AT137770T - Metallocene catalyst having a Lewis acid and alkylaluminum - Google Patents

Metallocene catalyst having a Lewis acid and alkylaluminum

Info

Publication number
AT137770T
AT137770T AT90870176T AT90870176T AT137770T AT 137770 T AT137770 T AT 137770T AT 90870176 T AT90870176 T AT 90870176T AT 90870176 T AT90870176 T AT 90870176T AT 137770 T AT137770 T AT 137770T
Authority
AT
Austria
Prior art keywords
alkylaluminum
lewis acid
metallocene catalyst
metallocene
catalyst
Prior art date
Application number
AT90870176T
Other languages
German (de)
Inventor
John A Ewen
Michael J Elder
Original Assignee
Fina Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US41905789A priority Critical
Application filed by Fina Technology filed Critical Fina Technology
Publication of AT137770T publication Critical patent/AT137770T/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
AT90870176T 1989-10-10 1990-10-09 Metallocene catalyst having a Lewis acid and alkylaluminum AT137770T (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US41905789A true 1989-10-10 1989-10-10

Publications (1)

Publication Number Publication Date
AT137770T true AT137770T (en) 1996-05-15

Family

ID=23660629

Family Applications (1)

Application Number Title Priority Date Filing Date
AT90870176T AT137770T (en) 1989-10-10 1990-10-09 Metallocene catalyst having a Lewis acid and alkylaluminum

Country Status (9)

Country Link
US (2) US5561092A (en)
EP (1) EP0427697B1 (en)
JP (1) JP3088012B2 (en)
KR (1) KR100196614B1 (en)
CN (2) CN1033859C (en)
AT (1) AT137770T (en)
CA (1) CA2027145C (en)
DE (2) DE69026907T2 (en)
ES (1) ES2087145T3 (en)

