid chromatography. [0042] "Chemical stability" refers to the ability of a formation fluid to be transported without components in the formation fluid reacting to form polymers and/or compositions that plug 10 pipelines, valves, and/or vessels. [0043] "Condensable hydrocarbons" are hydrocarbons that condense at 25 'C and one atmosphere absolute pressure. Condensable hydrocarbons may include a mixture of hydrocarbons having carbon numbers greater than 4. "Non-condensable hydrocarbons" are hydrocarbons that do not condense at 25 'C and one atmosphere absolute pressure. Non 15 condensable hydrocarbons may include hydrocarbons having carbon numbers less than 5. [0044] "Coring" is a process that generally includes drilling a hole into a formation and removing a substantially solid mass of the formation from the hole. [0045] "Cracking" refers to a process involving decomposition and molecular recombination of organic compounds to produce a greater number of molecules than were initially present. In 20 cracking, a series of reactions take place accompanied by a transfer of hydrogen atoms between molecules. For example, naphtha may undergo a thermal cracking reaction to form ethene and

H

2 . [0046] A "fluid" may be, but is not limited to, a gas, a liquid, an emulsion, a slurry, and/or a stream of solid particles that has flow characteristics similar to liquid flow. 25 [0047] "Fluid pressure" is a pressure generated by a fluid in a formation. "Lithostatic pressure" (sometimes referred to as "lithostatic stress") is a pressure in a formation equal to a weight per unit area of an overlying rock mass. "Hydrostatic pressure" is a pressure in a formation exerted by a column of water. [0048] A "formation" includes one or more hydrocarbon containing layers, one or more non 30 hydrocarbon layers, an overburden, and/or an underburden. "Hydrocarbon layers" refer to layers in the formation that contain hydrocarbons. The hydrocarbon layers may contain non hydrocarbon material and hydrocarbon material. The "overburden" and/or the "underburden" include one or more different types of impermeable materials. For example, the overburden and/or underburden may include rock, shale, mudstone, or wet/tight carbonate. In some 35 embodiments of in situ heat treatment processes, the overburden and/or the underburden may 6 WO 2011/127292 PCT/US2011/031591 include a hydrocarbon containing layer or hydrocarbon containing layers that are relatively impermeable and are not subjected to temperatures during in situ heat treatment processing that result in significant characteristic changes of the hydrocarbon containing layers of the overburden and/or the underburden. For example, the underburden may contain shale or mudstone, but the 5 underburden is not allowed to heat to pyrolysis temperatures during the in situ heat treatment process. In some cases, the overburden and/or the underburden may be somewhat permeable. [0049] "Formation fluids" refer to fluids present in a formation and may include pyrolyzation fluid, synthesis gas, mobilized hydrocarbons, and water (steam). Formation fluids may include hydrocarbon fluids as well as non-hydrocarbon fluids. The term "mobilized fluid" refers to 10 fluids in a hydrocarbon containing formation that are able to flow as a result of thermal treatment of the formation. "Produced fluids" refer to fluids removed from the formation. [0050] A "heat source" is any system for providing heat to at least a portion of a formation substantially by conductive and/or radiative heat transfer. For example, a heat source may include electrically conducting materials and/or electric heaters such as an insulated conductor, 15 an elongated member, and/or a conductor disposed in a conduit. A heat source may also include systems that generate heat by burning a fuel external to or in a formation. The systems may be surface burners, downhole gas burners, flameless distributed combustors, and natural distributed combustors. In some embodiments, heat provided to or generated in one or more heat sources may be supplied by other sources of energy. The other sources of energy may directly heat a 20 formation, or the energy may be applied to a transfer medium that directly or indirectly heats the formation. It is to be understood that one or more heat sources that are applying heat to a formation may use different sources of energy. Thus, for example, for a given formation some heat sources may supply heat from electrically conducting materials, electric resistance heaters, some heat sources may provide heat from combustion, and some heat sources may provide heat 25 from one or more other energy sources (for example, chemical reactions, solar energy, wind energy, biomass, or other sources of renewable energy). A chemical reaction may include an exothermic reaction (for example, an oxidation reaction). A heat source may also include a electrically conducting material and/or a heater that provides heat to a zone proximate and/or surrounding a heating location such as a heater well. 30 [0051] A "heater" is any system or heat source for generating heat in a well or a near wellbore region. Heaters may be, but are not limited to, electric heaters, burners, combustors that react with material in or produced from a formation, and/or combinations thereof. [0052] "Heavy hydrocarbons" are viscous hydrocarbon fluids. Heavy hydrocarbons may include highly viscous hydrocarbon fluids such as heavy oil, tar, and/or asphalt. Heavy hydrocarbons 35 may include carbon and hydrogen, as well as smaller concentrations of sulfur, oxygen, and 7 WO 2011/127292 PCT/US2011/031591 nitrogen. Additional elements may also be present in heavy hydrocarbons in trace amounts. Heavy hydrocarbons may be classified by API gravity. Heavy hydrocarbons generally have an API gravity below about 200. Heavy oil, for example, generally has an API gravity of about 10 20', whereas tar generally has an API gravity below about 100. The viscosity of heavy 5 hydrocarbons is generally greater than about 100 centipoise at 15 'C. Heavy hydrocarbons may include aromatics or other complex ring hydrocarbons. [0053] Heavy hydrocarbons may be found in a relatively permeable formation. The relatively permeable formation may include heavy hydrocarbons entrained in, for example, sand or carbonate. "Relatively permeable" is defined, with respect to formations or portions thereof, as 10 an average permeability of 10 millidarcy or more (for example, 10 or 100 millidarcy). "Relatively low permeability" is defined, with respect to formations or portions thereof, as an average permeability of less than about 10 millidarcy. One darcy is equal to about 0.99 square micrometers. An impermeable layer generally has a permeability of less than about 0.1 millidarcy. 15 [0054] Certain types of formations that include heavy hydrocarbons may also include, but are not limited to, natural mineral waxes, or natural asphaltites. "Natural mineral waxes" typically occur in substantially tubular veins that may be several meters wide, several kilometers long, and hundreds of meters deep. "Natural asphaltites" include solid hydrocarbons of an aromatic composition and typically occur in large veins. In situ recovery of hydrocarbons from formations 20 such as natural mineral waxes and natural asphaltites may include melting to form liquid hydrocarbons and/or solution mining of hydrocarbons from the formations. [0055] "Hydrocarbons" are generally defined as molecules formed primarily by carbon and hydrogen atoms. Hydrocarbons may also include other elements such as, but not limited to, halogens, metallic elements, nitrogen, oxygen, and/or sulfur. Hydrocarbons may be, but are not 25 limited to, kerogen, bitumen, pyrobitumen, oils, natural mineral waxes, and asphaltites. Hydrocarbons may be located in or adjacent to mineral matrices in the earth. Matrices may include, but are not limited to, sedimentary rock, sands, silicilytes, carbonates, diatomites, and other porous media. "Hydrocarbon fluids" are fluids that include hydrocarbons. Hydrocarbon fluids may include, entrain, or be entrained in non-hydrocarbon fluids such as hydrogen, 30 nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, water, and ammonia. [0056] An "in situ conversion process" refers to a process of heating a hydrocarbon containing formation from heat sources to raise the temperature of at least a portion of the formation above a pyrolysis temperature so that pyrolyzation fluid is produced in the formation. [0057] An "in situ heat treatment process" refers to a process of heating a hydrocarbon 35 containing formation with heat sources to raise the temperature of at least a portion of the 8 WO 2011/127292 PCT/US2011/031591 formation above a temperature that results in mobilized fluid, visbreaking, and/or pyrolysis of hydrocarbon containing material so that mobilized fluids, visbroken fluids, and/or pyrolyzation fluids are produced in the formation. [0058] "Insulated conductor" refers to any elongated material that is able to conduct electricity 5 and that is covered, in whole or in part, by an electrically insulating material. [0059] "Karst" is a subsurface shaped by the dissolution of a soluble layer or layers of bedrock, usually carbonate rock such as limestone or dolomite. The dissolution may be caused by meteoric or acidic water. The Grosmont formation in Alberta, Canada is an example of a karst (or "karsted") carbonate formation. 10 [0060] "Kerogen" is a solid, insoluble hydrocarbon that has been converted by natural degradation and that principally contains carbon, hydrogen, nitrogen, oxygen, and sulfur. Coal and oil shale are typical examples of materials that contain kerogen. "Bitumen" is a non crystalline solid or viscous hydrocarbon material that is substantially soluble in carbon disulfide. "Oil" is a fluid containing a mixture of condensable hydrocarbons. 15 [0061] "Olefins" are molecules that include unsaturated hydrocarbons having one or more non aromatic carbon-carbon double bonds. [0062] "Perforations" include openings, slits, apertures, or holes in a wall of a conduit, tubular, pipe or other flow pathway that allow flow into or out of the conduit, tubular, pipe or other flow pathway. 20 [0063] "Periodic Table" refers to the Periodic Table as specified by the International Union of Pure and Applied Chemistry (JUPAC), November 2003. [0064] "Physical stability" refers to the ability of a formation fluid to not exhibit phase separation or flocculation during transportation of the fluid. Physical stability is determined by ASTM Method D7060. 25 [0065] "Pyrolysis" is the breaking of chemical bonds due to the application of heat. For example, pyrolysis may include transforming a compound into one or more other substances by heat alone. Heat may be transferred to a section of the formation to cause pyrolysis. [0066] "Pyrolyzation fluids" or "pyrolysis products" refers to fluid produced substantially during pyrolysis of hydrocarbons. Fluid produced by pyrolysis reactions may mix with other fluids in a 30 formation. The mixture would be considered pyrolyzation fluid or pyrolyzation product. As used herein, "pyrolysis zone" refers to a volume of a formation (for example, a relatively permeable formation such as a tar sands formation) that is reacted or reacting to form a pyrolyzation fluid. [0067] "Residue" refers to hydrocarbons that have a boiling point above 537 'C (1000 'F). 9 WO 2011/127292 PCT/US2011/031591 [0068] "Rich layers" in a hydrocarbon containing formation are relatively thin layers (typically about 0.2 m to about 0.5 m thick). Rich layers generally have a richness of about 0.150 L/kg or greater. Some rich layers have a richness of about 0.170 L/kg or greater, of about 0.190 L/kg or greater, or of about 0.210 L/kg or greater. Lean layers of the formation have a richness of about 5 0.100 L/kg or less and are generally thicker than rich layers. The richness and locations of layers are determined, for example, by coring and subsequent Fischer assay of the core, density or neutron logging, or other logging methods. Rich layers may have a lower initial thermal conductivity than other layers of the formation. Typically, rich layers have a thermal conductivity 1.5 times to 3 times lower than the thermal conductivity of lean layers. In addition, 10 rich layers have a higher thermal expansion coefficient than lean layers of the formation. [0069] "Slot" refers to a fissure in a hydrocarbon containing formation that is substantially perpendicular to a wellbore. A slot may be a groove, crevasse, planar opening, or pathway. A slot may be in any orientation. [0070] "Subsidence" is a downward movement of a portion of a formation relative to an initial 15 elevation of the surface. [0071] "Superposition of heat" refers to providing heat from two or more heat sources to a selected section of a formation such that the temperature of the formation at least at one location between the heat sources is influenced by the heat sources. [0072] "Synthesis gas" is a mixture including hydrogen and carbon monoxide. Additional 20 components of synthesis gas may include water, carbon dioxide, nitrogen, methane, and other gases. Synthesis gas may be generated by a variety of processes and feedstocks. Synthesis gas may be used for synthesizing a wide range of compounds. [0073] "Tar" is a viscous hydrocarbon that generally has a viscosity greater than about 10,000 centipoise at 15 'C. The specific gravity of tar generally is greater than 1.000. Tar may have an 25 API gravity less than 10'. [0074] A "tar sands formation" is a formation in which hydrocarbons are predominantly present in the form of heavy hydrocarbons and/or tar entrained in a mineral grain framework or other host lithology (for example, sand or carbonate). Examples of tar sands formations include formations such as the Athabasca formation, the Grosmont formation, and the Peace River 30 formation, all three in Alberta, Canada; and the Faja formation in the Orinoco belt in Venezuela. [0075] "Temperature limited heater" generally refers to a heater that regulates heat output (for example, reduces heat output) above a specified temperature without the use of external controls such as temperature controllers, power regulators, rectifiers, or other devices. Temperature limited heaters may be AC (alternating current) or modulated (for example, "chopped") DC 35 (direct current) powered electrical resistance heaters. 