AU2011203205B2 - Dishwasher and method for the operation of a dishwasher using a detergent composition containing several active substances - Google Patents

Dishwasher and method for the operation of a dishwasher using a detergent composition containing several active substances Download PDF

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AU2011203205B2
AU2011203205B2 AU2011203205A AU2011203205A AU2011203205B2 AU 2011203205 B2 AU2011203205 B2 AU 2011203205B2 AU 2011203205 A AU2011203205 A AU 2011203205A AU 2011203205 A AU2011203205 A AU 2011203205A AU 2011203205 B2 AU2011203205 B2 AU 2011203205B2
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wash solution
dishwasher
wash
program
cycle
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AU2011203205A1 (en
AU2011203205A2 (en
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Klaus-Martin Forst
Stefan Fuglein
Karlheinz Kohles
Rolf Stahlmann
Winfried Steiner
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Electrolux Home Products Corp NV
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Electrolux Home Products Corp NV
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Abstract

Abstract There is disclosed a dishwasher, where at least one wash program is selectable, characterised in that this wash program is itself defined for the use of a detergent 5 composition comprising several active substances or where at least one means for connecting an additional function is provided, by which means upon switching on this function at least one parameter of the selected wash program can be changed with regard to the use of a composition with several active substances. *4) U) 41 = E * I I-lW 1 -- - - - - --- LO c J o TI, C I-: C\I Hr

Description

Australian Patents Act 1990 - Regulation 3.2 ORIGINAL COMPLETE SPECIFICATION STANDARD PATENT Invention Title "Method for the operation of a dishwasher using a detergent composition containing several active substances" The following statement is a full description of this invention, including the best method of performing it known to us: C \NRIorbl\DCC\AZM\4695S58_1 DOC - 23/10/12 C \NRPonbl\DCC\AZM\46949M)_LDOC-24/1)/2)12 Method for the operation of a dishwasher using a detergent composition containing several active substances The entire content of Australian patent application no. 2003204196 as filed (including any 5 content incorporated therein by reference) is incorporated herein by reference. The invention relates to a method for the operation of a dishwasher. For some time so called "3inl compositions" have been available for the use in 10 dishwashers which comprise a cleaning substance, a softening substance and a rinsing substance and which are simultaneously introduced into the wash tub or chamber of the dishwasher at a certain point of time in the cycle. These ,,3inl" compositions are available in the form of pressed tablets, so called ,,3inl tabs" and also as a ,,3inl " powder. The ,,3inl compositions" can be inserted into dosing devices provided in the dishwasher and in such a 15 case they are metered into the tub at a certain point of time which is determined by the wash program of the dishwasher. On the other hand they 2 can also be inserted into the dishwasher by the user of the dishwasher, for instance into the cutlery basket, prior to switching on the wash program. Generally today the user has at his disposal more than one selectable wash program for washing the dirty items placed into the dishwasher. Several programs can be selected as wash programs 5 known under such descriptions as quick program, normal program, intensive program and economy program for which terms a variety of synonyms exist. Ever since the commencement of the use of ,,3inI" compositions by the users of dishwashers, the customer complaints received by the manufacturers of dishwashers have significantly increased. The reason for this is that the cleaning and/or drying results of the articles 10 washed in the dishwasher have to some extent dramatically deteriorated where ,,3inl" compositions are used by contrast to situations where traditional individual metering of the respective substances was used. A particular problem has been that the user does not observe the specific instructions regarding placement of the ,,3inl" compositions into the dishwasher; some, for instance, place the ,,3inl" compositions 15 into the tub of the dishwasher, whilst the manufacturer prescribes an exclusive use by means of a dosing device. At times the instructions from the manufacturers are not specific enough or inaccurate. A further problem is that whilst the user of the dishwasher generally knows which wash program he must select depending on the soil content of the wash load and the dryness/adherence of the dirt particles, he does not 20 however have any intimate knowledge regarding the sequence of the wash program per se. This knowledge is usually taken for granted by the manufacturer of the ,,3inl" compositions who apparently totally disregards the fact that a variety of ,,3in)" compositions are available in the market, which in dependence of a variety of parameters dissolve differently and therefore achieve their highest efficiency at 3 different points of time. Some of the available ,,3inI" compositions work according to the ,,dilution principle" (also known as the carry over principle), i.e. at the commencement of the cleaning the ,,3inl" composition is introduced and begins to dissolve. In this situation the rinsing agent is mainly added initially in a high 5 concentration, i.e. overdosed, and it is assumed that due to it being carried over in wash water residues and by way of adhesion of the dissolved rinsing agent to the items to be washed, at the dishwasher tub walls and ceiling as well as in the supply lines, the concentration in the final (clear) rinsing process is still sufficient to achieve a particularly good drying result. A further type of the ,,3inl" compositions available 10 has the feature that initially only the cleaning agent and the softening agent dissolve and the rinsing agent, which is encapsulated within the ,,3inl" composition for instance within a wax-covered pearl only dissolves during the final (clear) rinsing cycle depending on the temperature value and/or the pH value. When using a wash program which works with high temperatures already in the cleaning cycle of the 15 program and/or when selecting a very long cleaning process, which usually goes hand in hand with intensive programs, the rinsing agent of the second type will then already be dissolved during the cleaning process. The rinsing agent of the first type in particular has the disadvantage where several program cycle processes are performed prior to the final (clear) rinsing process, such as cleaning and intermediate rinse cycles 20 (with the latter being run between the cleaning and final rinse cycles), that the rinsing agent dissolves too soon and after several dishwasher water changes is no longer present in sufficient concentration during the final (clear) rinse program cycle. A further disadvantage when using the ,,3inl" composition may arise where the user of the dishwasher, prior to the start of the wash program, adds the dose, for instance a CANRPonbl\DCC\AZM\46949O I DOC-24/10/2012 -4 ,,3inl" tab by inserting it anywhere in the dishwasher, rather than into the dosing dispenser. In this case for instance at least the cleaning agent and softening agent begin to dissolve in the pre-wash rinse cycle, and laboratory tests have shown that the dissolution behaviour of the ,,3inl "compositions is even very good in water which 5 essentially has the temperature 5 prevailing in the supply pipes. Since the water is drained from the tub, the substances of the ,,3inl" composition are available in lower concentrations to the subsequent program processes of the cleaning, intermediate rinse and final (clear) rinse cycles. This has a direct effect on the cleaning result as well as the drying result of the dishes and generally impairs the result. 