Families Citing this family (249)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
DE69130320D1 (en) * 1990-07-24 1998-11-12 Mitsui Chemicals Inc Catalyst for alpha-olefin polymerization and preparation of poly (alpha) olefins thus
JP3117231B2 (en) * 1991-03-11 2000-12-11 三井化学株式会社 Method for producing a syndiotactic poly -α- olefins having a broad molecular weight distribution
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
TW300901B (en) 1991-08-26 1997-03-21 Hoechst Ag
NL9101502A (en) * 1991-09-06 1993-04-01 Dsm Nv A process for the preparation of a bridged metallocene compound as well as a catalyst component and a process for the polymerization of olefins.
TW309523B (en) * 1991-11-30 1997-07-01 Hoechst Ag
TW304963B (en) * 1992-01-27 1997-05-11 Hoechst Ag
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
EP0572034A3 (en) * 1992-05-29 1994-01-26 Idemitsu Kosan Co
JP3153000B2 (en) * 1992-06-11 2001-04-03 三菱化学株式会社 Preparation of α- olefin polymer
JPH061803A (en) * 1992-06-18 1994-01-11 Mitsubishi Petrochem Co Ltd Process for polymerizing olefin
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
WO1994001471A1 (en) * 1992-07-01 1994-01-20 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
NL9201970A (en) * 1992-11-11 1994-06-01 Dsm Nv Indenyl compounds and catalyst components for the polymerization of olefins.
DE69310101T2 (en) * 1992-11-18 1997-09-25 Mitsui Petrochemical Ind the same olefin polymerization catalyst and process for olefin polymerization using
BE1006438A3 (en) * 1992-12-17 1994-08-30 Solvay Catalyst system, use of this system catalyst for the (co) polymerization of olefins, method of preparation of this system and method for catalyst (co) polymerization of olefins.
GB9226905D0 (en) * 1992-12-24 1993-02-17 Wellcome Found Pharmaceutical preparation
BE1006880A3 (en) * 1993-03-01 1995-01-17 Solvay Precurseur solid system of a catalyst for olefin polymerization, method of preparation, catalytic system including the solid precursor and method for polymerization of olefins in the presence of this system catalyst.
US5858904A (en) * 1993-03-31 1999-01-12 Idemitsu Kosan Co., Ltd. Catalyst for production of vinyl-based polymer and process for production of vinyl-based aromatic polymer
EP0812854B2 (en) * 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
DE69431222T2 (en) * 1993-06-07 2003-04-17 Mitsui Chemicals Inc Transition metal compound, and those containing polymerization catalyst
ES2156153T3 (en) * 1993-06-15 2001-06-16 Idemitsu Kosan Co Method of producing olefin polymer and catalyst for polymerization of an olefin.
JPH0733812A (en) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd Catalyst for styrene polymerization and production of styrene polymer thereby
US5455214A (en) * 1993-09-09 1995-10-03 Mobil Oil Corporation Metallocenes supported on ion exchange resins
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
FI945959A (en) * 1993-12-21 1995-06-22 Hoechst Ag Metallocenes and their use as catalysts
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
KR100353463B1 (en) * 1994-04-11 2003-01-24 미쓰이 가가쿠 가부시키가이샤 Process for producing a propylene polymer composition and a propylene polymer composition
EP0704462B1 (en) * 1994-04-11 1998-12-23 Mitsui Chemicals, Inc. Process for producing propylene polymer composition, and propylene polymer composition
DE4420456A1 (en) * 1994-06-13 1995-12-14 Hoechst Ag Neutral zwitterionic transition metal cpds.
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
EP0775164B1 (en) * 1994-08-03 2001-11-07 ExxonMobil Chemical Patents Inc. Supported ionic catalyst composition
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
DE4431838A1 (en) * 1994-09-07 1996-03-14 Basf Ag Supported metallocene catalyst systems
TW369547B (en) 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
DE4434640C1 (en) 1994-09-28 1996-02-01 Hoechst Ag Bridged metallocene prodn. in-situ
DE4436113A1 (en) 1994-10-10 1996-04-11 Hoechst Ag metallocene
US5500398A (en) * 1994-11-09 1996-03-19 Northwestern University Homogeneous α-olefin dimerization catalysts
DE69533310D1 (en) * 1994-12-20 2004-09-02 Mitsui Chemicals Inc A process for the preparation of ethylene polymer and ethylene polymer