10 WO 2011/127292 PCT/US2011/031591 [0076] "Thermal fracture" refers to fractures created in a formation caused by expansion or contraction of a formation and/or fluids in the formation, which is in turn caused by increasing/decreasing the temperature of the formation and/or fluids in the formation, and/or by increasing/decreasing a pressure of fluids in the formation due to heating. 5 [0077] "Thermal oxidation stability" refers to thermal oxidation stability of a liquid. Thermal oxidation stability is as determined by ASTM Method D3241. [0078] "Thickness" of a layer refers to the thickness of a cross section of the layer, wherein the cross section is normal to a face of the layer. [0079] "Time-varying current" refers to electrical current that produces skin effect electricity 10 flow in a ferromagnetic conductor and has a magnitude that varies with time. Time-varying current includes both alternating current (AC) and modulated direct current (DC). [0080] A "u-shaped wellbore" refers to a wellbore that extends from a first opening in the formation, through at least a portion of the formation, and out through a second opening in the formation. In this context, the wellbore may be only roughly in the shape of a "v" or "u", with 15 the understanding that the "legs" of the "u" do not need to be parallel to each other, or perpendicular to the "bottom" of the "u" for the wellbore to be considered "u-shaped". [0081] "Upgrade" refers to increasing the quality of hydrocarbons. For example, upgrading heavy hydrocarbons may result in an increase in the API gravity of the heavy hydrocarbons. [0082] "Visbreaking" refers to the untangling of molecules in fluid during heat treatment and/or 20 to the breaking of large molecules into smaller molecules during heat treatment, which results in a reduction of the viscosity of the fluid. [0083] "Viscosity" refers to kinematic viscosity at 40 'C unless otherwise specified. Viscosity is as determined by ASTM Method D445. [0084] "Wax" refers to a low melting organic mixture, or a compound of high molecular weight 25 that is a solid at lower temperatures and a liquid at higher temperatures, and when in solid form can form a barrier to water. Examples of waxes include animal waxes, vegetable waxes, mineral waxes, petroleum waxes, and synthetic waxes. [0085] The term "wellbore" refers to a hole in a formation made by drilling or insertion of a conduit into the formation. A wellbore may have a substantially circular cross section, or another 30 cross-sectional shape. As used herein, the terms "well" and "opening," when referring to an opening in the formation may be used interchangeably with the term "wellbore." [0086] A formation may be treated in various ways to produce many different products. Different stages or processes may be used to treat the formation during an in situ heat treatment process. In some embodiments, one or more sections of the formation are solution mined to 35 remove soluble minerals from the sections. Solution mining minerals may be performed before, 11 WO 2011/127292 PCT/US2011/031591 during, and/or after the in situ heat treatment process. In some embodiments, the average temperature of one or more sections being solution mined may be maintained below about 120 0C. [0087] In some embodiments, one or more sections of the formation are heated to remove water 5 from the sections and/or to remove methane and other volatile hydrocarbons from the sections. In some embodiments, the average temperature may be raised from ambient temperature to temperatures below about 220 'C during removal of water and volatile hydrocarbons. [0088] In some embodiments, one or more sections of the formation are heated to temperatures that allow for movement and/or visbreaking of hydrocarbons in the formation. In some 10 embodiments, the average temperature of one or more sections of the formation are raised to mobilization temperatures of hydrocarbons in the sections (for example, to temperatures ranging from 100 'C to 250 'C, from 120 'C to 240 'C, or from 150 'C to 230 'C). [0089] In some embodiments, one or more sections are heated to temperatures that allow for pyrolysis reactions in the formation. In some embodiments, the average temperature of one or 15 more sections of the formation may be raised to pyrolysis temperatures of hydrocarbons in the sections (for example, temperatures ranging from 230 'C to 900 'C, from 240 'C to 400 'C or from 250 'C to 350 C). [0090] Heating the hydrocarbon containing formation with a plurality of heat sources may establish thermal gradients around the heat sources that raise the temperature of hydrocarbons in 20 the formation to desired temperatures at desired heating rates. The rate of temperature increase through the mobilization temperature range and/or the pyrolysis temperature range for desired products may affect the quality and quantity of the formation fluids produced from the hydrocarbon containing formation. Slowly raising the temperature of the formation through the mobilization temperature range and/or pyrolysis temperature range may allow for the production 25 of high quality, high API gravity hydrocarbons from the formation. Slowly raising the temperature of the formation through the mobilization temperature range and/or pyrolysis temperature range may allow for the removal of a large amount of the hydrocarbons present in the formation as hydrocarbon product. [0091] In some in situ heat treatment embodiments, a portion of the formation is heated to a 30 desired temperature instead of slowly raising the temperature through a temperature range. In some embodiments, the desired temperature is 300 'C, 325 C, or 350 'C. Other temperatures may be selected as the desired temperature. [0092] Superposition of heat from heat sources allows the desired temperature to be relatively quickly and efficiently established in the formation. Energy input into the formation from the 12 WO 2011/127292 PCT/US2011/031591 heat sources may be adjusted to maintain the temperature in the formation substantially at a desired temperature. [0093] Mobilization and/or pyrolysis products may be produced from the formation through production wells. In some embodiments, the average temperature of one or more sections is 5 raised to mobilization temperatures and hydrocarbons are produced from the production wells. The average temperature of one or more of the sections may be raised to pyrolysis temperatures after production due to mobilization decreases below a selected value. In some embodiments, the average temperature of one or more sections may be raised to pyrolysis temperatures without significant production before reaching pyrolysis temperatures. Formation fluids including 10 pyrolysis products may be produced through the production wells. [0094] In some embodiments, the average temperature of one or more sections may be raised to temperatures sufficient to allow synthesis gas production after mobilization and/or pyrolysis. In some embodiments, hydrocarbons may be raised to temperatures sufficient to allow synthesis gas production without significant production before reaching the temperatures sufficient to allow 15 synthesis gas production. For example, synthesis gas may be produced in a temperature range from about 400 'C to about 1200 'C, about 500 'C to about 1100 'C, or about 550 'C to about 1000 'C. A synthesis gas generating fluid (for example, steam and/or water) may be introduced into the sections to generate synthesis gas. Synthesis gas may be produced from production wells. 20 [0095] Solution mining, removal of volatile hydrocarbons and water, mobilizing hydrocarbons, pyrolyzing hydrocarbons, generating synthesis gas, and/or other processes may be performed during the in situ heat treatment process. In some embodiments, some processes may be performed after the in situ heat treatment process. Such processes may include, but are not limited to, recovering heat from treated sections, storing fluids (for example, water and/or 25 hydrocarbons) in previously treated sections, and/or sequestering carbon dioxide in previously treated sections. [0096] FIG. 1 depicts a schematic view of an embodiment of a portion of the in situ heat treatment system for treating the hydrocarbon containing formation. The in situ heat treatment system may include barrier wells 200. Barrier wells are used to form a barrier around a treatment 30 area. The barrier inhibits fluid flow into and/or out of the treatment area. Barrier wells include, but are not limited to, dewatering wells, vacuum wells, capture wells, injection wells, grout wells, freeze wells, or combinations thereof. In some embodiments, barrier wells 200 are dewatering wells. Dewatering wells may remove liquid water and/or inhibit liquid water from entering a portion of the formation to be heated, or to the formation being heated. In the embodiment 35 depicted in FIG. 1, the barrier wells 200 are shown extending only along one side of heat sources 13 WO 2011/127292 PCT/US2011/031591 202, but the barrier wells typically encircle all heat sources 202 used, or to be used, to heat a treatment area of the formation. [0097] Heat sources 202 are placed in at least a portion of the formation. Heat sources 202 may include heaters such as insulated conductors, conductor-in-conduit heaters, surface burners, 5 flameless distributed combustors, and/or natural distributed combustors. Heat sources 202 may also include other types of heaters. Heat sources 202 provide heat to at least a portion of the formation to heat hydrocarbons in the formation. Energy may be supplied to heat sources 202 through supply lines 204. Supply lines 204 may be structurally different depending on the type of heat source or heat sources used to heat the formation. Supply lines 204 for heat sources may 10 transmit electricity for electric heaters, may transport fuel for combustors, or may transport heat exchange fluid that is circulated in the formation. In some embodiments, electricity for an in situ heat treatment process may be provided by a nuclear power plant or nuclear power plants. The use of nuclear power may allow for reduction or elimination of carbon dioxide emissions from the in situ heat treatment process. 