AU2009101361A4 - Preparation method for silver metal oxide made electric contact material - Google Patents

Preparation method for silver metal oxide made electric contact material Download PDF

Info

Publication number
AU2009101361A4
AU2009101361A4 AU2009101361A AU2009101361A AU2009101361A4 AU 2009101361 A4 AU2009101361 A4 AU 2009101361A4 AU 2009101361 A AU2009101361 A AU 2009101361A AU 2009101361 A AU2009101361 A AU 2009101361A AU 2009101361 A4 AU2009101361 A4 AU 2009101361A4
Authority
AU
Australia
Prior art keywords
meo
contact material
electrical contact
powders
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2009101361A
Inventor
Jian Li
Xiaodong Lu
Bin Wang
Chunping Wu
Canhui Xu
Danqing Yi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central South University
Original Assignee
Central South University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central South University filed Critical Central South University
Application granted granted Critical
Publication of AU2009101361A4 publication Critical patent/AU2009101361A4/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G5/00Compounds of silver
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G29/00Compounds of bismuth
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G30/00Compounds of antimony
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00Compounds of molybdenum
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00Compounds of zinc
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/023Composite material having a noble metal as the basic material

Abstract

The present invention discloses a method for producing Ag-MeO electrical contact material. Firstly, Ag-Me alloy powders with homogeneous composition and fine grain size are prepared by gas atomization. The alloy powders 5 are internally oxidized to form Ag-MeO composite powders, and the Ag-MeO composite powders are processed by die processing and powder hot extrusion to form an electrical contact material. The present invention features a low internal oxidation temperature, a short processing duration, and a simple technique. The present invention solves difficult-to-machine problem of Ag-MeO material, and reduces the 10 manufacturing cost. In addition, the present invention improves the microstructure of the electrical contact material, and enhances the overall properties of the electrical contact material.

