AT537196T - Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated diene - Google Patents

Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated diene

Info

Publication number
AT537196T
AT537196T AT00121834T AT00121834T AT537196T AT 537196 T AT537196 T AT 537196T AT 00121834 T AT00121834 T AT 00121834T AT 00121834 T AT00121834 T AT 00121834T AT 537196 T AT537196 T AT 537196T
Authority
AT
Austria
Prior art keywords
production
copolymer
catalyst
ethylene
conjugated diene
Prior art date
Application number
AT00121834T
Other languages
German (de)
Inventor
Fanny Barbotin
Christophe Boisson
Roger Spitz
Original Assignee
Michelin Soc Tech
Michelin Rech Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9912798A priority Critical patent/FR2799468B1/en
Application filed by Michelin Soc Tech, Michelin Rech Tech filed Critical Michelin Soc Tech
Publication of AT537196T publication Critical patent/AT537196T/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/083Copolymers of ethene with aliphatic polyenes, i.e. containing more than one unsaturated bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
AT00121834T 1999-10-12 2000-10-06 Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated diene AT537196T (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR9912798A FR2799468B1 (en) 1999-10-12 1999-10-12 Catalytic system for use in the copolymerization of ethylene and a conjugated diene, process for the preparation of this catalytic system, and copolymer of ethylene and conjugated diene

Publications (1)

Publication Number Publication Date
AT537196T true AT537196T (en) 2011-12-15

Family

ID=9550906

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00121834T AT537196T (en) 1999-10-12 2000-10-06 Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated diene

Country Status (9)

Country Link
US (2) US6569799B1 (en)
EP (2) EP1092731B1 (en)
JP (1) JP4806784B2 (en)
KR (1) KR100722171B1 (en)
CN (1) CN1205238C (en)
AT (1) AT537196T (en)
BR (1) BR0004778B1 (en)
CA (1) CA2321362C (en)
FR (1) FR2799468B1 (en)