US5888636A (en) * 1995-01-19 1999-03-30 Mitsui Chemicals, Inc. Multi-layer blow molded article of polypropylene
CN1076282C (en) 1995-03-02 2001-12-19 三井化学株式会社 Polypropylene composite film
ES2124054T3 (en) * 1995-06-12 1999-01-16 Targor Gmbh Transition metal compound.
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
WO1997014725A1 (en) * 1995-10-18 1997-04-24 Chisso Corporation Olefin (co)polymer composition, process for producing the same, catalyst for (co)polymerizing olefin, and process for producing the same
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
DE19546501A1 (en) 1995-12-13 1997-06-19 Hoechst Ag metallocene
DE19546500A1 (en) 1995-12-13 1997-06-19 Hoechst Ag Production of cyclo-olefin copolymers e.g. for pipes
AR005066A1 (en) 1995-12-15 1999-04-07 Union Carbide Chem Plastic A process for making a homopolymer, copolymer or terpolymer of polyethylene with long chain branching, a composition of polietilenoasi obtained and an article by injection molding or film comprising said composition.
DE69720823T2 (en) * 1996-01-25 2004-01-22 Tosoh Corp., Shinnanyo A process for olefin polymerization using a transition metal catalyst.
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
IT1282666B1 (en) 1996-02-22 1998-03-31 Enichem Spa substituted metallocene catalyst for the (co) polymerization of olefins
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
DE69704614T2 (en) 1996-06-17 2001-11-08 Exxonmobil Chem Patents Inc Olefinpolymerisationkatalysatorsysteme of mixed transition metalen
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6207608B1 (en) 1996-08-09 2001-03-27 University Of Iowa Research Foundation Olefin polymerization with direct use of ansa-metallocene amide complexes as catalysts
US6130302A (en) 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
US5854166A (en) * 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
JPH10101727A (en) * 1996-09-24 1998-04-21 Shell Internatl Res Maatschappij Bv Catalyst for hydrogenating olefin or polymer and method therefor
DE69735068T2 (en) 1996-11-15 2006-08-24 Basell Polyolefine Gmbh Heterocyclic Metallocne and polymerization catalysts
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
EP0972800A4 (en) 1997-04-02 2004-06-16 Chisso Corp Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
JP3817015B2 (en) * 1997-04-14 2006-08-30 チコナ ゲーエムベーハー Cyclic olefin copolymer and use thereof
TWI246520B (en) 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
DE19732804A1 (en) 1997-07-30 1999-02-04 Bayer Ag Catalysts based on fulvene metal complexes
DE19733017A1 (en) 1997-07-31 1999-02-04 Hoechst Ag Chemical compound
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
US7026404B2 (en) 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
AT485319T (en) 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc A process for the polymerization of propylene and ethylene in solution
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
FR2769245B1 (en) 1997-10-02 1999-10-29 Atochem Elf Sa activator solid support for metallocene catalysts in polymerization of olefins, process for its preparation, catalyst system and method of polymerization corresponding
DE19744102A1 (en) 1997-10-06 1999-04-15 Targor Gmbh Metallocene catalyst system useful in (co)polyolefin production
DE19808253A1 (en) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Catalyst system, a process for its preparation and its use for the polymerization of olefins
DE19808254A1 (en) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Chemical compound
TW562810B (en) 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
EP1522553B1 (en) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
GB9816940D0 (en) 1998-08-05 1998-09-30 Bp Chem Int Ltd Polymerisation catalysts
WO2000018808A1 (en) 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6147173A (en) * 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
TW576843B (en) 1998-12-25 2004-02-21 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
BR0009363A (en) 1999-03-29 2001-12-26 Basf Ag Process for the polymerization of olefins, sistemacatalisador, and olefin polymer
JP2000351813A (en) 1999-04-09 2000-12-19 Mitsui Chemicals Inc ETHYLENE/α-OLEFIN COPOLYMER, ITS PRODUCTION, AND ITS USE