10 The invention provides a method for operating a dishwasher, wherein at least one dishwasher program is selectable, which by optional switching on or off of an additional function for the use of a detergent composition comprising several active substances and/or upon an automatic, essentially sensoric detection of the use of a composition is adapted in 15 its structure and in its sequence to the use of such a composition, wherein in the course of a wash program at least one of the following process steps is executed: A) metering of certain substances which are stored in a dosing device of the dishwasher is delayed with regard to its point of time and/or has the 20 dosage quantity altered or is completely disabled; B) an automatic regeneration function of a regeneration device of the dishwasher will be switched off unless it is detected by a hardness sensor provided that the actual degree of hardness has fallen below or has 25 exceeded a defined degree of hardness and/or by a user-dependent input at the regeneration/dosing device a defined degree of hardness of a wash solution is determined and/or via a program-controlled input device the regeneration function is enabled whilst the additional function is switched on, wherein upon exceeding a defined degree of hardness of the wash 30 solution by means of at least temporary re-enabling of the regeneration C:\NRPorbl\DCC\ZM\46949%0LI DOC-24/1/2012 -5 function and/or blending of the wash solution with soft water, the degree of hardness of the wash solution as a whole is reduced; C) at the commencement of the wash program, the metering of a 5 rinsing substance from the dosing device is blocked, for this purpose a respective default value being set and stored in a memory unit of the program control, wherein in the event of detection that the rinsing substance concentration has fallen below a definable concentration value, the default value is resettable and/or, at a definable point of time of a program 10 sequence, a definable volume of rinsing substance is added to the wash solution and/or until a definable minimum concentration value is achieved ; D) during the program sequence and depending on a particular process run of an actually executed step (B) regarding the regeneration function an 15 addition of a defined brine volume into a softening device is disabled or enabled; E) information regarding an actual status and/or desired status of at least one parameter of the wash program or a prompt derived therefrom 20 and/or request to a user of the dishwasher is indicated by corresponding indicators; F) a duration of at least one program cycle is reduced in time or reduced to zero; 25 G) two process cycles are prolonged and/or shortened, whereby the duration of the prolongation/shortening are in a definable proportion; I) one or more proposed intermediate rinse cycles are reduced to one 30 intermediate rinse cycle or none; C \NRPonb\DCC\AZN\6949X_ .DOC-24/11/20)12 -6 I) at least in one program cycle by once only or repeated switching on and off of a circulating pump of the dishwasher with variably definable or specifiable duration of the switched on and switched off status of the circulating pump or by controlled speed variation of the circulating pump, 5 the wash solution is caused to act upon the wash load in the manner of pulse rinsing; J) during at least one program cycle, at least one dilution step for reduction of soil concentration of the wash solution in dependence of at 10 least one measurement of turbidity and/or concentration of at least one active substance in the wash solution or independent thereof is undertaken; K) the maximum temperature in program cycles preceding a final (clear) rinse cycle is reduced to a temperature below the dissolution 15 temperature of rinsing substance; and L) in a final (clear) rinse cycle, the solution is heated to a temperature which is above the temperature of the solution of rinsing substance. 20 Preferred embodiments of the present invention provide a dishwasher operation method which overcomes at least one of the aforementioned disadvantages, which proceeds in accordance with a wash program, and which is adapted to, or will be adapted to the use of dishwasher compositions containing several active substances, wherein the user will be enabled in principle to continue using the hitherto known wash programs. 25 In the method according to a preferred embodiment of the invention, the user of the dishwasher is able to select at least one wash program, such as for instance an intensive program, normal program, quick program, economy program. The selection means are mostly in an operating panel of the dishwasher and are well known per se. 30 In accordance with a preferred embodiment of the invention, there is provided a switchable C:\NRPortbl\DCC\AZM\46949ILIDOC-24/I10/2012 -7 additional feature by which, upon the use of compositions containing several agents, such a use of a program control is displayed. The result of this is that the wash program which is selected by the user, such as intensive program, normal program, quick program, economy program is automatically adapted to the use of a composition which comprises in particular 5 a cleaning substance, softener substance and rinsing substance. This means that when the additional function is switched on, a corresponding signal is given to the control unit which automatically adapts the user-selected wash program to the use of the composition. For this purpose there are for instance stored in the microcontroller of the control unit various control sequence routines to fall back upon, and/or various parameters of the dishwasher 10 program, such as temperature, duration of a certain dishwasher program cycle, wash solution fill volume, pH-value amongst others are defined and can then be accessed or changed by way of intervention. An alternative solution is offered by an additional function, wherein a switching means is switched off in accordance with the inventive operation. In a further embodiment of the invention there is an especially structured wash 15 program for particular use with a composition which program can be selected specifically from amongst other wash programs. Preferably, the additional function is designed for the use of a ,,3inl"composition, wherein this composition contains as active substances for the cleaning of the wash load essentially 20 only a cleaning substance, softener substance and rinsing substance. Independent of these constituents, the ,,3inl "composition can also contain further substances whose direct or indirect effect on the cleaning and drying result of individual wash program cycles or the total cleaning result of the wash program is of secondary importance. Insofar as further active substances of the composition are not expressly named, these are however known 25 and embraced by the invention. A switching means for switching the additional function, is preferably located in the control panel of the dishwasher besides other selection means and/or display means. A further option of arranging the switching means is being offered by the dosing device into 30 which the composition is preferably filled. For the design of the switching means a variety of known designs, such as rotary switches, contact switches or the like, are feasible.