Families Citing this family (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100826080B1 (en) * 2001-12-27 2008-04-29 삼성토탈 주식회사 Copolymerization method of ethylene/diene having high melt strength
CN101045770A (en) 2002-10-16 2007-10-03 米其林技术公司 Ethylene/butadiene copolymers, catalytic system of producing same and production of said polymers
WO2004044018A2 (en) * 2002-11-07 2004-05-27 Dow Global Technologies, Inc. Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby
FR2858817B1 (en) * 2003-08-13 2006-02-03 Michelin Soc Tech Catalytic system for obtaining conjugated (s) / mono-olefine (s) diene (s) copolymers and copolymers
US7294649B2 (en) * 2004-12-17 2007-11-13 Roche Diagnostics Operatins, Inc. Methamphetamine derivatives and conjugates for immunoassay
WO2007016700A2 (en) * 2005-08-04 2007-02-08 The Regents Of The University Of Colorado, A Body Corporate Catalysts for radical polymerization
FR2893029B1 (en) 2005-11-09 2009-01-16 Michelin Soc Tech Metalocene complex borohydride of lanthanide, incorporating catalytic system, polymerization method using the same, and ethylene / butadiene copolymer obtained by this process
FR2893028B1 (en) * 2005-11-09 2008-02-15 Michelin Soc Tech METALOCENE COMPLEX BOROHYDRIDE OF LANTHANIDE, INCORPORATING CATALYTIC SYSTEM, POLYMERIZATION METHOD USING THE SAME, AND ETHYLENE / BUTADIENE COPOLYMER OBTAINED BY THIS PROCESS
FR2893030B1 (en) * 2006-10-17 2011-04-15 Michelin Soc Tech COPOLYMER ETHYLENE / BUTADIENE
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
KR20120052385A (en) * 2009-08-07 2012-05-23 가부시키가이샤 브리지스톤 Method for producing copolymer
FR2954332B1 (en) 2009-12-22 2012-01-13 Michelin Soc Tech Particularly pneumatic article with external rubber mixture comprising a salt of lanthanide
JP5823674B2 (en) * 2010-07-30 2015-11-25 株式会社ブリヂストン Copolymer of conjugated diene compound and non-conjugated olefin
RU2542992C2 (en) * 2010-07-30 2015-02-27 Бриджстоун Корпорейшн Method of regulating copolymer chain structure
JP5557642B2 (en) * 2010-07-30 2014-07-23 株式会社ブリヂストン Copolymer of conjugated diene compound and non-conjugated olefin
JP5917809B2 (en) * 2010-11-30 2016-05-18 株式会社ブリヂストン Copolymer, production method thereof, rubber composition, crosslinked rubber composition, and tire
CN103476813A (en) * 2011-02-04 2013-12-25 株式会社普利司通 Copolymer, rubber composition, rubber composition for tire side use, crosslinked rubber composition, and tire
JP5932224B2 (en) 2011-02-04 2016-06-08 株式会社ブリヂストン Copolymer, rubber composition, crosslinked rubber composition, and tire
JP5731217B2 (en) * 2011-02-04 2015-06-10 株式会社ブリヂストン Copolymer, rubber composition, crosslinked rubber composition, and tire
CN103459402B (en) 2011-02-05 2016-09-07 株式会社普利司通 Lanthanide complexes catalyst and use its polymerization
JP5612511B2 (en) * 2011-02-28 2014-10-22 株式会社ブリヂストン Rubber composition, crosslinked rubber composition, and tire
EP2900702B1 (en) 2012-09-30 2018-05-02 Bridgestone Corporation Polymerization method employing an organometallic catalyst complex
WO2014055868A1 (en) 2012-10-04 2014-04-10 Bridgestone Corporation Organometallic complex catalyst and polymerization method employing same
FR3001223B1 (en) * 2013-01-22 2015-03-06 Michelin & Cie Rubber composition comprising a highly saturated dienic elastomer
CN106536414B (en) 2014-05-30 2018-12-04 株式会社普利司通 Metal complex catalyst and the polymerization for using metal complex catalyst
EP3738927A1 (en) 2014-05-31 2020-11-18 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same and polymer products thereof
FR3037588B1 (en) 2015-06-19 2017-05-19 Michelin & Cie THERMOPLASTIC ELASTOMERIC COPOLYMER BASED ON DIENE ELASTOMER AND POLYPROPYLENE, COMPOSITIONS COMPRISING THE SAME, AND PROCESS FOR PREPARING THE SAME
CN108137746A (en) * 2015-10-16 2018-06-08 株式会社普利司通 Multiple copolymer, rubber composition, crosslinked rubber composition, rubber and tire
EP3363826A4 (en) * 2015-10-16 2019-03-13 Bridgestone Corporation Multi-component copolymer, resin composition, cross-linked resin composition, and product
FR3044241A1 (en) * 2015-12-01 2017-06-02 Michelin & Cie CATALYTIC SYSTEM COMPRISING RARE EARTH METALLOCENE
FR3044662B1 (en) 2015-12-03 2017-12-08 Michelin & Cie Preformed catalytic system comprising rare earth metallocene
FR3044664B1 (en) 2015-12-08 2017-12-29 Michelin & Cie Monofunctional or telechelic copolymer of 1,3-diene and ethylene or alpha-monoolefin.
FR3044663B1 (en) 2015-12-08 2017-12-29 Michelin & Cie MONOFUNCTIONAL OR TELECHELIC COPOLYMER OF 1,3-BUTADIENE AND ETHYLENE
FR3045612B1 (en) 2015-12-17 2017-12-15 Michelin & Cie COPOLYMER OF ETHYLENE AND BUTADIENE OF HOMOGENEOUS MICROSTRUCTURE
FR3045613B1 (en) 2015-12-17 2017-12-15 Michelin & Cie COPOLYMER OF ETHYLENE AND BUTADIENE OF HOMOGENEOUS MICROSTRUCTURE
FR3045633B1 (en) 2015-12-22 2017-12-15 Michelin & Cie Pneumatic comprising a rubber composition comprising a substituted dienic elastomer
WO2017170654A1 (en) 2016-03-31 2017-10-05 Compagnie Generale Des Etablissements Michelin A tire having a tread comprising a rubber composition
EP3436287B1 (en) 2016-03-31 2019-12-25 Compagnie Générale des Etablissements Michelin A tire having a tread comprising a rubber composition
FR3054222A1 (en) 2016-07-25 2018-01-26 Compagnie Generale Des Etablissements Michelin Process for preparing a catalytic system based on rare earth metallocene
FR3054221A1 (en) 2016-07-25 2018-01-26 Compagnie Generale Des Etablissements Michelin Preformed catalytic system comprising rare earth metallocene
FR3054220A1 (en) 2016-07-25 2018-01-26 Compagnie Generale Des Etablissements Michelin Preformed catalytic system comprising rare earth metallocene
FR3059254A1 (en) 2016-11-30 2018-06-01 Compagnie Generale Des Etablissements Michelin Preformed catalytic system comprising rare earth metallocene
FR3060004B1 (en) 2016-12-09 2019-05-24 Compagnie Generale Des Etablissements Michelin ORGANOMETALLIC COMPOUND HAVING IMINOPHOSPHORANE FUNCTION
FR3060007A1 (en) 2016-12-09 2018-06-15 Compagnie Generale Des Etablissements Michelin TERPOLYMERS OF ETHYLENE, 1,3-BUTADIENE OR ISOPRENE, AND AROMATIC ALPHA-MONOOLEFIN
US20200040166A1 (en) 2017-03-08 2020-02-06 Compagnie Generale Des Etablissements Michelin Tire having a composition comprising an ethylyne-rich elastomer, a peroxide and a zinc acrylate
FR3063732A1 (en) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatic having a composition comprising an ethylene-rich elastomer, a peroxide and a polyfunctional acrylate derivative
FR3065004A1 (en) 2017-04-10 2018-10-12 Compagnie Generale Des Etablissements Michelin Rubber composition based on highly saturated diene elastomer and dithiosulfate salt
FR3065005A1 (en) 2017-04-10 2018-10-12 Compagnie Generale Des Etablissements Michelin Tire tread for pneumatic tires based on a highly saturated diene elastomer
FR3065216A1 (en) 2017-04-18 2018-10-19 Compagnie Generale Des Etablissements Michelin Continuous synthesis of copolymer of ethylene and butadiene
FR3065215A1 (en) * 2017-04-18 2018-10-19 Compagnie Generale Des Etablissements Michelin Continuous synthesis of copolymer of ethylene and butadiene
FR3067355A1 (en) 2017-06-08 2018-12-14 Compagnie Generale Des Etablissements Michelin Rubber composition
FR3067354B1 (en) 2017-06-08 2020-10-23 Centre Nat Rech Scient FUNCTIONAL COPOLYMER OF ETHYLENE AND 1,3-BUTADIENE
FR3067353B1 (en) 2017-06-08 2020-10-23 Centre Nat Rech Scient FUNCTIONAL COPOLYMER OF 1,3-DIENE AND OLEFIN
WO2019077234A1 (en) 2017-10-19 2019-04-25 Compagnie Generale Des Etablissements Michelin Diene and ethylenic block polymers with saturated, hydrocarbon cyclic units
CN111212860A (en) 2017-10-19 2020-05-29 米其林集团总公司 Block polymers having diene units and monoolefin units
WO2019077232A1 (en) 2017-10-19 2019-04-25 Compagnie Generale Des Etablissements Michelin Method for synthesising polymer blocks
US20200239616A1 (en) 2017-10-19 2020-07-30 Compagnie Generale Des Etablissements Michelin Block polymers
WO2019077236A1 (en) 2017-10-19 2019-04-25 Compagnie Generale Des Etablissements Michelin Block polymers
EP3720700A1 (en) 2017-12-06 2020-10-14 Compagnie Générale des Etablissements Michelin Elastomeric laminate
CN111448062A (en) 2017-12-06 2020-07-24 米其林集团总公司 Elastomeric laminate
FR3085166B1 (en) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Tire provided with a composition comprising an ethylene-rich elastomer, a peroxide and a specific acrylate derivative
FR3085167B1 (en) 2018-08-23 2020-07-31 Michelin & Cie Pneumatics provided with a composition consisting of an elastomer rich in ethylene, a peroxide and a specific acrylate derivative
FR3085165B1 (en) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Tire provided with a composition comprising an ethylene-rich elastomer, a peroxide and a specific acrylate derivative
FR3085684A1 (en) 2018-09-11 2020-03-13 Compagnie Generale Des Etablissements Michelin RUBBER COMPOSITION
FR3085683B1 (en) 2018-09-11 2020-10-23 Michelin & Cie PNEUMATIC
FR3086948B1 (en) 2018-10-09 2020-12-04 Michelin & Cie RUBBER COMPOSITION
FR3086949B1 (en) 2018-10-09 2020-12-04 Michelin & Cie RUBBER COMPOSITION
FR3087443B3 (en) 2018-10-23 2020-10-23 Michelin & Cie RUBBER COMPOSITION
FR3088328B3 (en) 2018-11-09 2020-12-04 Michelin & Cie FUNCTIONAL DIENIC ELASTOMER AND RUBBER COMPOSITION
FR3090639A3 (en) 2018-12-20 2020-06-26 Michelin & Cie Terpolymers of ethylene, 1,3-butadiene and an aromatic α-monoolefin.
FR3090661A3 (en) 2018-12-21 2020-06-26 Michelin & Cie Tire tread
FR3090663A3 (en) 2018-12-21 2020-06-26 Michelin & Cie Tire tread
FR3090656A3 (en) 2018-12-21 2020-06-26 Michelin & Cie Tire tread
FR3090659A3 (en) 2018-12-21 2020-06-26 Michelin & Cie Tire tread
FR3090654A3 (en) 2018-12-21 2020-06-26 Michelin & Cie Rubber composition