15 [0098] When the formation is heated, the heat input into the formation may cause expansion of the formation and geomechanical motion. The heat sources may be turned on before, at the same time, or during a dewatering process. Computer simulations may model formation response to heating. The computer simulations may be used to develop a pattern and time sequence for activating heat sources in the formation so that geomechanical motion of the formation does not 20 adversely affect the functionality of heat sources, production wells, and other equipment in the formation. [0099] Heating the formation may cause an increase in permeability and/or porosity of the formation. Increases in permeability and/or porosity may result from a reduction of mass in the formation due to vaporization and removal of water, removal of hydrocarbons, and/or creation of 25 fractures. Fluid may flow more easily in the heated portion of the formation because of the increased permeability and/or porosity of the formation. Fluid in the heated portion of the formation may move a considerable distance through the formation because of the increased permeability and/or porosity. The considerable distance may be over 1000 m depending on various factors, such as permeability of the formation, properties of the fluid, temperature of the 30 formation, and pressure gradient allowing movement of the fluid. The ability of fluid to travel considerable distance in the formation allows production wells 206 to be spaced relatively far apart in the formation. [0100] Production wells 206 are used to remove formation fluid from the formation. In some embodiments, production well 206 includes a heat source. The heat source in the production 35 well may heat one or more portions of the formation at or near the production well. In some in 14 WO 2011/127292 PCT/US2011/031591 situ heat treatment process embodiments, the amount of heat supplied to the formation from the production well per meter of the production well is less than the amount of heat applied to the formation from a heat source that heats the formation per meter of the heat source. Heat applied to the formation from the production well may increase formation permeability adjacent to the 5 production well by vaporizing and removing liquid phase fluid adjacent to the production well and/or by increasing the permeability of the formation adjacent to the production well by formation of macro and/or micro fractures. [0101] More than one heat source may be positioned in the production well. A heat source in a lower portion of the production well may be turned off when superposition of heat from adjacent 10 heat sources heats the formation sufficiently to counteract benefits provided by heating the formation with the production well. In some embodiments, the heat source in an upper portion of the production well may remain on after the heat source in the lower portion of the production well is deactivated. The heat source in the upper portion of the well may inhibit condensation and reflux of formation fluid. 15 [0102] In some embodiments, the heat source in production well 206 allows for vapor phase removal of formation fluids from the formation. Providing heating at or through the production well may: (1) inhibit condensation and/or refluxing of production fluid when such production fluid is moving in the production well proximate the overburden, (2) increase heat input into the formation, (3) increase production rate from the production well as compared to a production 20 well without a heat source, (4) inhibit condensation of high carbon number compounds (C 6 hydrocarbons and above) in the production well, and/or (5) increase formation permeability at or proximate the production well. [0103] Subsurface pressure in the formation may correspond to the fluid pressure generated in the formation. As temperatures in the heated portion of the formation increase, the pressure in 25 the heated portion may increase as a result of thermal expansion of in situ fluids, increased fluid generation and vaporization of water. Controlling rate of fluid removal from the formation may allow for control of pressure in the formation. Pressure in the formation may be determined at a number of different locations, such as near or at production wells, near or at heat sources, or at monitor wells. 30 [0104] In some hydrocarbon containing formations, production of hydrocarbons from the formation is inhibited until at least some hydrocarbons in the formation have been mobilized and/or pyrolyzed. Formation fluid may be produced from the formation when the formation fluid is of a selected quality. In some embodiments, the selected quality includes an API gravity of at least about 200, 30', or 40'. Inhibiting production until at least some hydrocarbons are mobilized 35 and/or pyrolyzed may increase conversion of heavy hydrocarbons to light hydrocarbons. 15 WO 2011/127292 PCT/US2011/031591 Inhibiting initial production may minimize the production of heavy hydrocarbons from the formation. Production of substantial amounts of heavy hydrocarbons may require expensive equipment and/or reduce the life of production equipment. [0105] In some hydrocarbon containing formations, hydrocarbons in the formation may be 5 heated to mobilization and/or pyrolysis temperatures before substantial permeability has been generated in the heated portion of the formation. An initial lack of permeability may inhibit the transport of generated fluids to production wells 206. During initial heating, fluid pressure in the formation may increase proximate heat sources 202. The increased fluid pressure may be released, monitored, altered, and/or controlled through one or more heat sources 202. For 10 example, selected heat sources 202 or separate pressure relief wells may include pressure relief valves that allow for removal of some fluid from the formation. [0106] In some embodiments, pressure generated by expansion of mobilized fluids, pyrolysis fluids or other fluids generated in the formation may be allowed to increase because an open path to production wells 206 or any other pressure sink may not yet exist in the formation. The fluid 15 pressure may be allowed to increase towards a lithostatic pressure. Fractures in the hydrocarbon containing formation may form when the fluid approaches the minimal in situ stress. In some embodiments, the minimal in situ stress may be equal to or approximate the lithostatic pressure of the hydrocarbon formation. For example, fractures may form from heat sources 202 to production wells 206 in the heated portion of the formation. The generation of fractures in the 20 heated portion may relieve some of the pressure in the portion. Pressure in the formation may have to be maintained below a selected pressure to inhibit unwanted production, fracturing of the overburden or underburden, and/or coking of hydrocarbons in the formation. [0107] After mobilization and/or pyrolysis temperatures are reached and production from the formation is allowed, pressure in the formation may be varied to alter and/or control a 25 composition of produced formation fluid, to control a percentage of condensable fluid as compared to non-condensable fluid in the formation fluid, and/or to control an API gravity of formation fluid being produced. For example, decreasing pressure may result in production of a larger condensable fluid component. The condensable fluid component may contain a larger percentage of olefins. 30 [0108] In some in situ heat treatment process embodiments, pressure in the formation may be maintained high enough to promote production of formation fluid with an API gravity of greater than 20'. Maintaining increased pressure in the formation may inhibit formation subsidence during in situ heat treatment. Maintaining increased pressure may reduce or eliminate the need to compress formation fluids at the surface to transport the fluids in collection conduits to treatment 35 facilities. 16 WO 2011/127292 PCT/US2011/031591 [0109] Maintaining increased pressure in a heated portion of the formation may surprisingly allow for production of large quantities of hydrocarbons of increased quality and of relatively low molecular weight. Pressure may be maintained so that formation fluid produced has a minimal amount of compounds above a selected carbon number. The selected carbon number 5 may be at most 25, at most 20, at most 12, or at most 8. Some high carbon number compounds may be entrained in vapor in the formation and may be removed from the formation with the vapor. Maintaining increased pressure in the formation may inhibit entrainment of high carbon number compounds and/or multi-ring hydrocarbon compounds in the vapor. High carbon number compounds and/or multi-ring hydrocarbon compounds may remain in a liquid phase in 10 the formation for significant time periods. The significant time periods may provide sufficient time for the compounds to pyrolyze to form lower carbon number compounds. [0110] Generation of relatively low molecular weight hydrocarbons is believed to be due, in part, to autogenous generation and reaction of hydrogen in a portion of the hydrocarbon containing formation. For example, maintaining an increased pressure may force hydrogen generated during 15 pyrolysis into the liquid phase within the formation. Heating the portion to a temperature in a pyrolysis temperature range may pyrolyze hydrocarbons in the formation to generate liquid phase pyrolyzation fluids. The generated liquid phase pyrolyzation fluids components may include double bonds and/or radicals. Hydrogen (H 2 ) in the liquid phase may reduce double bonds of the generated pyrolyzation fluids, thereby reducing a potential for polymerization or formation of 20 long chain compounds from the generated pyrolyzation fluids. In addition, H 2 may also neutralize radicals in the generated pyrolyzation fluids. H 2 in the liquid phase may inhibit the generated pyrolyzation fluids from reacting with each other and/or with other compounds in the formation. [0111] Formation fluid produced from production wells 206 may be transported through 25 collection piping 208 to treatment facilities 210. Formation fluids may also be produced from heat sources 202. For example, fluid may be produced from heat sources 202 to control pressure in the formation adjacent to the heat sources. Fluid produced from heat sources 202 may be transported through tubing or piping to collection piping 208 or the produced fluid may be transported through tubing or piping directly to treatment facilities 210. Treatment facilities 210 30 may include separation units, reaction units, upgrading units, fuel cells, turbines, storage vessels, and/or other systems and units for processing produced formation fluids. The treatment facilities may form transportation fuel from at least a portion of the hydrocarbons produced from the formation. In some embodiments, the transportation fuel may be jet fuel, such as JP-8. [0112] An insulated conductor may be used as an electric heater element of a heater or a heat 35 source. The insulated conductor may include an inner electrical conductor (core) surrounded by 17 WO 2011/127292 PCT/US2011/031591 an electrical insulator and an outer electrical conductor (jacket). The electrical insulator may include mineral insulation (for example, magnesium oxide) or other electrical insulation. [0113] In certain embodiments, the insulated conductor is placed in an opening in a hydrocarbon containing formation. In some embodiments, the insulated conductor is placed in an uncased 5 opening in the hydrocarbon containing formation. Placing the insulated conductor in an uncased opening in the hydrocarbon containing formation may allow heat transfer from the insulated conductor to the formation by radiation as well as conduction. Using an uncased opening may facilitate retrieval of the insulated conductor from the well, if necessary. [0114] In some embodiments, an insulated conductor is placed within a casing in the formation; 10 may be cemented within the formation; or may be packed in an opening with sand, gravel, or other fill material. The insulated conductor may be supported on a support member positioned within the opening. The support member may be a cable, rod, or a conduit (for example, a pipe). The support member may be made of a metal, ceramic, inorganic material, or combinations thereof. Because portions of a support member may be exposed to formation fluids and heat 15 during use, the support member may be chemically resistant and/or thermally resistant. [0115] Ties, spot welds, and/or other types of connectors may be used to couple the insulated conductor to the support member at various locations along a length of the insulated conductor. The support member may be attached to a wellhead at an upper surface of the formation. In some embodiments, the insulated conductor has sufficient structural strength such that a support 20 member is not needed. The insulated conductor may, in many instances, have at least some flexibility to inhibit thermal expansion damage when undergoing temperature changes. [0116] In certain embodiments, insulated conductors are placed in wellbores without support members and/or centralizers. An insulated conductor without support members and/or centralizers may have a suitable combination of temperature and corrosion resistance, creep 25 strength, length, thickness (diameter), and metallurgy that will inhibit failure of the insulated conductor during use. [0117] FIG. 2 depicts a perspective view of an end portion of an embodiment of heater 212. Heater 212 may include insulated conductor 214. Insulated conductor 214 may have any desired cross-sectional shape such as, but not limited to, round (depicted in FIG. 2), triangular, 30 ellipsoidal, rectangular, hexagonal, or irregular. In certain embodiments, insulated conductor 214 includes jacket 216, core 218, and electrical insulator 220. Core 218 may resistively heat when an electrical current passes through the core. Alternating or time-varying current and/or direct current may be used to provide power to core 218 such that the core resistively heats. [0118] In some embodiments, electrical insulator 220 inhibits current leakage and arcing to 35 jacket 216. Electrical insulator 220 may thermally conduct heat generated in core 218 to jacket 18 WO 2011/127292 PCT/US2011/031591 216. Jacket 216 may radiate or conduct heat to the formation. In