C \NRPorbl\DCC\AZM\46949XI5_LDOC-24/I/20)12 -8 Furthermore, actuation of a switching means by way of user selection is also possible which can be added on by selection from a menu-driven selection device, for instance in a display type or in networked household appliances via a graphical interface or, optionally, a speech recognition system. 5 In the dishwasher there can be detected by means of at least one sensor being provided the use of a composition, in particular of a ,,3inl" composition so that for the program sequence design it is distinguishable on the one hand whether a composition works according to the dilution principle or whether a composition is used which only dissolves 10 the rinsing agent pH value-dependent or temperature-dependent in the rinsing phase. On the other hand, it is possible during the entire dishwashing program sequence to determine in repeated sensor measurements any concentration changes and/or pH value changes and/or hardness level changes of the wash solution which permit conclusions to be drawn regarding the concentration of the individual active substances of the ,,3inrcomposition, 15 with the consequence that the program sequence can be modified at any suitable point of time. As regards sensors, least one of the sensors is preferably designed as a chemical and/or acoustic and/or thermal and/or optic and/or pneumatic sensor type. Their employment can 20 vary with regard to the number employed and their specific detection characteristics. There is preferably further an evaluation of the sensor signal with regard to the adaptation of the wash program sequence relating to the ,,3inI "composition, as well as for the design opf the other parameters of the entire wash program sequence. 25 Furthermore, alternatively at least one chemical sensor proposed for the use with respectively selected receptors which is designed to detect several simultaneously present agents, such as cleaning agent and softening agent and/or rinsing agent, can detect the use of a composition and even without the additional function to the program sequence control being switched on can signalise the use of a composition. Control measurements, 30 optionally repeated control measurements, or comparison with other sensor measurements during the program allow detection of a composition used and the program is changed C \NRPOdbl\DCC\AZM\46949K1)_I DOC-24/10/2012 -8a accordingly. Particularly preferred is at present the use of one sensor, which detects at least the pH value and/or the temperature and/or the degree of hardness of the dishwasher solution. 5 The sensor(s) preferably ascertain continuously or discontinuously during the program or during individual program cycles whose time frames or points of time can be preset, individual program parameters, for instance by means of an actual/desired value comparison and/or a differential value and/or the changed course of a parameter such as pH value, temperature, turbidity, foaming, concentration, water hardness, and whether a 10 certain agent of the composition for instance exceeds or falls below a predetermined minimum or maximum value. Furthermore, for instance depending on a differential value, which for instance can be manufacturer-dependent and result from the ,,3inl "composition itself, as also with regard to other typical parameters such as concentration jumps, dissolution temperatures or parameter combinations such as pH value and concentration or 15 concentration and temperature of the wash program. For a selectable time segment of a wash program or over the entire duration of the wash program, the change of at least one parameter of the wash program may be recorded and evaluated. It is for instance possible with regard to the course of the pi value of the wash solution to draw conclusions on the concentration of the individual active substances of the ,,3inrcomposition. Thus, at present 20 the evaluation of the pH value can be performed in such a manner that the cleaning program cycle represents a max. alkaline pH value and must either fall below a specified value in the final (clear) rinse program cycle or the course of its change is predefined, for instance in a specified family of characteristics within specified tolerances, or pH value jumps are ascertained within predefined time frames or otherwise time constants for their 25 occurrence are ascertained, for instance after reaching the dissolution temperature of an encapsulated rinsing agent. In accordance with a preferred embodiment of the invention, whilst an additional function for the adaptation of a wash program to the use of a composition is switched 9 on, such sensor measurements are employed in any case for the active intervention into the program. When selecting a specially designed wash program these initially have a kind of control function to determine whether, during the program sequence, a composition is actually being used or at least an active substance is present in 5 sufficient concentration at the preset time. Adjustments of the program are optional. A suitable method for the evaluation of the sensor measurement signals is for instance to ascertain the value or the change of certain parameters of the wash program such as turbidity, p-1 value, foaming, concentration, water hardness and others individually as 10 well as in suitable combination, at characteristic points of time of the wash program sequence, with regard to their quality and quantity and their respective delay times. For this purpose at least individual parameter values can be ascertained and subjected to an actual-desired value adjustment, a differential value formation or a threshold value interrogation or the changes can be made against preset values or values 15 ascertained during the program sequence. All reference values are backed up in tables or as default values in at least one memory unit of the program control. In networked household appliances this memory unit can also be located outside the dishwasher. Furthermore it is also possible to store in the memory unit certain program statuses whose combination pairing is not desirable for instance and these can prompt the user 20 to undertake certain actions. Such not desirable constellations arise for instance in the pre-wash rinse program cycle when an increased foaming and/or distinct pH value fluctuations occur or when the rinsing agent concentration falls below a preset value during all the program cycles or rinsing agent concentration jumps occur independent of a certain temperature or temperature variation. Depending on the error situation, the 10 user can for instance be prompted to place a composition into the dosing compartment or the program sequence is interrupted until the user restarts the dishwasher or the measuring result detected as erroneous is at least displayed. 5 The program cycles pre-wash rinse or cleaning can be designed such that the point of time of the actual addition of the ,,3inl"composition is additionally monitored, for instance in that the fall of a tablet from the dosing device into the dishwasher tub is detected by an acoustic sensor. Other detection options are optical sensors, which for instance register increased foaming, or chemical sensors which evaluate the change in 10 the pH value of the wash solution. A further advantage is offered if, when using a composition which may be modified which comprises for instance an enzymatic cleaning substance with an effectiveness temperature limit of approx. 30'C and a rinsing substance with a dissolution 15 temperature of approx. 58C - and at the same time applying preset shortened program cycles and consequently reduced dissolution periods, the wash solution is heated by way of short, optionally repeated, switching on and/or controlled power output of the heating means during the pre-wash rinse and/or intermediate rinse cycles, preferably at the end of the respective cycle so that for the following cycles, 20 cleaning or final (clear) rinse, which are run with hot wash solution, the respective chemical substance is able to develop its effectiveness in an improved manner and for a longer time frame. By the preheating or increased heating of the wash solution at the end of the preceding wash program cycle the dissolution and therefore the CANRPodbl\DCCkAZM\46949X_ DOC-24/10/2012 - 11 effectiveness of the cleaning agent or rinsing agent is improved for the duration of each program cycle. The energy thus supplied is comparable to an activation energy. When a temperature control is proposed, the dissolution period, concentration, action time, point of time of release of a chemical substance of the ,,3inl" composition can be optimised. 