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4801666A (en) * 1985-03-25 1989-01-31 Northwestern University Olefin and cycloalkene polymerization with organolanthanide catalysts
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
US4716257A (en) 1985-03-25 1987-12-29 Northwestern University Organolanthanide catalysts
US5066739A (en) * 1990-07-30 1991-11-19 Phillips Petroleum Company Olefin polymerization with cyclopentadienyl lanthanidealkyl of hydride in presence of hydrogen
US5109085A (en) * 1990-08-27 1992-04-28 Phillips Petroleum Company Olefin polymerization process
FR2681870B1 (en) * 1991-10-01 1994-02-11 Ecp Enichem Polymeres France Sa Catalysts and process for the preparation of catalysts for use in the polymerization of ethylene.
JPH0641232A (en) * 1992-07-22 1994-02-15 Idemitsu Kosan Co Ltd Polymerization catalyst, production of polymer using same, and production of catalyst component
FR2696750B1 (en) * 1992-10-08 1995-01-27 Enichem Polymeres France Caralyzers and process for the preparation of catalysts suitable for the polymerization of ethylene.
JPH06256419A (en) * 1993-03-09 1994-09-13 Showa Denko Kk Production of ethylene polymer
US5428120A (en) * 1993-10-08 1995-06-27 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent
JPH07304829A (en) * 1994-05-09 1995-11-21 Mitsubishi Chem Corp Production of polymer
JPH08245711A (en) * 1995-03-10 1996-09-24 Showa Denko Kk New lanthanide complex and production of unsaturated carboxylic ester polymer and polyolefin using the same
KR100472591B1 (en) * 1996-07-05 2005-05-16 바이엘 악티엔게젤샤프트 Method for Producing High Melting-Point Polyolefins