certain embodiments, insulated conductor 214 is 1000 m or more in length. Longer or shorter insulated conductors may also be used to meet specific application needs. The dimensions of core 218, electrical insulator 220, and jacket 216 of insulated conductor 214 may be selected such that the insulated conductor has 5 enough strength to be self supporting even at upper working temperature limits. Such insulated conductors may be suspended from wellheads or supports positioned near an interface between an overburden and a hydrocarbon containing formation without the need for support members extending into the hydrocarbon containing formation along with the insulated conductors. [0119] Insulated conductor 214 may be designed to operate at power levels of up to about 1650 10 watts/meter or higher. In certain embodiments, insulated conductor 214 operates at a power level between about 500 watts/meter and about 1150 watts/meter when heating a formation. Insulated conductor 214 may be designed so that a maximum voltage level at a typical operating temperature does not cause substantial thermal and/or electrical breakdown of electrical insulator 220. Insulated conductor 214 may be designed such that jacket 216 does not exceed a 15 temperature that will result in a significant reduction in corrosion resistance properties of the jacket material. In certain embodiments, insulated conductor 214 may be designed to reach temperatures within a range between about 650 'C and about 900 'C. Insulated conductors having other operating ranges may be formed to meet specific operational requirements. [0120] FIG. 2 depicts insulated conductor 214 having a single core 218. In some embodiments, 20 insulated conductor 214 has two or more cores 218. For example, a single insulated conductor may have three cores. Core 218 may be made of metal or another electrically conductive material. The material used to form core 218 may include, but not be limited to, nichrome, copper, nickel, carbon steel, stainless steel, and combinations thereof. In certain embodiments, core 218 is chosen to have a diameter and a resistivity at operating temperatures such that its 25 resistance, as derived from Ohm's law, makes it electrically and structurally stable for the chosen power dissipation per meter, the length of the heater, and/or the maximum voltage allowed for the core material. [0121] In some embodiments, core 218 is made of different materials along a length of insulated conductor 214. For example, a first section of core 218 may be made of a material that has a 30 significantly lower resistance than a second section of the core. The first section may be placed adjacent to a formation layer that does not need to be heated to as high a temperature as a second formation layer that is adjacent to the second section. The resistivity of various sections of core 218 may be adjusted by having a variable diameter and/or by having core sections made of different materials. 19 WO 2011/127292 PCT/US2011/031591 [0122] Electrical insulator 220 may be made of a variety of materials. Commonly used powders may include, but are not limited to, MgO, A1 2 0 3 , Zirconia, BeO, different chemical variations of Spinels, and combinations thereof. MgO may provide good thermal conductivity and electrical insulation properties. The desired electrical insulation properties include low leakage current and 5 high dielectric strength. A low leakage current decreases the possibility of thermal breakdown and the high dielectric strength decreases the possibility of arcing across the insulator. Thermal breakdown can occur if the leakage current causes a progressive rise in the temperature of the insulator leading also to arcing across the insulator. [0123] Jacket 216 may be an outer metallic layer or electrically conductive layer. Jacket 216 10 may be in contact with hot formation fluids. Jacket 216 may be made of material having a high resistance to corrosion at elevated temperatures. Alloys that may be used in a desired operating temperature range of jacket 216 include, but are not limited to, 304 stainless steel, 310 stainless steel, Incoloy@ 800, and Inconel@ 600 (Inco Alloys International, Huntington, West Virginia, U.S.A.). The thickness of jacket 216 may have to be sufficient to last for three to ten years in a 15 hot and corrosive environment. A thickness of jacket 216 may generally vary between about 1 mm and about 2.5 mm. For example, a 1.3 mm thick, 310 stainless steel outer layer may be used as jacket 216 to provide good chemical resistance to sulfidation corrosion in a heated zone of a formation for a period of over 3 years. Larger or smaller jacket thicknesses may be used to meet specific application requirements. 20 [0124] One or more insulated conductors may be placed within an opening in a formation to form a heat source or heat sources. Electrical current may be passed through each insulated conductor in the opening to heat the formation. Alternately, electrical current may be passed through selected insulated conductors in an opening. The unused conductors may be used as backup heaters. Insulated conductors may be electrically coupled to a power source in any 25 convenient manner. Each end of an insulated conductor may be coupled to lead-in cables that pass through a wellhead. Such a configuration typically has a 180' bend (a "hairpin" bend) or turn located near a bottom of the heat source. An insulated conductor that includes a 1800 bend or turn may not require a bottom termination, but the 1800 bend or turn may be an electrical and/or structural weakness in the heater. Insulated conductors may be electrically coupled 30 together in series, in parallel, or in series and parallel combinations. In some embodiments of heat sources, electrical current may pass into the conductor of an insulated conductor and may be returned through the jacket of the insulated conductor by connecting core 218 to jacket 216 (shown in FIG. 2) at the bottom of the heat source. [0125] In some embodiments, three insulated conductors 214 are electrically coupled in a 3 35 phase wye configuration to a power supply. FIG. 3 depicts an embodiment of three insulated 20 WO 2011/127292 PCT/US2011/031591 conductors in an opening in a subsurface formation coupled in a wye configuration. FIG. 4 depicts an embodiment of three insulated conductors 214 that are removable from opening 222 in the formation. No bottom connection may be required for three insulated conductors in a wye configuration. Alternately, all three insulated conductors of the wye configuration may be 5 connected together near the bottom of the opening. The connection may be made directly at ends of heating sections of the insulated conductors or at ends of cold pins (less resistive sections) coupled to the heating sections at the bottom of the insulated conductors. The bottom connections may be made with insulator filled and sealed canisters or with epoxy filled canisters. The insulator may be the same composition as the insulator used as the electrical insulation. 10 [0126] Three insulated conductors 214 depicted in FIGS. 3 and 4 may be coupled to support member 224 using centralizers 226. Alternatively, insulated conductors 214 may be strapped directly to support member 224 using metal straps. Centralizers 226 may maintain a location and/or inhibit movement of insulated conductors 214 on support member 224. Centralizers 226 may be made of metal, ceramic, or combinations thereof. The metal may be stainless steel or any 15 other type of metal able to withstand a corrosive and high temperature environment. In some embodiments, centralizers 226 are bowed metal strips welded to the support member at distances less than about 6 m. A ceramic used in centralizer 226 may be, but is not limited to, A1 2 0 3 , MgO, or another electrical insulator. Centralizers 226 may maintain a location of insulated conductors 214 on support member 224 such that movement of insulated conductors is inhibited 20 at operating temperatures of the insulated conductors. Insulated conductors 214 may also be somewhat flexible to withstand expansion of support member 224 during heating. [0127] Support member 224, insulated conductor 214, and centralizers 226 may be placed in opening 222 in hydrocarbon layer 228. Insulated conductors 214 may be coupled to bottom conductor junction 230 using cold pin 232. Bottom conductor junction 230 may electrically 25 couple each insulated conductor 214 to each other. Bottom conductor junction 230 may include materials that are electrically conducting and do not melt at temperatures found in opening 222. Cold pin 232 may be an insulated conductor having lower electrical resistance than insulated conductor 214. [0128] Lead-in conductor 234 may be coupled to wellhead 238 to provide electrical power to 30 insulated conductor 214. Lead-in conductor 234 may be made of a relatively low electrical resistance conductor such that relatively little heat is generated from electrical current passing through the lead-in conductor. In some embodiments, the lead-in conductor is a rubber or polymer insulated stranded copper wire. In some embodiments, the lead-in conductor is a mineral insulated conductor with a copper core. Lead-in conductor 234 may couple to wellhead 21 WO 2011/127292 PCT/US2011/031591 238 at surface 240 through a sealing flange located between overburden 242 and surface 240. The sealing flange may inhibit fluid from escaping from opening 222 to surface 240. [0129] In certain embodiments, lead-in conductor 234 is coupled to insulated conductor 214 using transition conductor 244. Transition conductor 244 may be a less resistive portion of 5 insulated conductor 2141. Transition conductor 244 may be referred to as "cold pin" of insulated conductor 214. Transition conductor 244 may be designed to dissipate about one-tenth to about one-fifth of the power per unit length as is dissipated in a unit length of the primary heating section of insulated conductor 214. Transition conductor 244 may typically be between about 1.5 m and about 15 m, although shorter or longer lengths may be used to accommodate specific 10 application needs. In an embodiment, the conductor of transition conductor 244 is copper. The electrical insulator of transition conductor 244 may be the same type of electrical insulator used in the primary heating section. A jacket of transition conductor 244 may be made of corrosion resistant material. [0130] In certain embodiments, transition conductor 244 is coupled to lead-in conductor 234 by a 15 splice or other coupling joint. Splices may also be used to couple transition conductor 244 to insulated conductor 214. Splices may have to withstand a temperature equal to half of a target zone operating temperature. Density of electrical insulation in the splice should in many instances be high enough to withstand the required temperature and the operating voltage. [0131] In some embodiments, as shown in FIG. 3, packing material 246 is placed between 20 overburden casing 248 and opening 222. In some embodiments, reinforcing material 250 may secure overburden casing 248 to overburden 242. Packing material 246 may inhibit fluid from flowing from opening 222 to surface 240. Reinforcing material 250 may include, for example, Class G or Class H Portland cement mixed with silica flour for improved high temperature performance, slag or silica flour, and/or a mixture thereof. In some embodiments, reinforcing 25 material 250 extends radially a width of from about 5 cm to about 25 cm. [0132] As shown in FIGS. 3 and 4, support member 224 and lead-in conductor 234 may be coupled to wellhead 238 at surface 240 of the formation. Surface conductor 236 may enclose reinforcing material 250 and couple to wellhead 238. Embodiments of surface conductors may extend to depths of approximately 3m to approximately 515 mn into an opening in the formation. 30 Alternatively, the surface conductor may extend to a depth of approximately 9 m into the formation. Electrical current may be supplied from a power source to insulated conductor 214 to generate heat due to the electrical resistance of the insulated conductor. Heat generated from three insulated conductors 214 may transfer within opening 222 to heat at least a portion of hydrocarbon layer 228. 22 WO 2011/127292 PCT/US2011/031591 [0133] Heat generated by insulated conductors 214 may heat at least a portion of a hydrocarbon containing formation. In some embodiments, heat is transferred to the formation substantially by radiation of the generated heat to the formation. Some heat may be transferred by conduction or convection of heat due to gases present in the opening. The opening may be an uncased opening, 5 as shown in FIGS. 3 and 4. An uncased opening eliminates cost associated with thermally cementing the heater to the formation, costs associated with a casing, and/or costs of packing a heater within an opening. In addition, heat transfer by radiation is typically more efficient than by conduction, so the heaters may be operated at lower temperatures in an open wellbore. Conductive heat transfer during initial operation of a heat source may be enhanced by the 10 addition of a gas in the opening. The gas may be maintained at a pressure up to about 27 bars absolute. The gas may include, but is not limited to, carbon dioxide and/or helium. An insulated conductor heater in an open wellbore may advantageously be free to expand or contract to accommodate thermal expansion and contraction. An insulated conductor heater may advantageously be removable or redeployable from an open wellbore. 