AT537196T - Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated diene - Google Patents
Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated dieneInfo
- Publication number
- AT537196T AT537196T AT00121834T AT00121834T AT537196T AT 537196 T AT537196 T AT 537196T AT 00121834 T AT00121834 T AT 00121834T AT 00121834 T AT00121834 T AT 00121834T AT 537196 T AT537196 T AT 537196T
- Authority
- AT
- Austria
- Prior art keywords
- production
- copolymer
- catalyst
- ethylene
- conjugated diene
- Prior art date
Links
- 239000005977 Ethylene Substances 0.000 title 1
- 239000003054 catalysts Substances 0.000 title 1
- 229920001577 copolymers Polymers 0.000 title 1
- 150000001993 dienes Chemical class 0.000 title 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/083—Copolymers of ethene with aliphatic polyenes, i.e. containing more than one unsaturated bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9912798A FR2799468B1 (en) | 1999-10-12 | 1999-10-12 | Catalytic system for use in the copolymerization of ethylene and a conjugated diene, process for the preparation of this catalytic system, and copolymer of ethylene and conjugated diene |
Publications (1)
Publication Number | Publication Date |
---|---|
AT537196T true AT537196T (en) | 2011-12-15 |
Family
ID=9550906
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00121834T AT537196T (en) | 1999-10-12 | 2000-10-06 | Catalyst system, method for the production thereof and method for the production of a copolymer of ethylene-conjugated diene |
Country Status (9)
Country | Link |
---|---|
US (2) | US6569799B1 (en) |
EP (2) | EP1092731B1 (en) |
JP (1) | JP4806784B2 (en) |
KR (1) | KR100722171B1 (en) |
CN (1) | CN1205238C (en) |
AT (1) | AT537196T (en) |
BR (1) | BR0004778B1 (en) |
CA (1) | CA2321362C (en) |
FR (1) | FR2799468B1 (en) |
Families Citing this family (75)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100826080B1 (en) * | 2001-12-27 | 2008-04-29 | 삼성토탈 주식회사 | Copolymerization method of ethylene/diene having high melt strength |
CN101045770A (en) | 2002-10-16 | 2007-10-03 | 米其林技术公司 | Ethylene/butadiene copolymers, catalytic system of producing same and production of said polymers |
WO2004044018A2 (en) * | 2002-11-07 | 2004-05-27 | Dow Global Technologies, Inc. | Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby |
FR2858817B1 (en) * | 2003-08-13 | 2006-02-03 | Michelin Soc Tech | Catalytic system for obtaining conjugated (s) / mono-olefine (s) diene (s) copolymers and copolymers |
US7294649B2 (en) * | 2004-12-17 | 2007-11-13 | Roche Diagnostics Operatins, Inc. | Methamphetamine derivatives and conjugates for immunoassay |
WO2007016700A2 (en) * | 2005-08-04 | 2007-02-08 | The Regents Of The University Of Colorado, A Body Corporate | Catalysts for radical polymerization |
FR2893029B1 (en) | 2005-11-09 | 2009-01-16 | Michelin Soc Tech | Metalocene complex borohydride of lanthanide, incorporating catalytic system, polymerization method using the same, and ethylene / butadiene copolymer obtained by this process |
FR2893028B1 (en) * | 2005-11-09 | 2008-02-15 | Michelin Soc Tech | METALOCENE COMPLEX BOROHYDRIDE OF LANTHANIDE, INCORPORATING CATALYTIC SYSTEM, POLYMERIZATION METHOD USING THE SAME, AND ETHYLENE / BUTADIENE COPOLYMER OBTAINED BY THIS PROCESS |
FR2893030B1 (en) * | 2006-10-17 | 2011-04-15 | Michelin Soc Tech | COPOLYMER ETHYLENE / BUTADIENE |
US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
KR20120052385A (en) * | 2009-08-07 | 2012-05-23 | 가부시키가이샤 브리지스톤 | Method for producing copolymer |
FR2954332B1 (en) | 2009-12-22 | 2012-01-13 | Michelin Soc Tech | Particularly pneumatic article with external rubber mixture comprising a salt of lanthanide |
JP5823674B2 (en) * | 2010-07-30 | 2015-11-25 | 株式会社ブリヂストン | Copolymer of conjugated diene compound and non-conjugated olefin |
RU2542992C2 (en) * | 2010-07-30 | 2015-02-27 | Бриджстоун Корпорейшн | Method of regulating copolymer chain structure |