Description

Method for Producing Ag-MeO Electrical Contact Material FIELD OF THE INVENTION The present invention relates to the field of electrical functional 5 materials, and particularly to a method for producing a silver-based electrical contact material. BACKGROUND OF THE INVENTION The Ag-MeO (metal oxide) contact material came out between 1920s 10 and 1930s. At the end of 1930s, F. R. Hensel and his colleagues manufactured the first Ag-CdO material. At the end of 1960s, the Ag-MeO contact material, such as Ag-SnO 2 , Ag-ZnO or the like, started to appear. Ag-CdO has been widely applied in the engineering due to its excellent properties. However, "cadmium poisoning" pollution occurs during production and usage stage of the Ag-CdO material, which 15 attracts the attention of the governments around the world. In the development of medium or low-pressure electrical contact material, it is an important trend to develop a new Ag-MeO which can replace the Ag-CdO contact, and to further improve the alloy properties. Nevertheless, the difficult-to-machine problem prevails in the new Cd-free Ag-MeO contact material, such as Ag-SnO 2 , Ag-ZnO or the like. Therefore, it 20 is necessary to develop a new manufacturing process with high efficiency and low cost. The current methods for producing Ag-MeO contact material mainly comprise alloy internal oxidation and powder metallurgy. The powder metallurgy comprises powder mixing, co-depositing, and coating. In the method of powder 25 mixing, a silver powder and a metal oxide powder are mixed, molded, and sintered. It is required in such a process that the powders of raw materials must be very fine to provide a homogeneous structure. However, too small powders are prone to agglomerate, thus making it difficult to mix homogeneously. Besides, it is relatively difficult to prepare a raw material powder with a grain size less than 5 im. Therefore, 30 this process is limited in applications. During preparing an Ag-MeO composite powder by co-depositing or coating, pollution like waste water or gas will occur. Besides, there is a poor wetting between silver and the metal oxide in the Ag-MeO contact material, which results in a low resistance to arc erosion of such a material. In addition, the oxide particles deposited on the surface of contact increase the contact 5 resistance of the material. The internal oxidation of an alloy bulk is suitable for mass production, but is has the following disadvantages. During the internal oxidation, oxygen atoms have to diffuse in the dense body of alloy, and the gradient of its density will lead to change in microstructure of the material, which is unfavorable for electrical properties of the material. At the same time, there are limitations to the size 10 of product and the content of oxide. By the method of alloy powder oxidation, it is possible to avoid the above problems. However, the Ag-MeO composite powder, which is obtained by oxidizing the silver alloy powder, is required to go through pressing, sintering, re-pressing, re-sintering, and repetitive extrusion and drawing to complete a finished product. The production flow is long. Besides, due to hardening 15 during extrusion and drawing, MeO particles easily agglomerate together, and the generated stress is concentrated, so that it is relatively difficult to further process the material. SUMMARY OF THE INVENTION 20 It is an object of the present invention to solve the problems of difficult-to-oxidize sufficiently, difficult-to-machine, and long-production-flow of Ag-MeO material. Also, it is an object of the present invention to enhance the binding between the dispersed oxides and the silver matrix, improve the overall properties of the products, shorten the production flow, and reduce the manufacturing cost. 25 The solution of the present invention resides in a method for producing Ag-MeO electrical contact material, which comprises the steps of: melting Ag and Me in a designed ratio; atomizing Ag and Me with an atomization device into Ag-Me alloy powders with homogeneous composition and fine grain size; 30 - performing an internal oxidization on the alloy powders to form Ag-MeO 2 composite powders; and processing the Ag-MeO composite powders by die processing and then powder hot extrusion to form an electrical contact material. The metal Me in said Ag-Me alloy may be one or more of Sn, Zn, Cu, La, 5 Ce, Sb, Bi, Mo, Al, Ti, Mg, Y, wherein Ag in the Ag-Me alloy amounts to 85%-92% by weight. Preferably, the oxidation parameters for said internal oxidation comprise a temperature of 400-800 'C and an oxygen pressure of 0.21-50 atm. The duration of the internal oxidation is 3-6 hr. 10 The Ag-MeO composite powder is processed by die processing into a green body with a relative density of 65%-80%. As for preferred conditions for the hot extrusion, the temperature for extrusion is 600-850 *C, and the extrusion ratio is 