5 It is of particular advantage in this situation, when the actually used ,,3in 1 "composition is specified as a parameter in the program control, for instance by input via an image recognition, which for instance recognises the bar code of a ,,3inI"composition, or by selection from commercially available ,,3inl"compositions stored in the program memory 10 or by input of a specified composition by the user in some other manner, where the user specified information regarding the use of a certain ,,3in 1" composition is stored until a different input of information is made or is again interrogated at the commencement of each or any specifically defined point of time. 15 A further advantage being offered at the time of the interrogation or evaluation of an information regarding the type and form of administration of the dispensed cleaning, rinsing and, if required, softening agents, is that a product which is clearly not identified as a ,,3inl "composition be able to switch off a ,,3inl" function erroneously selected by the user or that, upon selection of a ,,3in 1 program, an error message be issued. 20 It is further advantageous that when the ,,3inl" function is switched on or when a ,,3inl" wash program is selected, the display for statuses of the wash program, which in traditional wash programs with individual metering of the substances are switched on, be switched off or disabled, such as for instance switching off an LED at the time of the regeneration 25 process or an LED which is the prompt for refilling the rinsing agent. In accordance with a preferred embodiment of the invention, when after the dirty wash load has been filled into the dishwasher a wash program is selected by the user of the dishwasher, a composition is placed into the dishwasher, and by an optionally added-on 30 selection means the use of a composition is displayed, the program sequence control will take into account the additional function and will determine that the program sequence of ClNRPortbhDCC\AZM\46949X_ I DOC.24/10/2012 - 12 the selected program is changed and in its entire lay-out adapted to the use of the composition. In this situation, depending on the selected program, individual or more parameters of the 5 different program cycles, pre-wash rinse, cleaning, intermediate rinse, final (clear) rinse, are automatically adapted in the manner described below or changed in fixly preset manner essentially depending on the evaluation of preset sensor measurements. The steps described in the claims do not represent with regard to their sequence an inevitable requirement for the program sequence, but can, for instance be selected specifically in 10 dependence of the use of a certain composition or type of composition; they can be repeated and/or switched consecutively or can be followed by other program steps which are known per se. In accordance with a preferred embodiment of the invention, when the "3inl" composition 15 is used in situations where dosing devices with usually divided storage chambers for the cleaning substance and the rinsing substance are in place, the metering function for the rinsing agent or the metering function for the cleaning agent is disabled in the selected wash program. In an alternative lay out, where for instance the detection of the concentration of the rinsing agent is sensor- dependent, it is possible to subsequently add 20 the required quantity of rinsing agent, thereby compensating for any dilution losses experienced during the preceding wash program cycle. Insofar as, during the selected wash program, further opening times are preset for the dosing device for the purpose of releasing a variety of substances, these will be locked or the timing of the addition of a certain substance delayed and/or the dosing quantity altered. 25 In the event the composition comprises in addition to the cleaning substance and the rinsing substance also a softening substance, which obviates the need for a softening process in the dishwasher in the known manner by means of a softening device provided, then it is naturally not necessary to perform in the dishwasher the known method of 30 regenerating the softener with saturated saline solutions (brine). Therefore, in accordance with a preferred embodiment of the invention, in the program sequence, the regeneration C \NRPonbRDCC\AZM\4694980.1 DOC-24/10/2012 - 13 function, i.e. the addition of a defined brine volume into the softening device, which is otherwise intended at a defined point of time in the program sequence, is disabled. Alternatively, a hardness sensor can be provided to ascertain the water hardness of the wash solution. The water hardness actually prevailing in the dishwasher following the 5 softening with the softening substance contained in the composition can then be monitored and, if necessary, the regeneration function of the softening device can be switched on in addition so that a partial softening of the water is performed via the softening device. Experience has shown that the softening properties of the softening substances contained in the ,,3inl"composition alone are not sufficient in hard water areas. It is therefore of 10 particular advantage when the information regarding the hardness level of the actually used water arriving from the supply lines be included in the program sequence design. The hardness level of the water can for instance be input by the user via a specially provided input function, for instance in the control panel, and be stored or can alternatively be set at a blending device where respective means pass on the value of the water hardness setting 15 to the program control, and when the ,,3inl" function is switched on or the ,,3inl" wash program is selected, the regenerating function and/or at least the blending of hard with soft water will be facilitated at least at a preset point of time. It is proposed to continue with the previously used water supply via the softening device 20 independent of its softening capacity which will be exhausted with increasing numbers of wash solution changes and depending on the hardness level of the supply water. All other alternatives for the water supply, though possible in theory, are only practical however, where compositions comprising a softening substance become the only available standard. 25 The water volume which may be stored in the storage container of the dishwasher and be defined for the regeneration function may alternatively, in particular in soft water areas, be used as a defined volume, as a whole or in portions, during the wash soloution-carrying program cycles for metering of predetermined wash solution volumes. 30 In accordance with a preferred embodiment of the invention, if during an introductory pre wash rinse the use of a composition is detected by the sensor or the use of such a C:\NRPonbl\DCC\AZM\4694)_DI OC-24/11/21II2 - 14 composition is indicated by way of an additional function being switched on, the duration of the initially intended pre-wash rinse cycle can be reduced to prevent the cleaning agents and rinsing agents also comprised therein from dissolving too soon; they will then be available in sufficient concentration during the cleaning or rinsing cycles. If, on the other 5 hand, a program has been selected which involves two or more pre-wash rinse cycles with a complete change of water for each cycle, the cancellation of at least one pre-wash rinse may result in running just one pre-wash rinse cycle, may prophylactically prevent, even without the sensor detection of a composition, that a composition erroneously placed into the dishwasher instead into the dosing device dissolves too soon. 10 If, as described above, the pre-wash rinse cycle is reduced or completely omitted, the period where the water acts upon the load is reduced, the presoaking process of stubborn, dried-on soiling, which may have been adhering to the dishes for a long time, may thereby be shortened or completely cancelled. In some cases of high levels of soiling, this is not 15 conducive to a good cleaning result. In such cases therefore, the duration of the cleaning cycle is preferably prolonged by the time period by which the duration of the pre-wash rinsing cycle was reduced. Thus, the presoaking of the dirt particles is at least partially moved forward into the 20 cleaning cycle. It is particularly preferred to reduce the number of intermediate rinse cycles between the cleaning and final (clear) rinse cycles to one intermediate rinse which essentially has the task of removing individual, still adhering dirt particles and chemical residues remaining 25 after the cleaning process. It is of further advantage to operate the intermediate rinse with a reduced maximum wash solution volume as compared with the maximum solution volume proposed for the cleaning cycle so that the concentration of the dissolved rinsing agent is higher than it would be in the same wash solution volume as used in the cleaning process. If, during the cleaning cycle, the wash solution is diluted several times and/or if by a 30 respective turbidity measurement a low level of soiling of the wash solution has been recognised, it may be possible to forego the intermediate rinse cycle altogether.