15 [0134] In certain embodiments, an insulated conductor heater assembly is installed or removed using a spooling assembly. More than one spooling assembly may be used to install both the insulated conductor and a support member simultaneously. Alternatively, the support member may be installed using a coiled tubing unit. The heaters may be un-spooled and connected to the support as the support is inserted into the well. The electric heater and the support member may 20 be un-spooled from the spooling assemblies. Spacers may be coupled to the support member and the heater along a length of the support member. Additional spooling assemblies may be used for additional electric heater elements. [0135] Temperature limited heaters may be in configurations and/or may include materials that provide automatic temperature limiting properties for the heater at certain temperatures. In 25 certain embodiments, ferromagnetic materials are used in temperature limited heaters. Ferromagnetic material may self-limit temperature at or near the Curie temperature of the material and/or the phase transformation temperature range to provide a reduced amount of heat when a time-varying current is applied to the material. In certain embodiments, the ferromagnetic material self-limits temperature of the temperature limited heater at a selected 30 temperature that is approximately the Curie temperature and/or in the phase transformation temperature range. In certain embodiments, the selected temperature is within about 35 'C, within about 25 'C, within about 20 'C, or within about 10 'C of the Curie temperature and/or the phase transformation temperature range. In certain embodiments, ferromagnetic materials are coupled with other materials (for example, highly conductive materials, high strength materials, 35 corrosion resistant materials, or combinations thereof) to provide various electrical and/or 23 WO 2011/127292 PCT/US2011/031591 mechanical properties. Some parts of the temperature limited heater may have a lower resistance (caused by different geometries and/or by using different ferromagnetic and/or non ferromagnetic materials) than other parts of the temperature limited heater. Having parts of the temperature limited heater with various materials and/or dimensions allows for tailoring the 5 desired heat output from each part of the heater. [0136] Temperature limited heaters may be more reliable than other heaters. Temperature limited heaters may be less apt to break down or fail due to hot spots in the formation. In some embodiments, temperature limited heaters allow for substantially uniform heating of the formation. In some embodiments, temperature limited heaters are able to heat the formation 10 more efficiently by operating at a higher average heat output along the entire length of the heater. The temperature limited heater operates at the higher average heat output along the entire length of the heater because power to the heater does not have to be reduced to the entire heater, as is the case with typical constant wattage heaters, if a temperature along any point of the heater exceeds, or is about to exceed, a maximum operating temperature of the heater. Heat output 15 from portions of a temperature limited heater approaching a Curie temperature and/or the phase transformation temperature range of the heater automatically reduces without controlled adjustment of the time-varying current applied to the heater. The heat output automatically reduces due to changes in electrical properties (for example, electrical resistance) of portions of the temperature limited heater. Thus, more power is supplied by the temperature limited heater 20 during a greater portion of a heating process. [0137] In certain embodiments, the system including temperature limited heaters initially provides a first heat output and then provides a reduced (second heat output) heat output, near, at, or above the Curie temperature and/or the phase transformation temperature range of an electrically resistive portion of the heater when the temperature limited heater is energized by a 25 time-varying current. The first heat output is the heat output at temperatures below which the temperature limited heater begins to self-limit. In some embodiments, the first heat output is the heat output at a temperature about 50 'C, about 75 'C, about 100 'C, or about 125 'C below the Curie temperature and/or the phase transformation temperature range of the ferromagnetic material in the temperature limited heater. 30 [0138] The temperature limited heater may be energized by time-varying current (alternating current or modulated direct current) supplied at the wellhead. The wellhead may include a power source and other components (for example, modulation components, transformers, and/or capacitors) used in supplying power to the temperature limited heater. The temperature limited heater may be one of many heaters used to heat a portion of the formation. 24 WO 2011/127292 PCT/US2011/031591 [0139] In some embodiments, a relatively thin conductive layer is used to provide the majority of the electrically resistive heat output of the temperature limited heater at temperatures up to a temperature at or near the Curie temperature and/or the phase transformation temperature range of the ferromagnetic conductor. Such a temperature limited heater may be used as the heating 5 member in an insulated conductor heater. The heating member of the insulated conductor heater may be located inside a sheath with an insulation layer between the sheath and the heating member. [0140] FIGS. 5A and 5B depict cross-sectional representations of an embodiment of the insulated conductor heater with the temperature limited heater as the heating member. Insulated 10 conductor 214 includes core 218, ferromagnetic conductor 252, inner conductor 254, electrical insulator 220, and jacket 216. Core 218 is a copper core. Ferromagnetic conductor 252 is, for example, iron or an iron alloy. [0141] Inner conductor 254 is a relatively thin conductive layer of non-ferromagnetic material with a higher electrical conductivity than ferromagnetic conductor 252. In certain embodiments, 15 inner conductor 254 is copper. Inner conductor 254 may be a copper alloy. Copper alloys typically have a flatter resistance versus temperature profile than pure copper. A flatter resistance versus temperature profile may provide less variation in the heat output as a function of temperature up to the Curie temperature and/or the phase transformation temperature range. In some embodiments, inner conductor 254 is copper with 6% by weight nickel (for example, 20 CuNi 6 or LOHMTM). In some embodiments, inner conductor 254 is CuNiiOFe 1 Mn alloy. Below the Curie temperature and/or the phase transformation temperature range of ferromagnetic conductor 252, the magnetic properties of the ferromagnetic conductor confine the majority of the flow of electrical current to inner conductor 254. Thus, inner conductor 254 provides the majority of the resistive heat output of insulated conductor 214 below the Curie temperature 25 and/or the phase transformation temperature range. [0142] In certain embodiments, inner conductor 254 is dimensioned, along with core 218 and ferromagnetic conductor 252, so that the inner conductor provides a desired amount of heat output and a desired turndown ratio. For example, inner conductor 254 may have a cross sectional area that is around 2 or 3 times less than the cross-sectional area of core 218. Typically, 30 inner conductor 254 has to have a relatively small cross-sectional area to provide a desired heat output if the inner conductor is copper or copper alloy. In an embodiment with copper inner conductor 254, core 218 has a diameter of 0.66 cm, ferromagnetic conductor 252 has an outside diameter of 0.91 cm, inner conductor 254 has an outside diameter of 1.03 cm, electrical insulator 220 has an outside diameter of 1.53 cm, and jacket 216 has an outside diameter of 1.79 cm. In an 35 embodiment with a CuNi 6 inner conductor 254, core 218 has a diameter of 0.66 cm, 25 WO 2011/127292 PCT/US2011/031591 ferromagnetic conductor 252 has an outside diameter of 0.91 cm, inner conductor 254 has an outside diameter of 1.12 cm, electrical insulator 220 has an outside diameter of 1.63 cm, and jacket 216 has an outside diameter of 1.88 cm. Such insulated conductors are typically smaller and cheaper to manufacture than insulated conductors that do not use the thin inner conductor to 5 provide the majority of heat output below the Curie temperature and/or the phase transformation temperature range. [0143] Electrical insulator 220 may be magnesium oxide, aluminum oxide, silicon dioxide, beryllium oxide, boron nitride, silicon nitride, or combinations thereof. In certain embodiments, electrical insulator 220 is a compacted powder of magnesium oxide. In some embodiments, 10 electrical insulator 220 includes beads of silicon nitride. [0144] In certain embodiments, a small layer of material is placed between electrical insulator 220 and inner conductor 254 to inhibit copper from migrating into the electrical insulator at higher temperatures. For example, a small layer of nickel (for example, about 0.5 mm of nickel) may be placed between electrical insulator 220 and inner conductor 254. 15 [0145] Jacket 216 is made of a corrosion resistant material such as, but not limited to, 347 stainless steel, 347H stainless steel, 446 stainless steel, or 825 stainless steel. In some embodiments, jacket 216 provides some mechanical strength for insulated conductor 214 at or above the Curie temperature and/or the phase transformation temperature range of ferromagnetic conductor 252. In certain embodiments, jacket 216 is not used to conduct electrical current. 20 [0146] Oil shale formations may have a number of properties that depend on a composition of the hydrocarbons within the formation. Such properties may affect the composition and amount of products that are produced from the oil shale formation during an in situ heat treatment process (for example, an in situ conversion process). Properties of an oil shale formation may be used to determine if and/or how the oil shale formation is to be subjected to the in situ heat 25 treatment process. [0147] Kerogen is composed of organic matter that has been transformed due to a maturation process. The maturation process for kerogen may include two stages: a biochemical stage and a geochemical stage. The biochemical stage typically involves degradation of organic material by aerobic and/or anaerobic organisms. The geochemical stage typically involves conversion of 30 organic matter due to temperature changes and significant pressures. During maturation, oil and gas may be produced as the organic matter of the kerogen is transformed. Kerogen may be classified into four distinct groups: Type I, Type II, Type III, and Type IV. Classification of kerogen type may depend upon precursor materials of the kerogen. The precursor materials transform over time into macerals. Macerals are microscopic structures that have different 35 structures and properties depending on the precursor materials from which they are derived. 