AT148598B - Sintered hard metal alloy for implements and tools. - Google Patents
Sintered hard metal alloy for implements and tools.Info
- Publication number
- AT148598B AT148598B AT148598DA AT148598B AT 148598 B AT148598 B AT 148598B AT 148598D A AT148598D A AT 148598DA AT 148598 B AT148598 B AT 148598B
- Authority
- AT
- Austria
- Prior art keywords
- carbide
- hard metal
- tools
- implements
- metal alloy
- Prior art date
Links
- 229910001092 metal group alloy Inorganic materials 0.000 title description 7
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 claims description 6
- 229910003468 tantalcarbide Inorganic materials 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 5
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 239000010955 niobium Substances 0.000 claims description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 3
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000003825 pressing Methods 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 1
- 229910039444 MoC Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- -1 tantalum carbides Chemical class 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
- Carbon And Carbon Compounds (AREA)
Description
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Gesinterte Hartmetallegierung für Arbeitsgeräte und Werkzeuge.
Zur Herstellung von Arbeitsgeräten und Werkzeugen werden vielfach gesinterte Hartmetall- legierungen benutzt, die aus einem Karbid schwer schmelzbarer Metalle und einem zusätzlichen Hilfs- metall von wesentlich niedrigerem Schmelzpunkt, wie Eisen, Kobald oder Nickel, bestehen. Als höher schmelzender Anteil der Legierung wurde bisher in Praxis vornehmlich Wolframkarbid benutzt, da die unter Benutzung von Wolframkarbid hergestellten Hartmetallegierungen die günstigsten Eigen- schaften hinsichtlich Härte, Festigkeit und Zähigkeit aufweisen und den unter Benutzung anderer
Karbide schwer schmelzbarer Metalle, wie beispielsweise Molybdänkarbid, Titankarbid und Siliziumkarbid, hergestellten Hartmetallegierungen weit überlegen sind.
Erfindungsgemäss wurde festgestellt, dass bei derartigen aus einem Karbid schwer schmelzbarer Metalle und einem leichter schmelzenden Hilfsmetalle bestehenden Hartmetallegierungen die Anforderungen an grosse Härte und ausreichende Festigkeit und Zähigkeit auch erfüllt werden, wenn der mindestens 75% betragende höher schmelzende Anteil der Legierung aus einem gesinterten Gemisch von Vanadinkarbid und Niob-oder Tantalkarbid besteht. Gegebenenfalls können dem Vanadinkarbid auch gleichzeitig Niobkarbid und Tantalkarbid zugemischt werden.
Wie sich durch eingehende Versuche ergeben hat, wird bei einer derart zusammengesetzten Hartmetallegierung die grosse Härte durch das vorhandene Niob-oder Tantalkarbid, die grosse Zähigkeit dagegen durch das ebenfalls vorhandene Vanadinkarbid hervorgerufen, wobei durch die Gegenwart des letzteren gleichzeitig die durch das Vorhandensein des Niob-oder Tantalkarbides auch hervorgerufene Sprödigkeit weitgehend beseitigt wird.
Als besonders zweckmässig hat sich eine bei etwa 2000 C gesinterte Legierung erwiesen, die unter Zusatz von 2'5-5% Eisen oder Kobalt zu gleichen Teilen aus Vanadinkarbid und Niobkarbid besteht. Je nachdem eine grössere Zähigkeit oder Härte des Fertigerzeugnisses erwünscht ist, kann im Karbidgemisch entweder der Anteil des Vanadinkarbides oder aber auch der Anteil des Niobkarbides bzw. Tantalkarbides überwiegen. Die Menge des beigegebenen leichter schmelzenden Zusatzmetalls kann gegebenenfalls, wie an sich bekannt, bis auf 25% der Gesamtmenge der Legierung gesteigert werden.