C:XNRPorbDCC\AZM\469490_ I DOC-24ilO/20 12 - 15 In accordance with a preferred embodiment of the invention, in the intermediate rinse cycle, which is operated with lukewarm wash solution and consequently does not involve active heating by switching on of heating elements provided, the energy supplied during 5 the process cycles which are operated with hot wash solution is extracted. In order to design the program in an energy-saving and water-saving manner as described above and thereby increasing the concentration of the rinsing agent in the intermediate rinse cycle, it can be proposed by repeated switching on and off of the circulating pump with variable and /or presettable duration of the switched on or off status of the circulating pump, to 10 introduce the wash solution into the tub and have it act upon the load in the manner of a ,,pulse rinsing". When switching off the circulating pump, the circulation of the wash solution and therefore the mechanical action of the wash solution upon the load is interrupted. This type of pulse rinsing can be briefly described by the following sequence: spraying, pause, spraying, pause, spraying, pause etc. 15 In accordance with a preferred embodiment of the invention, at the end of at least one process cycle, such as for instance the intermediate rinse, a dilution step can be proposed in dependence of the turbidity measurement and/or of the content of rinsing agent in the wash solution. The dilution step has the effect that a partial volume of the wash solution, which 20 was used during the intermediate rinse is again used in the subsequent final (clear) rinse cycle and is mixed with fresh was solution which is newly supplied. Due to the dilution step, the loss of rinsing agent, in particular, compared with a complete draining and refilling of wash solution is reduced. For this very reason, it is possible, independent of the measurement of the turbidity of the wash solution, to force a dilution step instead of a 25 complete draining of the wash solution, for instance at the end of the wash cycle. As a further or alternative step, it is preferred to reduce the temperature in the cycle preceding the final rinse, preferably in the cleaning cycle, to a temperature below the dissolution temperature of the rinsing agent, preferably below 58*C. In this way, for 30 instance in a selected intensive program, which usually operates the cleaning cycle at temperatures between 58 and 70*C, it is prevented that, when using a composition with a C:\NRPonbT\DCC\AZM46949N0_ .DOC-24110/2012 - 16 temperature-dependent release of the rinsing substance, the latter may already dissolve in this cycle and therefore will be available in too low a concentration in the final (clear) rinse cycle.
C:\NRPorbl\DCC\AZM\46949l)8 I .DOC-24/1/2012 - 17 THIS PAGE HAS BEEN INTENTIONALLY LEFT BLANK 18 In the final (clear) rinse cycle, the load is heated to a temperature of at least 584C for the subsequent drying cycle. This facilitates the temperature-dependent and possibly pH-value dependent dissolution of the rinsing agent. 5 It is advantageous, on the one hand, to determine the temperature levels of the wash solution during a selected wash cycle which is automatically adapted to the use of a composition, as discussed above, based on the dissolution temperatures of the individual chemical substances. On the other hand, in the interest of energy saving, if I 0 a pre-wash rinse is performed, the wash solution is not heated by switching on the heating means, so that the wash solution essentially has the temperature of the water supply. During the cleaning and final (clear) rinse cycles, the wash solution is actively heated following switching on of the heating mcans provided, and in the intermediate cycle is heated passively, i.e. by absorption of energy from the heat 15 capacities of the dishwasher, clearly to a temperature below the dissolution temperature of a temperature-dependent rinsing agent. Without restricting the invention, it is possible to have components of the dishwasher program with selection of "3inl" function either fully or partially run according to a 20 defined preset program or fully or partially adapted in a suitable manner to the actual situation relative to a predefined situation, based on the detection and evaluation of certain parameters, for instance by means of sensors.
19 The addition of the "3in I" function or the selection of a "3inI" program can optionally also be added to networked household appliances which are independently operated by a central computer which is not located in the dishwasher. 5 Besides the already known selectable programs, such as normal, intensive, economy, quick programs, a special "3in1" program can be made available which from the outset is especially adapted to the use of compositions, in particular such compositions which at the same time contain cleaning, softening and rinsing agents. The "3n l "program is directly selected by the user of the dishwasher and is characterised 10 by the essential process steps mentioned below. The sequence mentioned, which is however not an inevitable sequence of the process steps, presents a possible program sequence without the finishing cycle, the drying cycle: Alteration or switching off of the softening function of the regeneration device and/or I5 alteration or switching off of the opening of specially assigned storage chambers of the dosing device for further individually stored chemical substances (cleaning, rinsing agent) and/or alteration of the dosage to be added of the individually stored chemical substances. 20 Switching off of display elements associated with functions which during the program sequence, at least through the program control, are from the outset, i.e. preset to be switched off, preferably by switching off the display "regeneration" whilst the regeneration function is switched off by the regeneration device and/or switching off 20 the display "refill rinsing agent" when at least the automatic metering of the rinsing agent is switched off. The pre-wash rinse is undertaken with cold water - its temperature depending 5 essentially on the water supply temperature - for an extremely short duration of between 2 and 5 minutes. During this time, mainly fresh soiling can be loosened and soiling which has been adhering for longer periods is presoaked and softened. When the load has a high level of soiling and depending on an optional turbidity measurement of the wash solution, one or several dilution steps of the wash solution 10 can be proposed with one dilution step being proposed preferably at the end of the pre-wash rinse in view of the short duration of this pre-wash rinse. If, at the end of the pre-wash rinse no dilution step is provided, the wash solution is completely exchanged prior to the subsequent cycle. 15 The then freshly supplied wash solution, which can also be diluted and thus may be polluted to a certain degree, is now heated in the cleaning cycle to a temperature which is below the dissolution temperature of the rinsing agent, preferably between 40 and 57'C. 20 The composition is introduced into the dishwasher tub by the dosing device preferably within the first third of the cleaning cycle unless the composition, prior to the start of the wash program, has been placed into the tub or into the cutlery basket by the user.