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US6787617B1 (en) 1999-05-10 2004-09-07 Japan As Represented By Director General Of The Agency Of Industrial Science And Technology Process for producing olefin living polymer
JP3808243B2 (en) 1999-07-27 2006-08-09 三井化学株式会社 Soft resin composition
DE19935592A1 (en) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromium compounds in catalyst systems for olefin polymerization
IT1313599B1 (en) * 1999-08-05 2002-09-09 Enichem Spa Metal complexes used in the catalysis for the (co) polymerization of alpha-olefins
PL200524B1 (en) 1999-08-13 2009-01-30 Basell Polyolefine Gmbh COPOLYMERS OF ETHYLENE WITH C₃ -C₉ $g(a) OLEFINS and uses as well as application of monoindenyl- or monofluorenyl complexes of chromium
US6475947B1 (en) 1999-09-10 2002-11-05 Phillips Petroleum Company Oligomeric metallocenes and their use
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
US6667274B1 (en) 1999-12-30 2003-12-23 Phillips Petroleum Company Polymerization catalysts
CN100436492C (en) 2000-01-26 2008-11-26 三井化学株式会社 Olefin polymer
US20040072975A1 (en) 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
EP1209179B1 (en) 2000-03-31 2005-11-02 Mitsui Chemicals, Inc. Processes for producing polyolefin composition
US6635733B2 (en) 2000-05-23 2003-10-21 Chisso Corporation Elastomeric polypropylene
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
JP2002020417A (en) 2000-07-04 2002-01-23 Mitsui Chemicals Inc Method for polymerizing olefin
KR100443766B1 (en) 2000-07-04 2004-08-09 미쓰이 가가쿠 가부시키가이샤 Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
EP1241194B1 (en) 2000-07-26 2013-09-04 Mitsui Chemicals, Inc. Polymer and process for producing the same
NO20013880L (en) 2000-08-22 2002-02-25 Rohm & Haas Matrix and method for the preparation of polyolefins
DE60141777D1 (en) 2000-09-07 2010-05-20 Mitsui Chemicals Inc Polar group-containing olefin copolymer, process for its preparation, this copolymer containing thermoplastic resin composition and the use thereof
KR100844062B1 (en) 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 Catalyst for olefin polymerizaion and method for producing olefin polymers using the catalyst
US7220801B2 (en) 2001-06-22 2007-05-22 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear low density polyethylenes as impact modifiers
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
FR2830868B1 (en) * 2001-10-11 2004-12-03 Atofina Composition isotactic polypropylene obtained by metallocene catalysis base and isotactic polypropylene produced by Ziegler-Natta catalysis, graft
CN100434444C (en) 2001-10-19 2008-11-19 旭化成株式会社 Process for polymerization of olefins
CA2488983A1 (en) 2002-07-31 2004-02-19 Exxonmobil Chemical Patents Inc. Silane crosslinkable polyethylene
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
EP1550693B1 (en) 2002-08-27 2007-07-11 Mitsui Chemicals, Inc. Thermoplastic elastomer and molded object thereof
ES2306884T3 (en) 2002-09-05 2008-11-16 Exxonmobil Chemical Patents Inc. shrinkable film.
AT494321T (en) 2002-09-05 2011-01-15 Exxonmobil Chem Patents Inc Stretch film wrapping method
EP2511305B1 (en) 2002-09-27 2019-05-29 Mitsui Chemicals, Inc. Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same
US7524910B2 (en) 2002-10-15 2009-04-28 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
AU2003301539A1 (en) 2002-10-23 2004-05-13 Mitsui Chemicals, Inc. Magnesium-containing carrier components and application thereof to olefin polymerization
DE10251513A1 (en) 2002-11-04 2004-05-19 Basf Ag Compounds with 5-membered heterocycle linked by amino- or phosphino-methyl to a benzene ring with an ortho-hydroxy, alkoxy, thiol or amino group, used as multidentate ligands in olefin polymerization catalysts
WO2004072174A1 (en) 2003-02-14 2004-08-26 Mitsui Chemicals, Inc. Syndiotactic propylene polymer composition
KR101045559B1 (en) 2003-03-28 2011-07-01 미쓰이 가가쿠 가부시키가이샤 A transition metal compound and an olefin polymerization catalyst comprising the same
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
BR112015015408A2 (en) 2012-12-28 2017-07-11 Dow Global Technologies Llc coating composition, and coated article
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