Also Published As

Publication number Publication date
JP4806784B2 (en) 2011-11-02
US6569799B1 (en) 2003-05-27
US20030004287A1 (en) 2003-01-02
KR20010050962A (en) 2001-06-25
EP1092731B1 (en) 2011-12-14
CN1310188A (en) 2001-08-29
FR2799468B1 (en) 2006-04-28
CA2321362A1 (en) 2001-04-12
EP1829901A3 (en) 2007-10-10
BR0004778B1 (en) 2010-11-30
EP1829901A2 (en) 2007-09-05
KR100722171B1 (en) 2007-05-29
EP1092731A1 (en) 2001-04-18
JP2001294607A (en) 2001-10-23
FR2799468A1 (en) 2001-04-13
US6800705B2 (en) 2004-10-05
EP1829901B1 (en) 2016-04-13
CA2321362C (en) 2010-06-15
BR0004778A (en) 2001-05-29
CN1205238C (en) 2005-06-08

Similar Documents

Publication Publication Date Title
DE69938048D1 (en) Two-wire control and monitoring system, especially for irrigation of limited base areas
DE69929311D1 (en) Oximanderivates and method for the production thereof
AT334197T (en) Process for producing polymers
RU97101172A (en) Catalytic polymerization systems, their production and application
BR0003808B1 (en) absorbent article, and process for its manufacture.
ZA200303543B (en) Catalytic system and method for preparing elastomers using same.
RU96124062A (en) Procatalizer for the production of ethylene polymers, method for its production and application
AT308373T (en) Cross-secondity filtration membrane and method for the production thereof
AT483042T (en) Structured composite material, manufacturing method and device for production
ZA200205634B (en) Sourcing system and method.
HK1046681A1 (en) 6-alkenyl-, 6-alkinyl- and 6-epoxy-epothilone derivatives, process for their production, and their use
HK1054710A1 (en) Method for producing dmc catalysts.
SG88774A1 (en) Ethylene/alpha-olefin copolymer, method for producing the same, and use thereof
AT201334T (en) Shell catalysts, method for their production and their use
HK1044338A1 (en) 5-Pyridyl-1, 3-azole compounds, process for producing the same and use thereof
ZA200200898B (en) High resistance steel band or sheet and method for the production thereof.
AT257722T (en) Catheter and method for the production thereof
ZA200006074B (en) Composite sheet and production method thereof.
AT517130T (en) Method for producing lighter polymers for processing
AT183526T (en) Liquid-absorbing polymers, method for the production and their use
AT326195T (en) Stent attachment system and method for the production thereof
DE69824148D1 (en) Process, catalyst and device for the production of acetaldehyde from acetic acid
AU4544500A (en) Method for producing platinum metal catalysts
AT347321T (en) Pressure butterclip, device and method
AU2856499A (en) Novel substances kf-1040t4a, kf-1040t4b, kf-1040t5a and kf-1040t5b and process for producing the same