JP5557642B2 (en) * | 2010-07-30 | 2014-07-23 | 株式会社ブリヂストン | Copolymer of conjugated diene compound and non-conjugated olefin |
JP5917809B2 (en) * | 2010-11-30 | 2016-05-18 | 株式会社ブリヂストン | Copolymer, production method thereof, rubber composition, crosslinked rubber composition, and tire |
CN103476813A (en) * | 2011-02-04 | 2013-12-25 | 株式会社普利司通 | Copolymer, rubber composition, rubber composition for tire side use, crosslinked rubber composition, and tire |
JP5932224B2 (en) | 2011-02-04 | 2016-06-08 | 株式会社ブリヂストン | Copolymer, rubber composition, crosslinked rubber composition, and tire |
JP5731217B2 (en) * | 2011-02-04 | 2015-06-10 | 株式会社ブリヂストン | Copolymer, rubber composition, crosslinked rubber composition, and tire |
CN103459402B (en) | 2011-02-05 | 2016-09-07 | 株式会社普利司通 | Lanthanide complexes catalyst and use its polymerization |
JP5612511B2 (en) * | 2011-02-28 | 2014-10-22 | 株式会社ブリヂストン | Rubber composition, crosslinked rubber composition, and tire |
EP2900702B1 (en) | 2012-09-30 | 2018-05-02 | Bridgestone Corporation | Polymerization method employing an organometallic catalyst complex |
WO2014055868A1 (en) | 2012-10-04 | 2014-04-10 | Bridgestone Corporation | Organometallic complex catalyst and polymerization method employing same |
FR3001223B1 (en) * | 2013-01-22 | 2015-03-06 | Michelin & Cie | Rubber composition comprising a highly saturated dienic elastomer |
CN106536414B (en) | 2014-05-30 | 2018-12-04 | 株式会社普利司通 | Metal complex catalyst and the polymerization for using metal complex catalyst |
EP3738927A1 (en) | 2014-05-31 | 2020-11-18 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
FR3037588B1 (en) | 2015-06-19 | 2017-05-19 | Michelin & Cie | THERMOPLASTIC ELASTOMERIC COPOLYMER BASED ON DIENE ELASTOMER AND POLYPROPYLENE, COMPOSITIONS COMPRISING THE SAME, AND PROCESS FOR PREPARING THE SAME |
CN108137746A (en) * | 2015-10-16 | 2018-06-08 | 株式会社普利司通 | Multiple copolymer, rubber composition, crosslinked rubber composition, rubber and tire |
EP3363826A4 (en) * | 2015-10-16 | 2019-03-13 | Bridgestone Corporation | Multi-component copolymer, resin composition, cross-linked resin composition, and product |
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FR3044662B1 (en) | 2015-12-03 | 2017-12-08 | Michelin & Cie | Preformed catalytic system comprising rare earth metallocene |
FR3044664B1 (en) | 2015-12-08 | 2017-12-29 | Michelin & Cie | Monofunctional or telechelic copolymer of 1,3-diene and ethylene or alpha-monoolefin. |
FR3044663B1 (en) | 2015-12-08 | 2017-12-29 | Michelin & Cie | MONOFUNCTIONAL OR TELECHELIC COPOLYMER OF 1,3-BUTADIENE AND ETHYLENE |
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FR3045613B1 (en) | 2015-12-17 | 2017-12-15 | Michelin & Cie | COPOLYMER OF ETHYLENE AND BUTADIENE OF HOMOGENEOUS MICROSTRUCTURE |
FR3045633B1 (en) | 2015-12-22 | 2017-12-15 | Michelin & Cie | Pneumatic comprising a rubber composition comprising a substituted dienic elastomer |
WO2017170654A1 (en) | 2016-03-31 | 2017-10-05 | Compagnie Generale Des Etablissements Michelin | A tire having a tread comprising a rubber composition |
EP3436287B1 (en) | 2016-03-31 | 2019-12-25 | Compagnie Générale des Etablissements Michelin | A tire having a tread comprising a rubber composition |
FR3054222A1 (en) | 2016-07-25 | 2018-01-26 | Compagnie Generale Des Etablissements Michelin | Process for preparing a catalytic system based on rare earth metallocene |
FR3054221A1 (en) | 2016-07-25 | 2018-01-26 | Compagnie Generale Des Etablissements Michelin | Preformed catalytic system comprising rare earth metallocene |
FR3054220A1 (en) | 2016-07-25 | 2018-01-26 | Compagnie Generale Des Etablissements Michelin | Preformed catalytic system comprising rare earth metallocene |
FR3059254A1 (en) | 2016-11-30 | 2018-06-01 | Compagnie Generale Des Etablissements Michelin | Preformed catalytic system comprising rare earth metallocene |
