AR090938A1 - 6-piridon-2-carbamoil-azoles y su uso como herbicidas - Google Patents

6-piridon-2-carbamoil-azoles y su uso como herbicidas

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AR090938A1
AR090938A1 ARP130101525A AR090938A1 AR 090938 A1 AR090938 A1 AR 090938A1 AR P130101525 A ARP130101525 A AR P130101525A AR 090938 A1 AR090938 A1 AR 090938A1
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cycloalkyl
alkoxy
heterocyclyl
group
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Dr Braun Ralf
Dr Lehr Stefan
Dr Khn Arnim
Dr Dietrich Hansjrg
Dr Gatzweiler Elmar
Hugh Dr Rosinger Christopher
Schmutzler Dirk
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Bayer Cropscience Ag
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Reivindicación 1: 6-Piridon-2-carbamoil-azoles de la fórmula (1) o sus sales, en la que Q significa un resto de fórmula (2), (3), (4) ó (5); R³ significa alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, estando estos restos sustituidos respectivamente con s restos del grupo que se compone de halógeno, ciano, hidroxi, nitro, SiR¹⁰₃, PO(OR¹⁰)₂, S(O)ₙ-alquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, COR³ᵃ, COOR³ᵃ, OCOR³ᵃ, NR³ᵃCOR³ᵃ, NR³ᵃSO₂R³ᵇ, cicloalquilo C₃₋₆, heteroarilo, heterociclilo o fenilo, estando los 4 restos mencionados en último lugar sustituidos respectivamente con p restos del grupo que se compone de metilo, etilo, metoxi, trifluorometilo, ciano y halógeno y donde el heterociclilo porta n grupos oxo, o R³ significa fenilo, que está sustituido con p restos del grupo que se compone de halógeno, nitro, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, S(O)ₙ-alquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alcoxi C₁₋₆-alquilo C₁₋₄; R³ᵃ significa hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆ o cicloalquil C₃₋₆-alquilo C₁₋₆ o fenilo; R³ᵇ significa alquilo C₁₋₆, alquenilo C₂₋₆ o alquinilo C₂₋₆, cicloalquilo C₃₋₆ o cicloalquil C₃₋₆-alquilo C₁₋₆ o fenilo; R⁴ significa hidrógeno, alquilo C₁₋₆, cicloalquilo C₃₋₇, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquenilo C₂₋₆, alqueniloxi C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, alquiniloxi C₂₋₆, haloalquinilo C₂₋₆, alcoxi C₁₋₆-alquilo C₁₋₆, ciano, nitro, metilsulfenilo, metilsulfinilo, metilsulfonilo, acetilamino, benzoílamino, metoxicarbonilo, etoxicarbonilo, metoxicarbonilmetilo, etoxicarbonilmetilo, benzoilo, metilcarbonilo, piperidinilcarbonilo, trifluorometilcarbonilo, halógeno, amino, aminocarbonilo, metilaminocarbonilo, dimetilaminocarbonilo, metoximetilo, o heteroarilo, heterociclilo o fenilo respectivamente sustituidos con p restos del grupo que se compone de metilo, etilo, metoxi, trifluorometilo y heteroarilo, heterociclilo o fenilo sustituidos con halógeno; R⁵ significa hidrógeno, alquilo C₁₋₆, alcoxi C₁₋₆-alquilo C₁₋₆, CH₂R⁵ᵃ, cicloalquilo C₃₋₇, haloalquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆, OR⁶, NHR⁶, metoxicarbonilo, etoxicarbonilo, metoxicarbonilmetilo, etoxicarbonilmetilo, metilcarbonilo, trifluorometilcarbonilo, dimetilamino, acetilamino, metilsulfenilo, metilsulfinilo, metilsulfonilo o heteroarilo, heterociclilo, bencilo o fenilo respectivamente sustituidos con p restos del grupo que se compone de halógeno, nitro, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, S(O)ₙ-alquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alcoxi C₁₋₆-alquilo C₁₋₄; R⁵ᵃ significa acetoxi, acetamido, N-metilacetamido, benzoiloxi, benzamido, N-metilbenzamido, metoxicarbonilo, etoxicarbonilo, benzoilo, metilcarbonilo, piperidinilcarbonilo, morfolinilcarbonilo, trifluorometilcarbonilo, aminocarbonilo, metilaminocarbonilo, dimetilaminocarbonilo, alcoxi C₁₋₆, cicloalquilo C₃₋₆ o heteroarilo o heterociclilo respectivamente sustituidos con p restos del grupo que se compone de