21 At the aforementioned temperature, the wash solution is circulated in the tub for approx. 10 to 30 minutes during the cleaning cycle and, at the end of the cleaning cycle, is either fully drained or diluted. This decision can be made depending on an optional turbidity measurement of the wash solution. 5 If at least one turbidity measurement of the wash solution is taken, it is optional to perform several dilution steps depending on the degree of soiling and/or the concentration of individual constituents of the composition. The cleaning cycle is followed by an intermediate rinsing cycle, wherein the now present fresh or diluted 10 wash solution is passively heated, i.e. exclusively by energy extracted from heat capacities of the dishwasher, so that the wash solution during its circulation removes the last soil particles and chemical residues still remaining from the cleaning cycle. The circulation of the wash solution in the intermediate rinse cycle is for a duration of approx. 2 to 10 minutes. Altcmatively, the intermediate rinsing can also be performed 15 by "pulse rinsing" employing a reduced wash solution volume relative to the maximum wash solution volume present during the cleaning cycle. The intermediate rinse cycle is terminated with a complete or partial draining of the wash solution. 20 In the final (clear) rinse cycle a defined wash solution volume is supplied to the dishwasher tub. This can either be fixed from the outset and/or variably set depending on a variety of parameters. A dependent value in this situation is the concentration of the rinsing agent actually present in the wash solution, since this concentration 22 directly affects the final (clear) rinse result and thus the subsequently achievable drying result of the load. Thus, in the case of a low concentration of the rinsing agent at the commencement of the final (clear) rinse program cycle, the wash solution is introduced at as low a volume as possible, however depending on the turbidity level of 5 the wash solution. If however the concentration of the rinsing agent at the commencement of the final (clear) rinse cycle is above average or sufficiently high, the concentration of the rinsing agent can be adjusted to a predetermined concentration by way of a defined presettable wash solution volume being supplied. The wash solution with already dissolved rinsing agent, as well as the solution with 10 the rinsing agent still to be dissolved, is now preferably heated to a dissolution temperature above the dissolution temperature of a rinsing agent whose dissolution is pH value-dependent and temperature-dependent. This dissolution temperature is at present above 58'C (for the ,,3inI"composition Calgonit Powerballs@). For a duration of 2 to 1 5 minutes, however at least until a predetermined temperature is I5 reached (at present preferably 65 to 70'C), the wash solution is heated and circulated. At the end of the final (clear) rinse cycle, the wash solution is drained from the tub as far as possible by being pumped out. Residual solution remaining on the wash load, the tub ceiling and the tub walls as well 20 as steam are removed during the drying cycle, which follows the final (clear) rinse cycle. The drying process is preferably by way of condensation drying. During the condensation drying, preferably during the first third of this program cycle, at least one recirculating air blower, if available, is employed.
23 The intermediate rinsing during the wash solution-carrying cycles, can preferably be in the manner of pulse rinsing, i.e. that during the intermediate rinsing process the circulating pump is repeatedly switched on or off for a presettable or definable 5 duration. In this case the duration of the switching on or off of the circulating pump is depending on a wash solution level in the tub, which corresponds to a lower fill level at which the circulating pump does not draw in any air. Based on the aforementioned limited factors there exist further dependencies to the speed of the circulating pump which with increasing number of revolutions draws more wash solution from the 10 sump. The design of the switch on and off pulses is also settable in dependence of a turbidity measurement of the wash solution. Thus, where low soil content is present, the duration of the switched on state of the circulating pump relative to the switched off state of the circulating pump can be shortened and is respectively prolonged where a high soil content is present. In dependence of a pH-value measurement and/or the 15 temperature of the solution and/or a detected rinsing agent concentration, the maximum wash solution volume during a wash solution-carrying cycle, preferably in the intermediate rinse cycle, can be defined. In this way the dissolution behaviour and/or the concentration of the rinsing agent and/or one of the other substances of the composition can be influenced. If a composition is used which contains a rinsing 20 agent, which has a temperature-dependent and/or pH-value dependent dissolution behaviour, a defined pH-value, preferably in the neutral pH range must be reached during the intermediate rinsing. This presumes an increased wash solution volume during the intermediate rinsing as well as that this p--value can be reached by one or more dilution steps provided during the intermediate rinsing.