26 WO 2011/127292 PCT/US2011/031591 [0148] Type I kerogen may be classified as an alginite, since it is developed primarily from algal bodies. Type I kerogen may result from deposits made in lacustrine environments. Type II kerogen may develop from organic matter that was deposited in marine environments. Type III kerogen may generally include vitrinite macerals. Vitrinite is derived from cell walls and/or 5 woody tissues (for example, stems, branches, leaves, and roots of plants). Type III kerogen may be present in most humic coals. Type III kerogen may develop from organic matter that was deposited in swamps. Type IV kerogen includes the inertinite maceral group. The inertinite maceral group is composed of plant material such as leaves, bark, and stems that have undergone oxidation during the early peat stages of burial diagenesis. Inertinite maceral is chemically 10 similar to vitrinite, but has a high carbon and low hydrogen content. [0149] Vitrinite reflectance may be used to assess the quality of fluids produced from certain kerogen containing formations. Formations that include kerogen may be assessed/selected for treatment based on a vitrinite reflectance of the kerogen. Vitrinite reflectance is often related to a hydrogen to carbon atomic ratio of a kerogen and an oxygen to carbon atomic ratio of the 15 kerogen. Vitrinite reflectance of a hydrocarbon containing formation may indicate which fluids are producible from a formation upon heating. For example, a vitrinite reflectance of approximately 0.5% to approximately 1.5% may indicate that the kerogen will produce a large quantity of condensable fluids. A vitrinite reflectance of approximately 1.5% to 3.0% may indicate a kerogen having a H/C molar ratio between about 0.25 to about 0.9. Heating of a 20 hydrocarbon formation having a vitrinite reflectance of approximately 1.5% to 3.0% may produce a significant amount (for example, a majority) of methane and hydrogen. [0150] In some embodiments, a hydrocarbon containing formation is treated using an in situ heat treatment process to remove methane from the formation. The hydrocarbon containing formation may be an oil shale formation and/or contain coal. In some embodiments, a barrier is formed 25 around the portion to be heated. In some embodiments, the hydrocarbon containing formation includes a coal containing layer (a deep coal seam) underneath a layer of oil shale. The coal containing layer may contain significantly more methane than the oil shale layer. For example, the coal containing layer may have a volume of methane that is five times greater than a volume of methane in the oil shale layer. Wellbores may be formed that extend through the oil shale 30 layer into the coal containing layer. Treatment of a hydrocarbon layer (for example, an oil shale layer) followed by thermal desorption of the hydrocarbons from a coal layer beneath the hydrocarbon layer allows for economical production of hydrocarbons from a portion of the hydrocarbon formation that was previously inaccessible. [0151] Heat may be provided to the hydrocarbon containing formation from a plurality of heaters 35 located in the formation. One or more of the heaters may be temperature limited heaters and or 27 WO 2011/127292 PCT/US2011/031591 one or more insulated conductors (for example, a mineral insulated conductor). The heating may be controlled to allow treatment of the oil shale layer while maintaining a temperature of the coal containing layer below a pyrolysis temperature. [0152] FIGS. 6A and 6B depict a representation of an embodiment of heating a hydrocarbon 5 formation containing a coal layer. Hydrocarbon formation may include overburden 242, hydrocarbon layer 228 (for example, an oil shale layer), and impermeable containing layer 256. Coal layer 256 may be a deep coal seam and/or a coal bed. Coal layer 256 may be below or substantially below hydrocarbon containing layer 228. Heaters 212 may be initially positioned in hydrocarbon layer 228. Heaters 212 may be vertical or horizontal heaters. Any pattern or 10 number of heaters may be used to heat the layers. Hydrocarbon layer 228 may be heated for a period of time with heaters 212 to mobilize hydrocarbons in the layer. The mobilized hydrocarbons may be produced from the hydrocarbon layer using production well 206. [0153] After treatment of hydrocarbon layer 228, heaters 212 may be provided (for example, extended or moved) to coal containing layer 256 as shown in FIG. 6B. Heater 212 may be an 15 insulated electrical conductor (for example, a mineral insulated electrical conductor). For example, a mineral insulated electrical conductor may be extended from an oil shale layer into a deep coal seam layer after in situ heat treatment of the oil shale layer with the insulated electrical conductor. The temperature in coal containing layer 256 may be maintained below a pyrolysis temperature of hydrocarbons in the formation. In some embodiments, coal containing layer 256 20 is maintained at a temperature between about 30 'C and about 200 'C or between 40'C and 150 C or between 50 'C and 100 'C. In some embodiments, coal containing layer 256 is maintained at a temperature between about 30 'C and about 40 'C. As the temperature of coal containing layer 256 increases, methane may be released from the formation. The methane may be produced from the hydrocarbon formation. For example, methane may be produced using 25 production well 206 positioned in hydrocarbon layer 228. In some embodiments, hydrocarbons having a carbon number between 1 and 5 are released from the coal continuing layer of the formation and produced from the formation. [0154] In some embodiments, slots or fissures are created in a hydrocarbon layer that has low permeability (for example, an oil shale layer and/or a coal containing layer) to enhance 30 permeability in the formation. Creating an extended slot or fissure in a hydrocarbon layer may increase the surface area proximate or near one or more wellbores. Increasing surface area in the hydrocarbon layer may enhance fluid connectivity in the hydrocarbon containing formation. Slots or fissures in the hydrocarbon layer may be formed in the hydrocarbon layer using techniques known in the art. Use of slots may reduce the number of heaters needed to treat a 35 hydrocarbon containing formation using an in situ heat treatment process. Placing a heater in a 28 WO 2011/127292 PCT/US2011/031591 slot and providing heat (for example, using an in situ heat treatment process or an in situ conversion process) to portions of the hydrocarbon formation may mobilize hydrocarbons in the formation. In some embodiments, a temperature is maintained below a pyrolysis temperature of the hydrocarbons in the hydrocarbon layer. Maintaining a temperature below pyrolysis 5 temperatures (for example, at a temperature of less than about 50 'C) may thermally desorb hydrocarbons from one or more hydrocarbon layers (for example, a deep coal seam). In some embodiments, a temperature of a portion of a hydrocarbon layer is maintained between about 30 'C and about 200 'C, between about 40'C and about 150 'C, or between about 50 'C and about 100 'C. Desorbed or mobilized hydrocarbons may move through the hydrocarbon layer and be 10 produced from the hydrocarbon containing formation using one or more production wells. Use of slots and an in situ heat treatment process may increase the production of methane from a coal bed by at least 20%, by at least 30%, or at least by 50% as compared to methane desorbed using conventional techniques. [0155] FIG. 7 depicts a representation of an embodiment of forming a slot in a hydrocarbon 15 containing formation. Wellbore 300 may be formed in hydrocarbon layer 228 using drilling techniques known in the art such as directional drilling. As shown, wellbore 300 has a "J" shape. Wellbore 300 may have a substantially vertical portion 302 and a substantially horizontal or inclined portion 304. Vertical portion 302 may be cased with cement. After drilling, a drill string is removed from wellbore 300. Abrasive cutting member 306 is attached to a tip of pipe 20 308 using a downhole tool (for example, a nose tool or shoe tool) to form slot drill 310. Abrasive cutting member 306 may be, but is not limited to, steel wire rope, diamond wire, diamond abrasive cable, wire saw, cutting cable, or cable saw. In some embodiments, abrasive cutting member 306 may be diamond abrasives that are fixed to, or embedded in an external surface of, a wire rope. Abrasive cutting member 306 may be any size. In some embodiments, abrasive 25 cutting member 306 has a diameter ranging from about 0.9 cm to about 8 cm. In some embodiments, abrasive cutting member 306 is a heater cable that has an abrasive embedded in, or fixed on, an outer sheath. [0156] Slot drill 310 is coupled to tensioning apparatus 312 (for example, abrasive cutting 306 member may be attached to a winch). Tensioning apparatus 312 may be, but is not limited to. a 30 winch, a drilling rig, or any known tensioning apparatus in the art. Tensioning apparatus 312 reciprocates slot drill 310 in wellbore 300 to maintain tension on the cable during reciprocation in the wellbore. Tensioning apparatus 312 holds a desired tension on abrasive cutting member 306 as pipe 308 is lowered into wellbore 300. Tensioning of abrasive cutting member 306 while pipe 308 is lowered in the hole prevents the pipe from rotating and wrapping up the abrasive 35 cutting member on the way into the vertical part of the hole. 29 WO 2011/127292 PCT/US2011/031591 [0157] As slot drill 310 is reciprocated (shown by arrows 314) in hydrocarbon containing layer 228, slots 316 are formed in the hydrocarbon containing layer. Slot drill 310 may be reciprocated with a full stroke (for example, 27 m) for a period of time to cut hydrocarbon layer 228. On the up stroke, abrasive cutting member 306 tension is limited to that provided by tensioning member 5 312 so the up stroke performs little to no cutting. Abrasive cutting member 306 tension allows the abrasive cutting member 306 to hug the inside radius of the curved portion of wellbore 300 while pipe 308 compressive loading tends to make the pipe hug the outside radius of the curve. The friction on the abrasive cutting member 306 around the curve multiplies the initial low abrasive cutting member tension from the tensioning apparatus and increases exponentially 10 around the curved path. Abrasive cutting member 306 cuts slots 316 on the inside radius curve of wellbore 300 on each downward stroke. In some embodiments, a curvature of the arc formed by cutting ranges between about 60 degrees and about 140 degrees. Thus, slots 316 are formed perpendicular to the axis of the abrasive cutting member, the curve, and the substantially horizontal or inclined portion of the wellbore. Slots 316 may expose a substantial cross-section 15 of the hydrocarbon layer to the wellbore (for example, at least 10,000 square feet to 100,000 square feet of cross-section is exposed). FIG. 7A depicts a cross-sectional view of slots 316 along section 7A-7A of FIG. 7. [0158] Formation cuttings created by drilling may be removed from slots 316 by circulating liquid or foam drilling fluid, gas, or compressed air through wellbore 300 and the slots. In some 20 embodiments, water is used as the drilling fluid. After cutting slots 316, drilling fluid may be removed from wellbore 300 and slots 316 (for example, pumped from the wellbore) and one or more heat sources (for example, heaters) may be provided to the wellbore and/or the slots. FIG. 8 depicts a representation of treating a hydrocarbon containing formation after formation of slots. Heaters 212 may be positioned in wellbore 300 and/or slots 316. Using an in situ heat treatment 25 process, hydrocarbons may be heated and moved through the hydrocarbon containing formation. In some embodiments, a temperature of the in situ heat treatment process is maintained below a pyrolysis temperature (for example, less than about 50 C) such that methane and/or C2-C' hydrocarbons are desorbed from hydrocarbon containing layer 228. Hydrocarbons may flow through the more permeable formation and be produced using production well 206. 30 [0159] The slot may be a longitudinal groove that extends a substantial distance (for example, at least about 30 m, at least about 40 m, or at least about 50 m) from a side of a wellbore. A width of a slot is dependent on the size of abrasive cutting member 306used for cutting. For example, a slot width may range from about 2 cm to about 10 cm. [0160] In some embodiments, slots 306 are formed using a two well system. FIG. 9 depicts a 35 representation of an embodiment of forming slots in a hydrocarbon layer using a two well 30 WO 2011/127292 PCT/US2011/031591 system. A first end of slot drill 310 may be coupled to a first tension apparatus 312 and a second end of slot drill 310 is coupled to a second tension apparatus 312'. Pipe 308 may be positioned inside of tubing 320. Tubing 320, 320' may reduce friction when pipe 308 is reciprocated in wellbore 300. Slots 316 are cut in hydrocarbon layer 228 by reciprocating slot drill 310 by 5 reciprocating the slot drill back and forth through the hydrocarbon layer using first tension apparatus 312'and second tension apparatus 312'. [0161] In some embodiments, two slot drills 310 are used. For example, a first slot drill may be coupled to first tension apparatus 312 and second slot drill 310' is coupled second tension apparatus 312'. Slots 316 are cut in hydrocarbon layer 228 by reciprocating each slot drill 10 through hydrocarbon layer 228. [0162] In some embodiments, slot drill 310 is operated (for example, by adjusting the amount of tension on the abrasive cutting member 306 such that a polygon pattern (for example, a triangle) between wells formed. FIG. 1 OA depicts a representation of a symmetric arch formed between two wellbores. FIG. 10B depicts a representation of a triangle formed between two wellbores. 