US8349929B2 (en) 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US8357749B2 (en) 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US8158711B2 (en) 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US9938413B2 (en) 2012-12-28 2018-04-10 Dow Global Technologies Llc Coating composition and articles made therefrom
US7947776B2 (en) 2003-08-25 2011-05-24 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US7803865B2 (en) 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
KR20060118564A (en) 2003-12-23 2006-11-23 바젤 폴리올레핀 게엠베하 Catalyst system for olefin polymerization
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
EP1788002A4 (en) 2004-08-27 2009-08-19 Mitsui Chemicals Inc Catalysts for olefin polymerization, process for production of olefin polymers, olefin copolymers, novel transition metal compounds, and process for production of transition metal compounds
US20060057351A1 (en) * 2004-09-10 2006-03-16 Alain Yang Method for curing a binder on insulation fibers
EP1805229A1 (en) 2004-10-28 2007-07-11 Dow Gloval Technologies Inc. Method of controlling a polymerization reactor
US7795194B2 (en) 2004-11-26 2010-09-14 Mitsui Chemicals, Inc. Synthetic lubricating oil and lubricating oil composition
KR101064037B1 (en) 2005-05-18 2011-09-08 미쓰이 가가쿠 가부시키가이샤 Olefin polymerization catalyst, process for producing an olefin polymer, method for producing a propylene-based copolymer, propylene polymer, propylene-based polymer composition and the use thereof
US20070080483A1 (en) * 2005-10-07 2007-04-12 Mitsui Chemicals, Inc. Process for producing injection molded product
US20070225423A1 (en) * 2005-10-07 2007-09-27 Mitsui Chemicals, Inc. Process for producing blow molded product by blow molding
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
EP1963347B1 (en) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
EP1995037B1 (en) 2006-03-10 2011-07-06 Mitsui Chemicals, Inc. Process for production of moldings by the inflation method
US20090166911A1 (en) 2006-03-27 2009-07-02 Mitsui Chemicals, Inc. Process for Producing Molded Article by T-Die Molding
JP2007261201A (en) 2006-03-29 2007-10-11 Mitsui Chemicals Inc Manufacturing method of molded object by blow molding
WO2007114009A1 (en) 2006-03-30 2007-10-11 Mitsui Chemicals, Inc. Process for producing molded object by injection molding
WO2007130277A1 (en) 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
WO2008016059A1 (en) 2006-07-31 2008-02-07 Mitsui Chemicals, Inc. Film or laminate comprising ethylene resin or ethylene resin composition
EP2065439B1 (en) 2006-09-20 2012-03-28 Mitsui Chemicals, Inc. Polyolefin composition
JPWO2008047878A1 (en) 2006-10-20 2010-02-25 三井化学株式会社 Copolymer, lubricating oil viscosity modifiers and lubricating oil compositions
JP5438256B2 (en) 2006-11-17 2014-03-12 三井化学株式会社 Polypropylene resin film and use thereof
DE102006057822A1 (en) 2006-12-06 2008-06-26 Basell Poliolefine Italia S.R.L. Solvent-free multilayer laminated material for production of, e.g. floor coverings, includes thermoplastic polymers, flexible material, fibrous intermediate layer comprising plastic and adhesive material, and metal, plastic, or wood
US7713636B2 (en) * 2006-12-15 2010-05-11 Exxonmobil Chemical Patents Inc. Multi-layer films comprising propylene-based polymers
DE102006060459A1 (en) * 2006-12-19 2008-06-26 Basell Poliolefine Italia S.R.L. Multilayer laminated material for Electrical and electronic component, has glass layer, lower substrate layer of plastic, metal or plastic and metal, intermediate layer, plastic fibrous intermediate layer and glass top layer
WO2008075717A1 (en) 2006-12-19 2008-06-26 Mitsui Chemicals, Inc. Solid catalyst for olefin polymerization, olefin polymerization method, and olefin polymer particle produced by the method
BRPI0806778B1 (en) 2007-01-16 2019-03-26 Prime Polymer Co., Ltd ethylene resin composition blow molded, blow molded article and fuel tank
WO2008152933A1 (en) 2007-06-14 2008-12-18 Mitsui Chemicals, Inc. Thermoplastic elastomer composition
JP5226973B2 (en) 2007-06-15 2013-07-03 三井化学株式会社 Ethylene copolymer, compositions and use thereof containing the copolymer