C.\NRPonbl\DCC\Z.M\46949' _l.DOC-24/10/2012 - 24 The invention is described in greater detail by way of a non-limiting embodiment example relating to the method for operating a domestic dishwasher which is suitable for the use of "3inl" compositions, namely such compositions containing the agents such as cleaning substance, rinsing substance and softening substance. 5 The only figure shows a schematic view of the individual cycle processes of a dishwasher program sequence. It is assumed herein that the water supply is essentially soft and thus has a low degree of hardness. 10 The ordinate of curve A does not show the time true to scale and the abscissa does not show the wash solution volume present in the tub true to scale. Individual important parameters for the cycle sequence, which are indispensable for a particularly good cleaning result of the wash load, are identified by arrows. Preferably, at the commencement of the program, automatic dosing functions which do not comprise the addition of "31nl" 15 compositions are disabled; this concerns in any case the automatic metering of the rinsing agent and, furthermore, the automatic regeneration function is disabled. As is shown in the figure, the dishwasher program comprises a pre-wash rinse of a very short duration of between 2 and 5 minutes at supply water temperature. 20 In this program cycle it is preferred not to add any chemical substances to the dishwasher to improve the pre-wash result. It can however not be prevented that the user may by mistake place the "3inl" composition into the dishwasher already prior to starting it. After complete drainage of the wash solution at the end of the pre-wash 25 rinse cycle, marked by arrow VV, fresh wash solution is supplied to the tub. This is limited to a maximum wash solution volume provided of approx. 4 1 for a dishwasher designed for a load of 12 standard sets of dishes. At the beginning of the cleaning cycle, the wash solution is heated by switching on heating means provided. The wash 5 solution shall reach a temperature of approx. 55*C which at the time of the invention corresponds to a temperature below the dissolution temperature of the rinsing agent in pH-dependent and temperature-dependent soluble "3inl" compositions, such as for instance Calgonit Powerballs@. In the first third of the cleaning cycle, the "3in!" composition is added, preferably during the supply of the wash solution (marked by 10 arrow "3 in "). The wash solution is circulated in the tub at the max. defined temperature and the wash load is subjected to this wash solution treatment for approx. 10 to 30 minutes. At the end of the cleaning cycle, the wash solution is almost completely drained from 15 the tub (marked by arrow VR). The wash solution volume is freshly filled up for a subsequent intermediate rinsing cycle and is heated exclusively by extracting energy which is stored in the heat capacities of the dishwasher and is then circulated. The max. supplied wash solution volume can be varied depending on a turbidity measurement and/or a concentration measurement of a rinsing agent which works 20 according to the dilution principle. Thus, as shown by the dotted line, the wash solution volume is preferably increased for high soil levels and/or high concentration levels of the rinsing agent and/or a strongly alkaline environment of the wash solution. At low levels of soiling, where a rather low concentration of the rinsing agent relative 26 to the concentration necessary for the rinsing cycle and/or an already neutral wash solution are present, the wash solution volume, shown as a dashed line, is reduced. The intermediate rinsing cycle, after a dilution step or after a complete draining (not 5 shown) for instance depending on the turbidity level, passes over into the final (clear) rinsing cycle. During this cycle, the wash solution volume is at least partially increased and preferably reaches the maximum possible wash solution volume of the cleaning cycle. Alternatively, the wash solution volume can be set exactly to a defined concentration range of the rinsing agent based on evaluated measuring results 10 of sensors in place. The value of the wash solution volume to be supplied must then be calculated by the computing unit of the program control. Thus the duration of the intermediate rinsing process varies between 2 and 10 min and the duration of the final (clear) rinse between approx. 2 and 15 min. During the sequence of the program, the temperature of the wash solution is then increased to above the dissolution 15 temperature of a pH value-dependent or temperature-dependent rinsing agent. The dissolution temperature of the rinsing agent is at present at approx. 58'C, so that in the final (clear) rinse the wash solution is heated to a minimum temperature of between 60 and 70'C. At the end of the final (clear) rinse cycle, the wash solution is almost completely drained from the tub (marked by arrow VK). The final (clear) rinse cycle 20 is followed by a drying cycle, which is not shown in the figure. Without hereby restricting the scope of the invention, all details relating to numerical values are adapted to presently commercially available "3inl" compositions (Calgonit C:NRPonblDCCAZM4694980 1.DOC-24110/2012 - 27 Powerball®, Somat 3inl@, Sun 3inl Optimal@). In the event the compositions of these 3inl preparations are changed, the parameters with numerical values will have to be adjusted accordingly. For a further modification of the program sequences suggested, we refer to parallel applications P-10073, Title "Method for the operation of a dishwasher" and 5 P-10026, Title: Method for the operation of a dishwasher, dishwasher" dtd. 16.05.2002. Without hereby restricting the invention, a program structure or a method is also feasible wherein the aforementioned invention is reversed, i.e. all the preset programs are designed for the use of ("3inl") compositions and by way of an activatable switching means an 10 adjustment of the selected wash program to the use of an individually rationed or metered cleaning agent, rinsing agent and softening agent is possible. Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" and "comprising", will 15 be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps. The reference to any prior art in this specification is not, and should not be taken as, an acknowledgement or any form of suggestion that that prior art forms part of the common 20 general knowledge in Australia.

Claims (21)

  1. 2. A method according to claim 1, wherein step (C) is executed. 15 3. A method according to claim 2, wherein in step (C) said definable volume of rinsing substance is added to the wash solution when the final (clear) rinse cycle is reached.
  2. 4. A method according to any one of the preceding claims, wherein step (F) is 20 executed and said duration of at least one program cycle therein is that of one pre wash rinse cycle.
  3. 5. A method according to any one of the preceding claims, wherein step (G) is executed and said two process cycles comprise a pre-wash rinse and cleaning 25 and/or cleaning and intermediate rinse cycles.
  4. 6. A method according to any one of the preceding claims, wherein step (J) is executed, in which step the at least one dilution step is undertaken at the end of a pre-wash rinse, cleaning and/or intermediate rinse cycles. 30 -11 N ( A~)(C'C 'l I I)I$.IX/i-t2 I)I -31
  5. 7. A method according to any one of the preceding claims, wherein step (K) is executed, in which step said maximum temperature is reduced in a cleaning cycle.
  6. 8. A method for operating a dishwasher according to any one of the preceding 5 claims, wherein, at least in a cleaning and final (clear) rinse cycle following switching on of heating means, the wash solution is actively heated.
  7. 9. A method according to claim 8, wherein, in an intermediate rinse cycle, the wash solution is passively heated without said heating means being switched on 10 and/or during the pre-wash rinsing the wash solution is essentially not actively heated.
  8. 10. A method for operating a dishwasher according to any one of the preceding claims, wherein, during intermediate rinsing and/or pre-wash rinsing, the heating 15 means is switched on and off for a very short period, repeatedly in intervals of different or equal length below or close to a dissolution temperature of' cleaning substance and/or softening substance and/or rinsing substance.