12:1-200:1. The Ag-Me alloy powder can be dried and screened before internal 15 oxidization. The present inventor prepares Ag-Me alloy powders with homogeneous composition and fine grain size by gas atomization, then internally oxidizes the powders to form Ag-MeO composite powders, and further processes the Ag-MeO composite powders by die processing and then powder hot extrusion to form an 20 electrical contact material. By means of the above process innovation, the cumbersome sintering, re-pressing, re-sintering, and repetitive extrusion and drawing in the prior art process are omitted, so that the production efficiency is increased and the manufacturing cost is reduced. Since the materials in the powder green body still substantially stay in the powder state and have certain deformation and mobility under 25 extrusion force. As compared with extrusion of dense metal materials, the required extrusion force is small and the range of temperature and speed for extrusion is large. Therefore, the difficult-to-machine problem of Ag-MeO material is solved, the microstructure of the Ag-MeO contact material is improved, and thus the overall properties are enhanced. 30 According to the present invention, the specific processes comprise: 3 melting Ag and Me in a designed ratio in a medium frequency induction furnace; - atomizing the alloy in an atomization device with compressed air; screening the atomized alloy powders; 5 - loading powders with a grain size below 325 mesh into an oxidation furnace to be oxidized, with the temperature for oxidation being controlled at 500-800 'C, the pressure for oxygen being kept at 0.21-50 atm, and the oxidation lasting for 3-6 hr; processing the powders, which have been tested and qualified in terms of 10 composition and microstructure, by die processing into green bodies with a relative density of 65%-80%; loading the green bodies, which have been heated to 600-850 'C, into an extrusion mold which has been preheated to 300-500 'C; and performing hot extrusion to form Ag-MeO rods or wires. 15 The advantages of the present invention comprise: the atomized alloy powders are more easily oxidized that cast alloys, so that the duration for oxidation can be decreased and the occurrence of metal-poor oxide region can be prevented, and the resulting MeO particles are dispersed in the composite powders. Besides, since the powder hot extrusion process is applied in the present invention, the cumbersome 20 sintering, re-pressing, re-sintering, and repetitive extrusion and drawing can be omitted, the manufacturing cost can be saved, and the difficult-to-machine problem of Cd-free Ag-MeO material can be solved. Besides, the microstructure of Ag-MeO contact material is improved, and the overall properties are increased. By means of the improvement and innovation to the complete process accomplished by the present 25 inventor, the complete process flow becomes simple and can effectively solve the problems of difficult-to-oxidize sufficiently, difficult-to-machine, and long-production-flow of Ag-MeO material. In addition, the binding between the dispersed oxides and the silver matrix is enhanced, the overall properties of the products are improved, the production flow is shortened, and the manufacturing cost 30 is reduced. 4 It is further preferred in the present invention that Ag and Me are mixed in a designed ratio and then melt in a medium frequency induction furnace, so that it is ensured to effectively provide a homogeneous composition of the alloy. 5 BRIEF DESCRIPTION OF THE DRAWINGS Fig. I is a flow chart showing a specific process of the present invention; Fig. 2 shows in a cross section a microstructure of a product of the present invention, which is magnified by 100; Fig. 3 shows in a longitudinal section a microstructure of a product of 10 the present invention, which is magnified by 100; Fig. 4 shows in a cross section a microstructure of a product of a comparative example, which is magnified by 100; Fig. 5 shows in a longitudinal section a microstructure of a product of a comparative example, which is magnified by 100. 15 DETAIL DESCRIPTION OF THE EMBODIMENTS The following embodiments intend to illustrate, but not further restrict the present invention. Embodiment 1 20 Silver 2004 g, tin 112.5 g, and antimony 76.5 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, the alloy is atomized in an atomization device with compressed air. The atomized alloy powders are screened, and the powders with a grain size below 325 mesh are loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 800 'C, and the 25 pressure for oxygen is kept at 50 atm. The oxidation lasts for 6 hr. The powders are then processed by die processing into green bodies with a diameter of 28 mm and a relative density of 70%. Then, the green bodies, which have been heated to 800 'C, are loaded into a mold which has been preheated to 500 'C, and are subject