EP2174928B1 (en) 2007-07-04 2015-03-11 Mitsui Chemicals, Inc. Transition metal complex compound, olefin oligomerization catalyst containing the compound, and method for producing olefin oligomer performed in the presence of the catalyst
US8354485B2 (en) * 2007-08-29 2013-01-15 Albemarle Corporation Aluminoxane catalyst activators derived from dialkylaluminum cation precursor agents, processes for making same, and use thereof in catalysts and polymerization of olefins
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
CA2706822C (en) 2007-11-19 2013-05-28 Mitsui Chemicals, Inc. Bridged metallocene compound, olefin polymerization catalyst containing the same, and ethylene polymer obtained with the catalyst
DE102007057606A1 (en) 2007-11-28 2009-06-04 Basell Polyolefine Gmbh Modular rotary drum for electrical and household appliances
US9469704B2 (en) 2008-01-31 2016-10-18 Exxonmobil Chemical Patents Inc. Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins
EP2103634A1 (en) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Production of propylene-based polymers
EP2275493B1 (en) 2008-03-27 2013-02-27 Mitsui Chemicals, Inc. Resin composition and use thereof
CN101981111A (en) 2008-03-31 2011-02-23 三井化学株式会社 Resin composition and meltable bag
EP2112173A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Catalyst compounds and use thereof
US9938400B2 (en) 2008-04-23 2018-04-10 Exxonmobil Chemical Patents Inc. Propylene copolymers in soft thermoplastic blends
WO2010021304A1 (en) 2008-08-19 2010-02-25 三井化学株式会社 Method for manufacturing olefin polymer using mixed catalyst
US8513368B2 (en) 2009-03-30 2013-08-20 Mitsui Chemicals, Inc. Copolymer of olefin and conjugated diene, and process for producing the same
KR101327598B1 (en) 2009-04-21 2013-11-12 가부시키가이샤 프라임 폴리머 Method for producing olefin polymer
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
WO2013115912A1 (en) 2012-02-03 2013-08-08 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
SG176951A1 (en) 2009-07-01 2012-02-28 Mitsui Chemicals Inc Organometallic compound and production method thereof
WO2011020582A1 (en) 2009-08-18 2011-02-24 Basell Polyolefine Gmbh Plastic fuel container for motor bikes or automotive hybrid cars
JP5780559B2 (en) 2009-08-18 2015-09-16 バーゼル・ポリオレフィン・ゲーエムベーハー Battery housing of a motor vehicle that is electrically driven
CN102686615B (en) 2009-12-21 2014-05-28 三井化学株式会社 Process for production of syndiotactic alpha-olefin polymer
WO2011079042A2 (en) 2009-12-24 2011-06-30 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
JP6075537B2 (en) 2010-01-22 2017-02-08 エクソンモービル・ケミカル・パテンツ・インク Ethylene copolymers, their preparation and use
JP5498588B2 (en) 2010-01-27 2014-05-21 エクソンモービル・ケミカル・パテンツ・インク Copolymer, the compositions and methods for their preparation
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
CN103025818B (en) 2010-07-28 2015-06-17 埃克森美孚化学专利公司 Viscosity modifiers comprising blends of ethylene-based copolymers
US20120028866A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
WO2012015576A1 (en) 2010-07-28 2012-02-02 Exxonmobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
CN103025819B (en) 2010-07-28 2015-07-22 埃克森美孚化学专利公司 Viscosity modifiers comprising blends of ethylene-based copolymers
EP2711380A4 (en) 2011-05-18 2014-11-05 Mitsui Chemicals Inc Propylene copolymer and propylene copolymer composition, molding and foam thereof, and processes for producing said molding and foam
CN104080792A (en) 2011-12-19 2014-10-01 沙特基础工业公司 Process for the preparation of metallocene complexes
JP6454548B2 (en) 2011-12-19 2019-01-16 サウディ ベーシック インダストリーズ コーポレイション Process for preparing metallocene complexes
KR101567269B1 (en) 2011-12-27 2015-11-06 미쓰이 가가쿠 가부시키가이샤 4-methyl-1-pentene (co)polymer composition, and film and hollow molded body, each of which is formed from 4-methyl-1-pentene (co)polymer composition
ES2643186T3 (en) 2011-12-28 2017-11-21 Mitsui Chemicals, Inc. Composition based on ethylene polymer and molded body obtained from the same
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
US9139794B2 (en) 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
US9315602B2 (en) 2012-03-21 2016-04-19 Mitsui Chemicals, Inc. Method for producing olefin polymer
EP2833415B1 (en) 2012-03-28 2018-05-02 Mitsui Chemicals, Inc. Solar cell sealing material and solar cell module