  9. 11. A method for operating a dishwasher, which can be selected - from amongst 20 several dishwasher programs with defined program sequences - as the dishwasher program for operating a dishwasher for the use of detergent compositions comprising several active substances wherein at least one of' the process steps recited in any one of the preceding claims is executed or several of' these process steps are consecutive or follow each other at intervals or are at least individually 25 repeated.
  10. 12. A method according to any one of the preceding claims, wherein at least one of the following process steps is Fixedly defined within a sequence of a dishwasher program adapted or selectable for use of a detergent composition 30 comprising several active substances: C \NRo h l ! NA A/\1\023 2 I I XU -I '/2|I I - 32 i) changing or switching off of a softening function of a regeneration device and/or changing or switching off of opening of special storage chambers of a dosing device; ii) switching off of corresponding indicators relating to functions which 5 during a program sequence at least by a program sequence control have been switched off from the outset, i.e. preset to be switched off; iii) pre-wash rinsing with cold, water supply temperature-dependent wash solution, complete wash solution change at an end of a pre-wash cycle, wherein one or more dilution steps with a wash solution change is 10 executed during pre-wash rinsing; iv) heating of wash solution in the cleaning cycle to a temperature which is below a dissolution temperature of rinsing agent: v) metering of a composition during heating of wash solution in a cleaning program cycle; 15 vi) circulation of wash solution in a tub of the dishwasher during a cleaning cycle at a cleaning temperature of 40C to 57C for 10 to 30 minutes, where, at the end of the cleaning cycle, the wash solution is completely drained or the cleaning cycle is terminated by at least one dilution step: 20 vii) passive heating of wash solution in an intermediate rinse cycle which is freshly supplied or blended with wash solution of a cleaning cycle and circulation of the wash solution in the tub for a duration of 2 to 10 minutes: viii) termination of the intermediate rinsing cycle with a complete or 25 partial draining, where the latter introduces a dilution step to a following process cycle; ix) filling up of wash solution to a defined and/or variably settable fill level of the wash solution in a final (clear) rinse cycle; x) heating of wash solution, by switching on of heating means, to 30 above a dissolution temperature of rinsing substance of the composition and C\NRl~orIbbJ)(Al*.Ox29' _LDOC- /~lI/08201 - 33 circulation of the wash solution with dissolved and "carried over" rinsing substance: and xi) complete draining of wash solution from a tub of the dishwasher at the end of a final (clear) rinse cycle, only after a rinsing substance 5 concentration for a denned time period has not fallen below a defined time period at least in the final (clear) rinse cycle.
  11. 13. A method according to claim 12, wherein step (iii) is fixedly defined within the sequence of the dishwasher program. 10
  12. 14. A method according to claim 13, wherein, in step (iii), pre-wash rinsing with cold, water supply temperaturc-dependent wash solution is carried out with a pre-wash duration of 2 to 5 minutes. 15 15, A method according to any one of claims 12 to 14. wherein step (iv) is lixedly defined within the sequence of the dishwasher program.
  13. 16. A method according to claim 15, wherein, in step (iv), said temperature which is below a dissolution temperature is between 45"C and 57C. 20
  14. 17. A method according to any one of claims 12 to 16, wherein step (v) is fixedly defined within the sequence of the dishwasher program, in which step said metering is at the beginning or in the first third of the cleaning program cycle. 25 18. A method according to any one of claims 12 to 17, wherein step (vi) is fixedly defined within the sequence of the dishwasher program. in which step the wash solution is completely drained depending on the results of a turbidity measurement of the wash solution. C N I ImbhDIX/Q/MU 1 . - 34 19. A method according to any one of claims 12 to 18, wherein step (vi) is fixedly defined within the sequence of the dishwasher program, in which step several dilution steps are executed during the cleaning cycle. 5 20. A method according to any one of claims 12 to 19. wherein step (x) is fixedly defined within the sequence of the dishwasher program. in which step the wash solution is heated to between 58"C and 70C.
  15. 21. A method according to any one of claims 12 to 20, wherein step (i) is 10 Fixedly defined and wherein in which step said changing or switching off' of opening of special storage chambers of the dosing device is effected.
  16. 22. A method for operating a dishwasher according to any one of claims 12 to 21, wherein a circulating pump of the dishwasher switched on and off for a 15 presettable or definable duration, wherein the duration of the switching on of the circulating pump or the switching off of the circulating pump is dependent on a wash solution level in a tub of the dishwasher and/or the speed of the circulating pump in a turbidity measurement of the wash solution, wherein a maximum present wash solution volume is set depending on wash solution temperature and/or 20 ascertained rinsing agent concentration and/or p-I value and/or a level of soil in a filter of the dishwasher.
  17. 23. A method according to claim 22, wherein the repeated switching on and off ofthe dishwasher is in the intermediate rinsing cycle. 25
  18. 24. A method according to any one of the preceding claims, wherein step (A) is executed.
  19. 25. A method according to claim 24, wherein in step (A) dosage of rinse aid is 30 reduced or completely disabled. C \NRPorbl\DCC\AZMW694KI LDOC-24/I/20'12 -35 26. A method according to any one of the preceding claims, wherein step (K) is executed.
  20. 27. A method according to any one of the preceding claims, wherein step (L) is 5 executed.
  21. 28. A method according to any one of the preceding claims, substantially as hereinbefore described with reference to the drawings and/or Examples.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5960804A (en) * 1995-04-12 1999-10-05 Maytag Corporation Cycle selection method and apparatus
DE19957243A1 (en) * 1999-11-27 2001-05-31 Aeg Hausgeraete Gmbh Dishwasher has controller that sets wash program parameters to approximately set advantageous washing atmosphere for active substance until substance starts to lose effectiveness

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5960804A (en) * 1995-04-12 1999-10-05 Maytag Corporation Cycle selection method and apparatus
DE19957243A1 (en) * 1999-11-27 2001-05-31 Aeg Hausgeraete Gmbh Dishwasher has controller that sets wash program parameters to approximately set advantageous washing atmosphere for active substance until substance starts to lose effectiveness

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