15 Creation of a polygon pattern 322 while slotting may be used to create a radial pattern having a central well shared among other pairs. FIG. 1 1A depicts a representation of radial pattern having a central well and eight surrounding wells. Use of a polygon pattern in the radial pattern may reduce the amount of wells from eight to seven as shown in FIG. 11B. [0163] In some embodiments, one or more slots may be formed in a hydrocarbon containing 20 layer after producing hydrocarbons from the hydrocarbon layer. Forming slots in the hydrocarbon containing layer after production of hydrocarbons may allow a wellbore to be repositioned (travel) in the hydrocarbon layer. FIGS. 12A-C depict perspective representations of embodiments of repositioning positioning wellbores in a hydrocarbon formation. First wellbore 300 and second wellbore 300' may be formed in hydrocarbon layer 228. First 25 substantially horizontal portion 304 of first wellbore 300 may be connected to second substantially horizontal portion 304' of second wellbore 300' by a curved portion of a wellbore to form a horizontal u-shaped wellbore. The horizontal u-shaped wellbore may be formed using drilling techniques known in the art. In some embodiments, first substantially horizontal or inclined portion 304 and second substantially horizontal or inclined portion 304' are directed 30 downward in hydrocarbon containing layer 228. Using inclined wells may minimize the use of downhole equipment and minimize casing side loads when forming slots. During slot formation, residual cutting fluids may drain to the lower portion (toe) of the inclined wells while allowing heat to be provided the hydrocarbon layer at the upper portion (heel) of the wellbore. Cutting fluids may be removed from wellbore 300 and/or slots 316 using techniques known in the art 31 WO 2011/127292 PCT/US2011/031591 such as artificial lifting techniques (for example, gas lift) or by applying pressure to the system. In some embodiments, the position of the toe and heel of the wellbore maybe reversed. [0164] First substantially horizontal or inclined portion 304 and second substantially horizontal or inclined portion 304' may extend a desired distance (for example, 500 m, 600 m, or 650 m) 5 into the hydrocarbon formation. First substantially horizontal or inclined portion 304 may be positioned a desired distance (for example, 500 m. 600 m, or 650 m) from second substantially horizontal or inclined portion 304'. In an embodiment, first substantially horizontal or inclined portion 304 is substantially above second substantially horizontal or inclined portion 304' in hydrocarbon containing layer 228. 10 [0165] Heater 212 (for example, an insulated electrical conductor) may be positioned in wellbore 300 in hydrocarbon layer 228, as shown in FIGS. 12A-C. Hydrocarbon containing layer 228 may be treated using an in situ heat treatment process to mobilize and/or pyrolyze hydrocarbons in a section of the hydrocarbon containing layer. Hydrocarbons may produced from the formation through production well 206. Heaters 212 may be turned off, cooled, and, in some 15 embodiments, removed from wellbore 300. The slot drill (not shown) may be inserted in wellbore and slots 316 may be formed in hydrocarbon layer 228 in the vertical plane between first substantially horizontal or inclined portion 304 and second substantially horizontal or inclined portion 304'. In some embodiments, slots 316 are drilled prior putting one or more heaters 212 in the hydrocarbon formation. After formation of a desired amount of slots, the slot 20 drill may be removed and heater 212' may be positioned (for example, an insulated electrical conductor may be threaded at a rate of about 9 m/min into the slot) in at least one slot 316 between first substantially horizontal or inclined portion 304 and second substantially horizontal or inclined portion 304', thus moving the wellbore from first position 324 to second position 326, as shown in FIG. 12B. Treatment of hydrocarbon layer 228' using an in situ heat treatment 25 process may mobilize hydrocarbons towards production well 206. After a desired amount of hydrocarbons have been removed from hydrocarbon containing layer 228', the process may be repeated to move wellbore 300 to place heater 212" at a third position 328 in the hydrocarbon layer 228 as shown in FIG. 12C. In some embodiments, hydrocarbon layers 228, 228', 228" are deep coal seams. 30 [0166] In some embodiments, heaters in the formation (for example, heaters in the slots and in the hydrocarbon containing layer) are operated at full power output to heat the formation to visbreaking temperatures or higher temperatures. Operating at full power may rapidly increase the pressure in the formation. In certain embodiments, fluids are produced from the formation to maintain a pressure in the formation below a selected pressure as the temperature of the 35 formation increases. In some embodiments, the selected pressure is a fracture pressure of the 32 WO 2011/127292 PCT/US2011/031591 formation. In certain embodiments, the selected pressure is between about 1000 kPa and about 15000 kPa, between about 2000 kPa and about 10000 kPa, or between about 2500 kPa and about 5000 kPa. In one embodiment, the selected pressure is about 10000 kPa. Maintaining the pressure as close to the fracture pressure as possible may minimize the number of production 5 wells needed for producing fluids from the formation. [0167] In certain embodiments, treating the formation includes maintaining the temperature at or near visbreaking temperatures (as described above) during the entire production phase while maintaining the pressure below the fracture pressure. The heat provided to the formation may be reduced or eliminated to maintain the temperature at or near visbreaking temperatures. Heating 10 to visbreaking temperatures but maintaining the temperature below pyrolysis temperatures or near pyrolysis temperatures (for example, below about 230 C) inhibits coke formation and/or higher level reactions. Heating to visbreaking temperatures at higher pressures (for example, pressures near but below the fracture pressure) keeps produced gases in the liquid oil (hydrocarbons) in the formation and increases hydrogen reduction in the formation with higher 15 hydrogen partial pressures. Heating the formation to only visbreaking temperatures also uses less energy input than heating the formation to pyrolysis temperatures. [0168] Fluids produced from the formation may include visbroken fluids, mobilized fluids, and/or pyrolyzed fluids. In some embodiments, a produced mixture that includes these fluids is produced from the formation. The produced mixture may have assessable properties (for 20 example, measurable properties). The produced mixture properties are determined by operating conditions in the formation being treated (for example, temperature and/or pressure in the formation). In certain embodiments, the operating conditions may be selected, varied, and/or maintained to produce desirable properties in hydrocarbons in the produced mixture. For example, the produced mixture may include hydrocarbons that have properties that allow the 25 mixture to be easily transported (for example, sent through a pipeline without adding diluent or blending the mixture and/or resulting hydrocarbons with another fluid). [0169] In some embodiments, after the formation reaches visbreaking temperatures, the pressure in the formation is reduced. In certain embodiments, the pressure in the formation is reduced at temperatures above visbreaking temperatures. Reducing the pressure at higher temperatures 30 allows more of the hydrocarbons in the formation to be converted to higher quality hydrocarbons by visbreaking and/or pyrolysis. Allowing the formation to reach higher temperatures before pressure reduction, however, may increase the amount of carbon dioxide produced and/or the amount of coking in the formation. For example, in some formations, coking of bitumen (at pressures above 700 kPa) begins at about 280 'C and reaches a maximum rate at about 340 'C. 35 At pressures below about 700 kPa, the coking rate in the formation is minimal. Allowing the 33 WO 2011/127292 PCT/US2011/031591 formation to reach higher temperatures before pressure reduction may decrease the amount of hydrocarbons produced from the formation. [0170] In certain embodiments, a drive process (for example, a steam injection process such as cyclic steam injection, a steam assisted gravity drainage process (SAGD), a solvent injection 5 process, a vapor solvent and SAGD process, or a carbon dioxide injection process) is used to treat a hydrocarbon containing formation (for example, a consolidated tar sands formation) in addition to the in situ heat treatment process. In some embodiments, slots are formed as described herein to create permeability zones in the formation for the drive process. In an embodiment, heaters are used in the wellbore and/or slots to create high permeability zones (or 10 injection zones) in the formation for the drive process. Heaters in wellbores and/or slots may be used to create a mobilization geometry or production network in the formation to allow fluids to flow through the formation during the drive process. For example, slots may be used to create drainage paths between the heaters and production wells for the drive process. In some embodiments, the heaters are used to provide heat during the drive process. The amount of heat 15 provided by the heaters may be small compared to the heat input from the drive process (for example, the heat input from steam injection). [0171] In some embodiments, the steam injection (or drive) process (for example, SAGD, cyclic steam soak, or another steam recovery process) is used to treat the formation and produce hydrocarbons from the formation. Slots may be created in the hydrocarbon formation using as 20 described herein and steam may be injected into the hydrocarbon formation wellbores and flow into the slots. [0172] The in situ heat treatment process may be used following the steam injection process to increase the recovery of oil in place from the formation. In certain embodiments, the steam injection process is used until the steam injection process is no longer efficient at removing 25 hydrocarbons from the formation (for example, until the steam injection process is no longer economically feasible). The in situ heat treatment process is used to produce hydrocarbons remaining in the formation after the steam injection process. Using the in situ heat treatment process after the steam injection process may allow recovery of at least about 25%, at least about 50%, at least about 55%, or at least about 60% of oil in place in the formation. 30 [0173] Treating the formation with the in situ heat treatment process after the drive fluid process (for example, a steam injection process) may be more efficient than only treating the fonnation with the in situ heat treatment process. The steam injection process may provide some energy (heat) to the formation with the steam. Any energy added to the formation during the steam injection process reduces the amount of energy needed to be supplied by heaters for the in situ 35 heat treatment process. Reducing the amount of energy supplied by heaters reduces costs for 34 WO 2011/127292 PCT/US2011/031591 treating the formation using the in situ heat treatment process. At least some additional hydrocarbons may be mobilized and from the portion of the formation using the in situ heat treatment process after steam injection. The additional hydrocarbons may include at least some hydrocarbons that are upgraded compared to the hydrocarbons produced by using the drive fluid. 5 [0174] It is to be understood the invention is not limited to particular systems described which may, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. As used in this specification, the singular forms "a", "an" and "the" include plural referents unless the content clearly indicates otherwise. Thus, for example, reference to "a core" includes a 10 combination of two or more cores and reference to "a material" includes mixtures of materials. [0175] Further modifications and alternative embodiments of various aspects of the invention will be apparent to those skilled in the art in view of this description. Accordingly, this description is to be construed as illustrative only and is for the purpose of teaching those skilled in the art the general manner of carrying out the invention. It is to be understood that the forms 15 of the invention shown and described herein are to be taken as the presently preferred embodiments. Elements and materials may be substituted for those illustrated and described herein, parts and processes may be reversed, and certain features of the invention may be utilized independently, all as would be apparent to one skilled in the art after having the benefit of this description of the invention. Changes may be made in the elements described herein without 20 departing from the spirit and scope of the invention as described in the following claims. It is to be understood that each of the features in the claims set forth below may be combined with, or separated from, features from other claims. For example, the features of two or more dependent claims can be combined together to form a claim that is multiply dependent. 35