to hot extrusion to form products with a diameter of 4 mm. 30 Embodiment 2 5 Silver 2000 g, zinc 223 g, lanthanum 105 g, and yttrium 25 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, the alloy is atomized in an atomization device with compressed air. The atomized alloy powders are screened, and the powders with a grain size below 325 mesh are 5 loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 400 'C, and the pressure for oxygen is kept at 10 atm. The oxidation lasts for 3 hr. The powders are then processed by die processing into green bodies with a diameter of 28 mm and a relative density of 75%. Then, the green bodies, which have been heated to 600 *C, are loaded into a mold which has been preheated 10 to 450 *C, and are subject to hot extrusion to form products with a diameter of 8 mm. Embodiment 3 Silver 2000 g, copper 110.5 g, antimony 82.9 g, and cerium 20 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, the alloy is atomized in an atomization device with compressed air. The atomized 15 alloy powders are screened, and the powders with a grain size below 325 mesh are loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 700 *C, and the pressure for oxygen is kept at 25 atm. The oxidation lasts for 5 hr. The powders are then processed by die processing into green bodies with a diameter of 28 mm and a relative density of 80%. Then, the green bodies, 20 which have been heated to 830 'C, are loaded into a mold which has been preheated to 300 'C, and are subject to hot extrusion to form products with a diameter of 4 mm. Embodiment 4 Silver 2005 g, cerium 160 g, bismuth 10 g, and lanthanum 5 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, 25 the alloy is atomized in an atomization device with compressed air. The atomized alloy powders are screened, and the powders with a grain size below 325 mesh are loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 650 0 C, and the pressure for oxygen is kept at 20 atm. The oxidation lasts for 5 hr. The powders are then processed by die processing into green bodies 30 with a diameter of 28 mm and a relative density of 80%. Then, the green bodies, 6 which have been heated to 800 'C, are loaded into a mold which has been preheated to 450 'C, and are subject to hot extrusion to form products with a diameter of 2 mm. Embodiment 5 Silver 1980 g, lanthanum 155 g, molybdenum 43.7 g, magnesium 10 g, 5 and antimony 15 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, the alloy is atomized in an atomization device with compressed air. The atomized alloy powders are screened, and the powders with a grain size below 325 mesh are loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 750 'C, and the pressure for oxygen is kept at 10 atm. 10 The oxidation lasts for 3 hr. The powders are then processed by die processing into green bodies with a diameter of 28 mm and a relative density of 75%. Then, the green bodies, which have been heated to 820 *C, are loaded into a mold which has been preheated to 400 'C, and are subject to hot extrusion to form products with a diameter of 6 mm. 15 Embodiment 6 Silver 2003 g, tin 157 g, aluminum 43.7 g, yttrium 5 g, and titanium 10 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, the alloy is atomized in an atomization device with compressed air. The atomized alloy powders are screened, and the powders with a grain size below 325 20 mesh are loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 600 'C, and the pressure for oxygen is kept at 5 atm. The oxidation lasts for 3 hr. The powders are then processed by die processing into green bodies with a diameter of 28 mm and a relative density of 70%. Then, the green bodies, which have been heated to 850 'C, are loaded into a mold which has been 25 preheated to 450 'C, and are subject to hot extrusion to form products with a diameter of 4 mm. Comparative example 7 Silver 2004 g, tin 112.5 g, and antimony 76.5 g are weighed and put into a medium frequency induction furnace to melt. Upon melting, the alloy is atomized in 30 an atomization device with compressed air. The atomized alloy powders are screened, 7 and the powders with a grain size below 325 mesh are loaded into an oxidation furnace to be oxidized. The temperature for oxidation is controlled at 800 'C, and the pressure for oxygen is kept at 50 atm. The oxidation lasts for 6 hr. The oxidized powders are pressed and then sintered at 830 'C for 2 hr. The sintered blanks are 5 forged at 820 *C to complete the products. Performance Index for the embodiments and the comparative example Products Relative Hardness Resistivity Tensile Elongation density (%) (HV/MPa) (pQ -cm) strength rate (%) (MPa) Embodiment 1 98.9 950 2.3 380 23 Embodiment 2 99.0 870 2.5 340 30 Embodiment 3 99.4 700 2.2 300 30 Embodiment 4 99.5 650 2.1 280 36 Embodiment 5 99.6 800 2.2 320 28 Embodiment 6 99.7 750 2.1 360 25 Comparative 98.5 1000 2.5 400 25 example 7 8