metilo, etilo, metoxi, trifluorometilo y halógeno; X significa alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₃₋₈, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, halocicloalquil C₃₋₆-alquilo C₁₋₆, OCOOR⁶, OC(O)N(R⁶)₂, OR⁶, OCOR⁶, OSO₂R⁷, alquil C₁₋₆-S(O)ₙR⁷, alquil C₁₋₆-OR⁶, alquil C₁₋₆-OCOR⁶, alquil C₁₋₆-OSO₂R⁷, alquil C₁₋₆-CO₂R⁶, alquil C₁₋₆-SO₂OR⁶, alquil C₁₋₆-CON(R⁶)₂, alquil C₁₋₆-CN, alquil C₁₋₆-SO₂N(R⁶)₂, alquil C₁₋₆-NR⁶COR⁶, alquil C₁₋₆-NR⁶SO₂R⁷, CH₂P(O)(OR¹⁰)₂, alquil C₁₋₆-arilo, alquil C₁₋₆-heteroarilo, alquil C₁₋₆-heterociclilo, estando los tres restos mencionados en último lugar sustituidos respectivamente con s restos del grupo que se compone de halógeno, ciano, nitro, alquilo C₁₋₆, haloalquilo C₁₋₆, S(O)ₙ-alquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆ y donde el heterociclilo porta n grupos oxo; Z significa hidrógeno, halógeno, ciano, rodano, nitro, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, alquil C₁₋₆-cicloalquilo C₃₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, halocicloalquil C₃₋₆-alquilo C₁₋₆, COR⁶, COOR⁶, OR⁶, OCOOR⁶, NR⁶COOR⁶, C(O)N(R⁶)₂, NR⁶C(O)N(R⁶)₂, OC(O)N(R⁶)₂, C(O)NR⁶OR⁶, OSO₂R⁷, S(O)ₙR⁷, SO₂OR⁶, SO₂N(R⁶)₂, NR⁶SO₂R⁷, NR⁶COR⁶, alquil C₁₋₆-S(O)ₙR⁷, alquil C₁₋₆-OR⁶, alquil C₁₋₆-OCOR¹, alquil C₁₋₆-OSO₂R⁷, alquil C₁₋₆-CO₂R⁶, alquil C₁₋₆-SO₂OR⁶, alquil C₁₋₆-CON(R⁶)₂, alquil C₁₋₆-SO₂N(R⁶)₂, alquil C₁₋₆-NR⁶COR⁶, alquil C₁₋₆-NR¹SO₂R⁷, N(R⁶)₂, P(O)(OR¹⁰)₂, heteroarilo, heterociclilo o fenilo, estando los tres restos mencionados en último lugar sustituidos respectivamente con s restos del grupo que se compone de halógeno, nitro, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, S(O)ₙ-alquilo C₁₋₆, alcoxi C₁₋₆ o haloalcoxi C₁₋₆ y donde el heterociclilo porta n grupos oxo; W significa hidrógeno, halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, S(O)ₙR¹⁰, o Z y W forman juntos con los átomos de carbono a los que están unidos, un sistema anular aromático de cinco o seis miembros, en el que p átomos C están sustituidos con heteroátomos del grupo que se compone de N, O y S, y que está sustituido con q restos del grupo que se compone de halógeno, nitro, ciano, alquilo C₁₋₆, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, S(O)ₙ-alquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆ y alcoxi C₁₋₆-alquilo C₁₋₆; R⁶ significa hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆, cicloalquilo C₃₋₆, cicloalquenilo C₃₋₆, halocicloalquilo C₃₋₆, alquil C₁₋₆-O-alquilo C₁₋₆, cicloalquil C₃₋₆-alquilo C₁₋₆, fenilo, fenil-alquilo C₁₋₆, heteroarilo, alquil C₁₋₆-heteroarilo, heterociclo, alquil C₁₋₆-heterociclilo, alquil C₁₋₆-O-heteroarilo, alquil C₁₋₆-O-heterociclilo, alquil C₁₋₆-NR⁸-heteroarilo, alquil C₁₋₆-NR⁸-heterociclilo, estando los 21 restos mencionados en último lugar sustituidos con s restos del grupo que se compone de ciano, halógeno, nitro, rodano, O
ARP130101525 2012-05-03 2013-05-03 6-piridon-2-carbamoil-azoles y su uso como herbicidas AR090938A1 (es)

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EP (1) EP2844650B1 (es)
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CN (1) CN104271564B (es)
AR (1) AR090938A1 (es)
AU (1) AU2013255839A1 (es)
BR (1) BR112014027183B1 (es)
CA (1) CA2872376A1 (es)
EA (1) EA201401203A1 (es)
MX (1) MX2014013036A (es)
WO (1) WO2013164333A1 (es)

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US20150111747A1 (en) 2015-04-23
BR112014027183B1 (pt) 2019-10-22
US9370184B2 (en) 2016-06-21
JP6134380B2 (ja) 2017-05-24
AU2013255839A1 (en) 2014-11-20
CN104271564A (zh) 2015-01-07
CN104271564B (zh) 2016-08-24
BR112014027183A2 (pt) 2017-06-27
EA201401203A1 (ru) 2015-04-30
CA2872376A1 (en) 2013-11-07
WO2013164333A1 (de) 2013-11-07
EP2844650B1 (de) 2016-03-23
JP2015523317A (ja) 2015-08-13
MX2014013036A (es) 2015-02-04

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