Die Herstellung der Legierung erfolgt durch Sintern, u. zw. kann das Sintern anschliessend an das Pressen des als Ausgangsmaterial verwendeten Pulvergemisches oder auch gleichzeitig mit dem Pressen durchgeführt werden. Diese Herstellungsart hat vor dem Schmelzherstellungsverfahren, bei dem das Ausgangsgemisch bis zur vollständigen Erreichung des Schmelzpunktes erhitzt wird, die Vorteile im Gefolge, dass wesentlich niedriger liegende Temperaturen erforderlich sind und auch auf ein wesentlich feineres Gefüge hingearbeitet werden kann. Erschmolzene Legierungen besitzen nämlich durchweg ein büschelförmiges grobkörniges Gefüge. Auch hinsichtlich der Zähigkeit ergeben die auf dem Sinterwege hergestellten Legierungen weitaus bessere Resultate.
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
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Sintered hard metal alloy for implements and tools.
Sintered hard metal alloys, which consist of a carbide of difficult-to-melt metals and an additional auxiliary metal with a significantly lower melting point, such as iron, cobalt or nickel, are often used to manufacture tools and equipment. In practice, tungsten carbide has primarily been used as the higher-melting portion of the alloy, since the hard metal alloys produced using tungsten carbide have the most favorable properties in terms of hardness, strength and toughness and those using others
Carbides of difficult-to-melt metals, such as molybdenum carbide, titanium carbide and silicon carbide, are far superior to manufactured hard metal alloys.
According to the invention, it was found that in the case of such hard metal alloys consisting of a carbide that is difficult to melt and a more easily melting auxiliary metal, the requirements for high hardness and sufficient strength and toughness are also met if the higher-melting portion of the alloy, which is at least 75%, consists of a sintered mixture of Vanadium carbide and niobium or tantalum carbide consists. If necessary, niobium carbide and tantalum carbide can also be mixed into the vanadium carbide at the same time.
As has been shown by detailed tests, in such a composite hard metal alloy, the great hardness is caused by the niobium or tantalum carbide present, while the great toughness is caused by the vanadium carbide, which is also present, with the presence of the latter at the same time as the niobium carbide. or tantalum carbides also caused brittleness is largely eliminated.
An alloy sintered at about 2000 ° C. which, with the addition of 2.5-5% iron or cobalt, consists of equal parts of vanadium carbide and niobium carbide, has proven to be particularly useful. Depending on whether a greater toughness or hardness of the finished product is desired, either the proportion of vanadium carbide or the proportion of niobium carbide or tantalum carbide can predominate in the carbide mixture. The amount of the added, more easily melting additional metal can optionally, as is known per se, be increased up to 25% of the total amount of the alloy.
The alloy is produced by sintering, u. zw. The sintering can be carried out after the pressing of the powder mixture used as the starting material or at the same time as the pressing. This type of production, before the melt production process, in which the starting mixture is heated until the melting point is completely reached, has the advantages that much lower temperatures are required and a much finer structure can also be worked towards. Melted alloys consistently have a tufted, coarse-grained structure. The alloys produced by sintering also give far better results in terms of toughness.
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE721024X | 1930-08-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
AT148598B true AT148598B (en) | 1937-02-10 |
Family
ID=6629016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT148598D AT148598B (en) | 1930-08-14 | 1931-08-04 | Sintered hard metal alloy for implements and tools. |
Country Status (4)
Country | Link |
---|---|
US (1) | US1991912A (en) |
AT (1) | AT148598B (en) |
CH (1) | CH156814A (en) |
FR (1) | FR721024A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2116584A (en) * | 1982-03-11 | 1983-09-28 | Metallurg Inc | Sintered hardmetals |
-
1931
- 1931-08-03 CH CH156814D patent/CH156814A/en unknown
- 1931-08-04 US US555072A patent/US1991912A/en not_active Expired - Lifetime
- 1931-08-04 AT AT148598D patent/AT148598B/en active
- 1931-08-04 FR FR721024D patent/FR721024A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR721024A (en) | 1932-02-26 |
US1991912A (en) | 1935-02-19 |
CH156814A (en) | 1932-08-31 |
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