FR3060004B1 (en) | 2016-12-09 | 2019-05-24 | Compagnie Generale Des Etablissements Michelin | ORGANOMETALLIC COMPOUND HAVING IMINOPHOSPHORANE FUNCTION |
FR3060007A1 (en) | 2016-12-09 | 2018-06-15 | Compagnie Generale Des Etablissements Michelin | TERPOLYMERS OF ETHYLENE, 1,3-BUTADIENE OR ISOPRENE, AND AROMATIC ALPHA-MONOOLEFIN |
US20200040166A1 (en) | 2017-03-08 | 2020-02-06 | Compagnie Generale Des Etablissements Michelin | Tire having a composition comprising an ethylyne-rich elastomer, a peroxide and a zinc acrylate |
FR3063732A1 (en) | 2017-03-08 | 2018-09-14 | Compagnie Generale Des Etablissements Michelin | Pneumatic having a composition comprising an ethylene-rich elastomer, a peroxide and a polyfunctional acrylate derivative |
FR3065004A1 (en) | 2017-04-10 | 2018-10-12 | Compagnie Generale Des Etablissements Michelin | Rubber composition based on highly saturated diene elastomer and dithiosulfate salt |
FR3065005A1 (en) | 2017-04-10 | 2018-10-12 | Compagnie Generale Des Etablissements Michelin | Tire tread for pneumatic tires based on a highly saturated diene elastomer |
FR3065216A1 (en) | 2017-04-18 | 2018-10-19 | Compagnie Generale Des Etablissements Michelin | Continuous synthesis of copolymer of ethylene and butadiene |
FR3065215A1 (en) * | 2017-04-18 | 2018-10-19 | Compagnie Generale Des Etablissements Michelin | Continuous synthesis of copolymer of ethylene and butadiene |
FR3067355A1 (en) | 2017-06-08 | 2018-12-14 | Compagnie Generale Des Etablissements Michelin | Rubber composition |
FR3067354B1 (en) | 2017-06-08 | 2020-10-23 | Centre Nat Rech Scient | FUNCTIONAL COPOLYMER OF ETHYLENE AND 1,3-BUTADIENE |
FR3067353B1 (en) | 2017-06-08 | 2020-10-23 | Centre Nat Rech Scient | FUNCTIONAL COPOLYMER OF 1,3-DIENE AND OLEFIN |
WO2019077234A1 (en) | 2017-10-19 | 2019-04-25 | Compagnie Generale Des Etablissements Michelin | Diene and ethylenic block polymers with saturated, hydrocarbon cyclic units |
CN111212860A (en) | 2017-10-19 | 2020-05-29 | 米其林集团总公司 | Block polymers having diene units and monoolefin units |
WO2019077232A1 (en) | 2017-10-19 | 2019-04-25 | Compagnie Generale Des Etablissements Michelin | Method for synthesising polymer blocks |
US20200239616A1 (en) | 2017-10-19 | 2020-07-30 | Compagnie Generale Des Etablissements Michelin | Block polymers |
WO2019077236A1 (en) | 2017-10-19 | 2019-04-25 | Compagnie Generale Des Etablissements Michelin | Block polymers |
EP3720700A1 (en) | 2017-12-06 | 2020-10-14 | Compagnie Générale des Etablissements Michelin | Elastomeric laminate |
CN111448062A (en) | 2017-12-06 | 2020-07-24 | 米其林集团总公司 | Elastomeric laminate |
FR3085166B1 (en) | 2018-08-23 | 2020-07-17 | Compagnie Generale Des Etablissements Michelin | Tire provided with a composition comprising an ethylene-rich elastomer, a peroxide and a specific acrylate derivative |
FR3085167B1 (en) | 2018-08-23 | 2020-07-31 | Michelin & Cie | Pneumatics provided with a composition consisting of an elastomer rich in ethylene, a peroxide and a specific acrylate derivative |
FR3085165B1 (en) | 2018-08-23 | 2020-07-17 | Compagnie Generale Des Etablissements Michelin | Tire provided with a composition comprising an ethylene-rich elastomer, a peroxide and a specific acrylate derivative |
FR3085684A1 (en) | 2018-09-11 | 2020-03-13 | Compagnie Generale Des Etablissements Michelin | RUBBER COMPOSITION |
FR3085683B1 (en) | 2018-09-11 | 2020-10-23 | Michelin & Cie | PNEUMATIC |
FR3086948B1 (en) | 2018-10-09 | 2020-12-04 | Michelin & Cie | RUBBER COMPOSITION |
FR3086949B1 (en) | 2018-10-09 | 2020-12-04 | Michelin & Cie | RUBBER COMPOSITION |
FR3087443B3 (en) | 2018-10-23 | 2020-10-23 | Michelin & Cie | RUBBER COMPOSITION |
FR3088328B3 (en) | 2018-11-09 | 2020-12-04 | Michelin & Cie | FUNCTIONAL DIENIC ELASTOMER AND RUBBER COMPOSITION |
FR3090639A3 (en) | 2018-12-20 | 2020-06-26 | Michelin & Cie | Terpolymers of ethylene, 1,3-butadiene and an aromatic α-monoolefin. |
FR3090661A3 (en) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Tire tread |
FR3090663A3 (en) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Tire tread |
FR3090656A3 (en) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Tire tread |
FR3090659A3 (en) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Tire tread |
FR3090654A3 (en) | 2018-12-21 | 2020-06-26 | Michelin & Cie | Rubber composition |
Family Cites Families (13)
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US4801666A (en) * | 1985-03-25 | 1989-01-31 | Northwestern University | Olefin and cycloalkene polymerization with organolanthanide catalysts |
US4668773A (en) * | 1985-03-25 | 1987-05-26 | Northwestern University | Organolanthanide catalysts |
US4716257A (en) | 1985-03-25 | 1987-12-29 | Northwestern University | Organolanthanide catalysts |
US5066739A (en) * | 1990-07-30 | 1991-11-19 | Phillips Petroleum Company | Olefin polymerization with cyclopentadienyl lanthanidealkyl of hydride in presence of hydrogen |
US5109085A (en) * | 1990-08-27 | 1992-04-28 | Phillips Petroleum Company | Olefin polymerization process |
FR2681870B1 (en) * | 1991-10-01 | 1994-02-11 | Ecp Enichem Polymeres France Sa | Catalysts and process for the preparation of catalysts for use in the polymerization of ethylene. |
JPH0641232A (en) * | 1992-07-22 | 1994-02-15 | Idemitsu Kosan Co Ltd | Polymerization catalyst, production of polymer using same, and production of catalyst component |
FR2696750B1 (en) * | 1992-10-08 | 1995-01-27 | Enichem Polymeres France | Caralyzers and process for the preparation of catalysts suitable for the polymerization of ethylene. |
JPH06256419A (en) * | 1993-03-09 | 1994-09-13 | Showa Denko Kk | Production of ethylene polymer |
US5428120A (en) * | 1993-10-08 | 1995-06-27 | The Dow Chemical Company | Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent |
JPH07304829A (en) * | 1994-05-09 | 1995-11-21 | Mitsubishi Chem Corp | Production of polymer |
JPH08245711A (en) * | 1995-03-10 | 1996-09-24 | Showa Denko Kk | New lanthanide complex and production of unsaturated carboxylic ester polymer and polyolefin using the same |
KR100472591B1 (en) * | 1996-07-05 | 2005-05-16 | 바이엘 악티엔게젤샤프트 | Method for Producing High Melting-Point Polyolefins |
-
1999
- 1999-10-12 FR FR9912798A patent/FR2799468B1/en not_active Expired - Lifetime
-
2000
- 2000-10-06 EP EP20000121834 patent/EP1092731B1/en not_active Expired - Fee Related
- 2000-10-06 EP EP07010599.4A patent/EP1829901B1/en not_active Expired - Fee Related
- 2000-10-06 AT AT00121834T patent/AT537196T/en unknown
- 2000-10-10 CA CA 2321362 patent/CA2321362C/en not_active Expired - Fee Related
- 2000-10-11 KR KR1020000059816A patent/KR100722171B1/en not_active IP Right Cessation
- 2000-10-11 BR BR0004778A patent/BR0004778B1/en not_active IP Right Cessation
- 2000-10-12 JP JP2000350288A patent/JP4806784B2/en not_active Expired - Fee Related
- 2000-10-12 US US09/689,464 patent/US6569799B1/en not_active Expired - Lifetime
- 2000-10-12 CN CN 00134404 patent/CN1205238C/en not_active IP Right Cessation
-
2002
- 2002-05-23 US US10/154,631 patent/US6800705B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP4806784B2 (en) | 2011-11-02 |
US6569799B1 (en) | 2003-05-27 |
US20030004287A1 (en) | 2003-01-02 |
KR20010050962A (en) | 2001-06-25 |
EP1092731B1 (en) | 2011-12-14 |
CN1310188A (en) | 2001-08-29 |
FR2799468B1 (en) | 2006-04-28 |
CA2321362A1 (en) | 2001-04-12 |
EP1829901A3 (en) | 2007-10-10 |
BR0004778B1 (en) | 2010-11-30 |
EP1829901A2 (en) | 2007-09-05 |
KR100722171B1 (en) | 2007-05-29 |
EP1092731A1 (en) | 2001-04-18 |
JP2001294607A (en) | 2001-10-23 |
FR2799468A1 (en) | 2001-04-13 |
US6800705B2 (en) | 2004-10-05 |
EP1829901B1 (en) | 2016-04-13 |
CA2321362C (en) | 2010-06-15 |
BR0004778A (en) | 2001-05-29 |
CN1205238C (en) | 2005-06-08 |
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