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
EP2897726B1 (en) 2012-09-24 2019-02-27 ExxonMobil Chemical Patents Inc. Production of vinyl terminated polyethylene
KR101640356B1 (en) 2012-09-25 2016-07-15 미쓰이 가가쿠 가부시키가이샤 Method for producing olefin polymer, and olefin polymer
EP2902400A4 (en) 2012-09-25 2016-06-08 Mitsui Chemicals Inc Transition metal compound, olefin polymerization catalyst, and method for producing olefin polymer
KR101394943B1 (en) 2012-11-19 2014-05-14 대림산업 주식회사 Copolymer of ethylene and alpha-olefin and method for producing the same
ITMI20122203A1 (en) 2012-12-20 2014-06-21 Versalis Spa Process for the preparation of (co) polymers of conjugated dienes in the presence of a catalytic system comprising a complex nitrogen oxo-cobalt
ITMI20122201A1 (en) 2012-12-20 2014-06-21 Versalis Spa Complex oxo-nitrogen cobalt, catalytic system comprising said complex and oxo-nitrogen process for the (co) polymerization of conjugated dienes
ITMI20122206A1 (en) 2012-12-20 2014-06-21 Versalis Spa Process for the preparation of (co) polymers of conjugated dienes in the presence of a catalytic system comprising a complex bis-imino-pyridine cobalt
ITMI20122199A1 (en) 2012-12-20 2014-06-21 Versalis Spa Process for the preparation of (co) polymers of conjugated dienes in the presence of a catalytic system comprising a complex of cobalt bis-imine
CN104822697A (en) 2012-12-21 2015-08-05 埃克森美孚化学专利公司 Bridged metallocene compounds, catalyst systems and processes for polymerization therewith
US20150376358A1 (en) 2013-02-20 2015-12-31 Prime Polymer Co., Ltd. Biaxially-stretched film and ethylene polymer composition
CN104994948B (en) 2013-02-27 2017-11-24 三井化学株式会社 Olefin polymerized and catalyst for producing an olefin polymer is carried out in the presence of the catalyst
KR101699658B1 (en) 2013-03-12 2017-01-24 미쓰이 가가쿠 가부시키가이샤 Method for producing olefin polymer and catalyst for olefin polymerization
WO2015056787A1 (en) 2013-10-18 2015-04-23 三井化学株式会社 Adhesive agent comprising ethylene-(α-olefin) copolymer
ITMI20131830A1 (en) 2013-11-05 2015-05-06 Versalis Spa Polybutadienes di-stereoregular block structure 1,4-cis / 1,2 syndiotactic by stereospecific polymerization
ITMI20131828A1 (en) 2013-11-05 2015-05-06 Versalis Spa Polybutadienes di-stereoregular block structure 1,4-cis / 1,2 syndiotactic by stereospecific polymerization
CA2936511C (en) 2014-02-13 2019-06-11 Mitsui Chemicals, Inc. Process for producing ethylene/.alpha.-olefin copolymer
TW201538540A (en) 2014-02-14 2015-10-16 Mitsui Chemicals Inc ETHYLENE/α-OLEFIN/NON-CONJUGATED POLYENE COPOLYMER, PRODUCTION METHOD THEREFOR, AND USE THEREFOR
WO2015129414A1 (en) 2014-02-28 2015-09-03 三井化学株式会社 Cross-linked product and production method and use therefor, and ethylene copolymer
MX2016012449A (en) 2014-03-28 2017-01-06 Mitsui Chemicals Inc Olefin resin and method for producing same.
CN106068291B (en) 2014-03-28 2019-03-12 三井化学株式会社 Olefin-based resin, its manufacturing method and propylene resin composition
EP3124505A4 (en) 2014-03-28 2017-12-06 Mitsui Chemicals, Inc. Ethylene/alpha-olefin copolymer and lubricating oil
WO2016039295A1 (en) 2014-09-10 2016-03-17 三井化学株式会社 Lubricant composition
KR101889669B1 (en) 2014-09-11 2018-08-17 미쓰이 가가쿠 가부시키가이샤 Method for producing olefin (co)polymer containing constituent unit derived from 1-butene
KR20170057277A (en) 2014-09-17 2017-05-24 베르살리스 에스.피.에이. Pyridine complex of zirconium, catalytic system comprising said pyridine complex of zirconium and process of (co)polymerization of conjugated dienes
KR101720920B1 (en) 2014-12-09 2017-03-28 미쯔이가가꾸가부시끼가이샤 Propylene-based resin composition
JP6426829B2 (en) 2015-03-20 2018-11-21 三井化学株式会社 Thermoplastic elastomer composition and method for producing the same
EP3375849A4 (en) 2015-11-09 2019-06-26 Mitsui Chemicals, Inc. Viscosity modifier for lubricating oils, additive composition for lubricating oils, and lubricating oil compositions
KR20170090977A (en) * 2016-01-29 2017-08-08 삼성전자주식회사 Polarizing film and optical film and display device
KR20180113205A (en) 2016-03-04 2018-10-15 미쓰이 가가쿠 가부시키가이샤 Laminate and its use
US20180016204A1 (en) 2016-07-12 2018-01-18 Chevron Phillips Chemical Company Lp Decene Oligomers