Claims

1. A method of treating a hydrocarbon containing formation, comprising: forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions and at least a first opening at 5 a first position of the earth's surface, wherein at least two of the substantially horizontal or inclined portions are substantially parallel; forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; [0 providing heat to a portion of the hydrocarbon containing formation from one or more heaters placed in at least a portion of the slot, wherein one or more of the heaters comprise one or more insulated electrical conductors; allowing the heat to transfer from the heaters to the portion of the hydrocarbon containing formation; and [5 producing hydrocarbons from the hydrocarbon containing formation.

2. The method of claim 1, wherein the wellbore is a u-shaped horizontal wellbore.

3. The method of claim 1, wherein forming the slot comprises adjusting a tension of an abrasive member of a slot drill such that the area between the first opening, a second opening of the wellbore at a first position of the earth's surface, and the one or more slots forms a polygon. 20

4. The method of claim 1, wherein a second portion of the at least two substantially horizontal or inclined portions is positioned below a first portion of the at least two substantially horizontal or inclined portions in the hydrocarbon containing formation.

5. The method of claim 1, wherein placing the heater in at least a portion of the slot comprises 25 removing a slot drill from the wellbore; coupling a portion of at least one heater to a pipe of the slot drill; and threading the heater through the slot.

6. The method of claim 1, further comprising 37 removing at least one of the heaters from at least one slot; forming one or more additional slots in another portion of the hydrocarbon containing layer; providing an additional heater to at least one of the additional slots; 5 providing heat to the additional portion of the hydrocarbon containing formation from the additional heater, wherein the additional heaters comprise an insulated electrical conductor; allowing the heat to transfer from the heater to the additional portion of the hydrocarbon containing formation; and producing additional hydrocarbons from the hydrocarbon containing formation. [0

7. The method of claim 1, wherein forming the slot comprises using at least one of the heaters as an abrasive tool member of a slot drill.

8. A method of treating a hydrocarbon containing formation, comprising: allowing the heat to transfer from a plurality of heaters to the first section of the formation; [5 producing hydrocarbons from the hydrocarbon containing formation; forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to a least two substantially horizontal or inclined portions of a wellbore positioned in the hydrocarbon containing formation, and wherein at least two of the substantially horizontal or inclined portions are substantially parallel; 20 providing heat to a second section of the hydrocarbon containing formation from one or more additional heaters placed in the slot; allowing the heat to transfer from the heaters to the second section of the formation; and producing additional hydrocarbons from the hydrocarbon containing formation.

9. The method of claim 8, wherein at least one of the additional heaters comprises an 25 insulated electrical conductor.

10. A method of producing methane from a hydrocarbon containing formation, comprising: forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions and at least a first opening at a first position of the earth's surface, and wherein at least two of the substantially horizontal or 30 inclined portions are substantially parallel; 38 forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; providing heat to a portion of the hydrocarbon containing formation from one or more 5 heaters placed in at least a portion of the slot, wherein one or more of the heaters comprise one or more insulated electrical conductors; maintaining an average temperature in the portion of the formation below a pyrolyzation temperature of hydrocarbons in the section; and removing methane from the hydrocarbon formation. [0

11. The method of claim 10, further comprising removing hydrocarbons having a carbon number between 1 and 5 from the portion of the hydrocarbon containing formation.

12. The method of claim 10, further comprising providing a barrier around the portion of the formation.

13. The method of claim 10, wherein an average temperature in the portion of the [5 hydrocarbon containing formation is below 230 'C.

14. A method of treating a hydrocarbon containing formation, comprising: forming at least one wellbore in a hydrocarbon containing formation, the wellbore comprising at least two substantially horizontal or inclined portions and at least a first opening at a first position of the earth's surface, and wherein at least two of the substantially horizontal or 20 inclined portions are substantially parallel; forming a plurality of slots in a portion of the hydrocarbon containing formation, wherein at least one of the slots is perpendicular to the at least two substantially horizontal or inclined portions of the wellbore; providing a drive fluid to at least one of the slots; and 25 producing hydrocarbons from the hydrocarbon formation.

15. The method of claim 14, wherein the drive fluid is steam.

16. The method of claim 14, further comprising providing heat to the hydrocarbon containing formation from one or more heaters located in the hydrocarbon containing formation; and 39 producing at least some additional hydrocarbons from the layer of the formation, the additional hydrocarbons comprising at least some hydrocarbons that are upgraded compared to the hydrocarbons produced by using the drive fluid.

17. A method of producing methane from a hydrocarbon containing formation, comprising: 5 providing heat the formation from a plurality of heaters located in the hydrocarbon containing formation, wherein one or more of the heaters comprise one or more insulated electrical conductors; allowing the heat to transfer from the heaters to at least a portion of the hydrocarbon containing formation comprising methane; [0 maintaining an average temperature in the portion of the hydrocarbon containing formation below a pyrolyzation temperature of hydrocarbons in the hydrocarbon containing formation comprising methane; and removing methane from the portion of the hydrocarbon containing formation.

18. The method of claim 17, further comprising providing a barrier around the portion of the [5 formation.

19. The method of claim 17, wherein an average temperature in the portion of the hydrocarbon containing formation is between 30 'C and 40 'C.

20. A method of producing methane from a hydrocarbon containing formation, comprising: providing heat to a first section of the hydrocarbon containing formation from a plurality 20 of heaters located in the formation, wherein one or more of the heaters comprise one or more insulated electrical conductors; allowing the heat to transfer from the heaters to the first section of the hydrocarbon containing formation, producing hydrocarbons from the first section; 25 providing one or more heaters from the first section to a second section of the hydrocarbon containing formation, wherein the second section of the formation comprises methane; maintaining an average temperature in the second section of the hydrocarbon containing formation below a pyrolyzation temperature of hydrocarbons in the second section; and 30 40 removing methane from the hydrocarbon containing formation. Shell Internationale Research Maatschappij B.V. Patent Attorneys for the Applicant/Nominated Person SPRUSON & FERGUSON