Claims (6)

1. A method for producing Ag-MeO electrical contact material, characterized in that the method comprises the steps of: 5 - melting Ag and a metal Me in a designed ratio; atomizing Ag and Me with an atomization device into Ag-Me alloy powders with homogeneous composition and fine grain size; performing an internal oxidization on the alloy powders to form Ag-MeO composite powders; and 10 - processing the Ag-MeO composite powders by die processing and then powder hot extrusion to form an electrical contact material.
2. The method for producing Ag-MeO electrical contact material according to claim 1, characterized in that: the metal Me in said Ag-Me alloy is one or more of Sn, Zn, Cu, La, Ce, 15 Sb, Bi, Mo, Al, Ti, Mg, Y, wherein Ag in the Ag-Me alloy amounts to 85%-92% by weight.
3. The method for producing Ag-MeO electrical contact material according to claim 1, characterized in that: the oxidation parameters for said internal oxidation comprise a 20 temperature of 400-800 'C and an oxygen pressure of 0.21-50 atm.
4. The method for producing Ag-MeO electrical contact material according to claim 3, characterized in that: - the duration of the internal oxidation is 3-6 hr.
5. The method for producing Ag-MeO electrical contact material according 25 to claim 1, characterized in that: the Ag-MeO composite powders are processed by die processing into green bodies with a relative density of 65%-80%.
6. The method for producing Ag-MeO electrical contact material according to claim I or 5, characterized in that: 30 - the temperature for extrusion is 600-850 'C, and the extrusion ratio is 9 12:1-200:1. 10
AU2009101361A 2009-07-08 2009-09-24 Preparation method for silver metal oxide made electric contact material Ceased AU2009101361A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200910304113.X 2009-07-08
CN200910304113XA CN101609755B (en) 2009-07-08 2009-07-08 Preparation method of silver-metallic oxide electrical contact material

Publications (1)

Publication Number Publication Date
AU2009101361A4 true AU2009101361A4 (en) 2012-03-01

Family

ID=41483450

Family Applications (2)

Application Number Title Priority Date Filing Date
AU2009101361A Ceased AU2009101361A4 (en) 2009-07-08 2009-09-24 Preparation method for silver metal oxide made electric contact material
AU2009349420A Pending AU2009349420A1 (en) 2009-07-08 2009-09-24 Preparation method for silver metal oxide made electric contact material

Family Applications After (1)

Application Number Title Priority Date Filing Date
AU2009349420A Pending AU2009349420A1 (en) 2009-07-08 2009-09-24 Preparation method for silver metal oxide made electric contact material

Country Status (3)

Country Link
CN (1) CN101609755B (en)
AU (2) AU2009101361A4 (en)
WO (1) WO2011003225A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102350502B (en) * 2011-10-27 2013-01-09 福达合金材料股份有限公司 Preparation method of silver-stannic oxide by using physical metallurgical coating method
CN103824711B (en) * 2013-12-20 2016-01-20 宁波赛特勒电子有限公司 A kind of double silver base composite oxidate electric contact material and application thereof
CN103762099B (en) * 2013-12-20 2016-06-22 宁波赛特勒电子有限公司 A kind of money base composite oxides electric contact material and application thereof
CN103722041B (en) * 2013-12-26 2017-01-11 浙江科扬新材料科技有限公司 Manufacturing equipment and method of compound silver belt
CN104525968A (en) * 2014-12-30 2015-04-22 桂林电器科学研究院有限公司 Flaky silver-tungsten electrical contact material preparation method
CN106158436B (en) * 2016-07-20 2019-04-30 永兴金荣材料技术有限公司 Ag-based electrical contact and its manufacturing method, special equipment, particular manufacturing craft
CN107400819A (en) * 2017-06-15 2017-11-28 昆明理工大学 A kind of preparation method of nano-metal-oxide enhancing Ag-based electrical contact material
CN108165797A (en) * 2017-12-27 2018-06-15 洛阳神佳窑业有限公司 A kind of preparation method of Zn-base alloy
CN108149122A (en) * 2017-12-27 2018-06-12 洛阳神佳窑业有限公司 A kind of preparation method of silver-base alloy contact material
CN109994327B (en) * 2019-04-30 2020-12-01 温州宏丰电工合金股份有限公司 AgMe contact material for circuit breaker and preparation method thereof
CN114262815B (en) * 2021-02-01 2022-05-31 中南大学 Silver-metal oxide composite material, preparation method thereof and application of silver-metal oxide composite material as electrical contact material
CN114262812B (en) * 2021-02-28 2022-05-31 中南大学 Dispersion strengthening superfine crystal silver-based-metal oxide composite material and preparation method thereof
CN114512359B (en) * 2022-01-05 2023-08-01 浙江福达合金材料科技有限公司 Silver metal oxide inlaid composite strip and preparation method thereof

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07320608A (en) * 1994-05-19 1995-12-08 Toshiba Corp Manufacture of contact material
JPH08143989A (en) * 1994-11-28 1996-06-04 Matsushita Electric Works Ltd Production of electrical contact material
CN1311487C (en) * 2003-10-28 2007-04-18 章景兴 Electric contact material based on slver, zinc oxide and indium oxide and manufacturing technique
CN100444294C (en) * 2005-09-01 2008-12-17 中南大学 Method for manufacturing sliver oxidized tin contactor materials
CN101038818A (en) * 2007-04-05 2007-09-19 章景兴 Electric contact material alloy based on silver tin Oxide-lanthanum oxide and production process therefor
CN101202170B (en) * 2007-10-23 2011-06-08 福达合金材料股份有限公司 Method of preparing sheet silver tin oxide electrical contact material
CN101202169A (en) * 2007-10-23 2008-06-18 福达合金材料股份有限公司 Method of preparing novel silver tin oxide silk electrical contact material
CN101217074B (en) * 2008-01-14 2011-02-23 中希合金有限公司 A silver tin/copper oxide compound electrical contact and preparation method

Also Published As

Publication number Publication date
AU2009349420A1 (en) 2012-02-02
AU2009349420A8 (en) 2012-02-16
WO2011003225A1 (en) 2011-01-13
CN101609755B (en) 2012-07-25
CN101609755A (en) 2009-12-23

Similar Documents

Publication Publication Date Title
AU2009101361A4 (en) Preparation method for silver metal oxide made electric contact material
US9761342B2 (en) Method of preparing silver-based oxide electrical contact materials with fiber-like arrangement
CN107794389B (en) Silver tin oxide indium oxide electric contact material and preparation method thereof
CN104711443B (en) A kind of graphene/copper composite material and preparation method thereof
CN101586198B (en) A process for preparing aluminum oxide dispersion strengthened copper with high strength and high conductivity
CN102312119B (en) Preparation method for silver tin oxide electrical contact material
CN101649399B (en) Preparation method of tin-oxygen-silver electric contact material
CN103695682B (en) A kind of silver oxide contact material and preparation method and products thereof with strengthening substrate performance additive
EP2537949B1 (en) Method for preparing fibrous silver-based electrical contact material
CN101202169A (en) Method of preparing novel silver tin oxide silk electrical contact material
CN1230566C (en) Preparation method of siluer metal oxide electric contact material
CN100402195C (en) Silver composite tin oxide contact material and its preparation technology
CN101241804A (en) A silver-ZnO electric contact and its making method
CN102350502B (en) Preparation method of silver-stannic oxide by using physical metallurgical coating method
CN103184384B (en) A kind of preparation method of Composite silver stannic oxide electric contact material
CN111468719B (en) Silver tin oxide sheet-shaped electrical contact and preparation method thereof
CN105200262B (en) A kind of preparation method of high oxidation Theil indices silver-based sheet electrical contact material
CN1141406C (en) Process for preparing Cu-Al2O3 composition
CN112501464B (en) Silver-nickel composite material and preparation method thereof
CN109593981B (en) Preparation method of silver tin oxide contact material for improving sintering property of ingot blank
WO2012088735A1 (en) Method for preparing fibrous silver-based oxide electrical contact material
CN105695782A (en) Preparation method of silver metal oxide electrical contact material
CN102509654B (en) Preparation method for silver stannic oxide wire
CN109609794A (en) A kind of preparation method of high ductility sliver oxidized tin contactor materials
CN108220650A (en) A kind of multicomponent oxide enhancing silver-based electric contact material and preparation method thereof

Legal Events

Date Code Title Description
FGI Letters patent sealed or granted (innovation patent)
MK22 Patent ceased section 143a(d), or expired - non payment of renewal fee or expiry