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US3756998A (en) * 1968-10-14 1973-09-04 Union Carbide Corp L catalysts polymerization of olefins using supported pi arenechromium tricarbony
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5162278A (en) * 1988-07-15 1992-11-10 Fina Technology, Inc. Non-bridged syndiospecific metallocene catalysts and polymerization process
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins

Also Published As

Publication number Publication date
CN1033859C (en) 1997-01-22
EP0427697A2 (en) 1991-05-15
CN1109474A (en) 1995-10-04
CN1051684A (en) 1991-05-29
US5883202A (en) 1999-03-16
DE69026907D1 (en) 1996-06-13
JP3088012B2 (en) 2000-09-18
EP0427697A3 (en) 1991-08-14
EP0427697B1 (en) 1996-05-08
JPH03179005A (en) 1991-08-05
US5561092A (en) 1996-10-01
CA2027145A1 (en) 1991-04-11
ES2087145T3 (en) 1996-07-16
KR100196614B1 (en) 1999-06-15
CN1034125C (en) 1997-02-26
DE69026907T2 (en) 1996-10-10
CA2027145C (en) 2002-12-10

Similar Documents

Publication Publication Date Title
DE69025673D1 (en) Epiduralsauerstoffsensor
DE19675051I2 (en) Aminosaeurederivate
DE69025197T2 (en) Fötalsonde
DE10075018I1 (en) Imidazoalkensaeure
FI103123B1 (en) The catalysts used in the polymerization of olefins
FI98573B (en) Läheisyysdetektori
FI102082B1 (en) Jäähdytysnestekoostumuksia
DE68927695T2 (en) Silanabgeschlossene liquid polymers
DE69032680D1 (en) neural computer
DE69028777T2 (en) Microfabricated microscope unit
DE69028564T2 (en) resistant Perfluoropolyätheremulsionen
DE69024965D1 (en) dehydrodidemnin b
DE69017703D1 (en) Labels and their verfertigung.
AT170636T (en) Zweiwellenlängenlaserabtastmikroskop
AT188076T (en) Spreizspektrumkorrelator
AT403713T (en) Stamzellfaktor
AT290536T (en) Metallocene compound and their use in olefin polymerization
NO180162C (en) A closure
DE68928195D1 (en) Monitoring of database objects
ATA118588A (en) Schliessfachanlage with several lockers
DE69032697D1 (en) Coding and coding
FI902987A0 (en) Pakkaussovitelma
ATA902490A (en) A recombinant poxvirus-host-selection-system
DE69028718T2 (en) distribution unit
FI90878B (en) A method for reducing sheeting in the polymerization of alpha-olefins

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties