AR040413A1 - Heterociclilalquinos herbicidally active - Google Patents

Heterociclilalquinos herbicidally active

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AR040413A1
AR040413A1 ARP030101900A AR040413A1 AR 040413 A1 AR040413 A1 AR 040413A1 AR P030101900 A ARP030101900 A AR P030101900A AR 040413 A1 AR040413 A1 AR 040413A1
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c1
alkyl
times
c3
substituted
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Syngenta Participations Ag
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    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
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    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
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    • C07D241/12Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D241/14Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D241/10Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D241/10Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D253/00Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00
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    • C07D253/061,2,4-Triazines
    • C07D253/0651,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members
    • C07D253/071,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members with hetero atoms, or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links

Abstract

Reivindicación 1: Un compuesto de fórmula (1) en la cual Q representa un elemento del grupo (2); CLAIMS 1. A compound of formula (1) wherein Q represents an element of group (2); Z es =N-, lN+-O-, ó =C(R1)-; Z is = N-, lN + -O-, or = C (R1) -; n vale 0, 1, 2, 3 o 4;siendo cada R1, independientemente de los demás, halógeno, -CN, -SCN, -SFS, -NO2, -NR5R6, -CO2R7, -CONR8R9, -C(R10)=NOR11, -COR12, -OR13, -SR14, -SOR15, -SO2R16, -OSO2R17, C1-8alquilo, C2-8alquenilo, C2-8alquinilo o C3-6cicloalquilo; n is 0, 1, 2, 3 or 4, wherein each R1, independently of the other, halogen, -CN, -SCN, -SFS, -NO2, -NR5R6, -CO2R7, -CONR8R9, -C (R10) = NOR11, -COR 12, -OR 13, -SR 14, -SOR15, -SO2R16, -OSO2R17, C 1-8 alkyl, C2-8alquenilo, C2-8alquinilo or C3-6 cycloalkyl; o representa C1-8alquilo, C2-8alquenilo, o C2-8alquinilo substituidos de una a cinco veces con halógeno o de una a tres veces con -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C(R24)=NOR25, -C(S)NR26R27, -C(C1-4alquiltio)=NR28, -OR29, -SR30, -SOR31, -SO2R32 o con C3-6cicloalquilo; or represents 1-8 alkyl, C2-8alquenilo or C2-8alquinilo monosubstituted to pentasubstituted by halogen or one to three times with -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C ( R24) = NOR25, -C (S) NR26R27, -C (C1-4alquiltio) = NR28, -OR 29, -SR30, -SOR31, -SO2R32 or C3-6 cycloalkyl; y/o cada R1, independientemente de los demás representa C3-6cicloalquilo substituido de una a cinco veces con halógeno, o de una a tres veces con -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C(R24)=NOR25, -C(S)NR26R27, -C(C1-4alquiltio)=NR28, -SR30, -SOR31, -SO2R32 ó C3-6cicloalquilo; and / or each R1, independently of the others represents C3-6 cycloalkyl substituted one to five times by halogen, or with one to three -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C (R24) = NOR25, -C (S) NR26R27, -C (C1-4alquiltio) = NR28, -SR30, -SOR31, -SO2R32 or C3-6 cycloalkyl; y/o cada R1, independientemente de los demás representa fenilo que por su parte puede estar substituido de una a cinco veces con halógeno o C1-4alquilo o de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o C1-4alquilsulfonilo; and / or each R1, independently of the others represents phenyl which in turn may be monosubstituted to pentasubstituted by halogen or C1-4 alkyl or one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2 , C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl; y/o dos substituyentes R1 adyacentes juntos forman un puente C1-7alquileno que puede estar interrumpido por 1 a 3 heteroátomos seleccionados entre oxígeno, nitrógeno y azufre y que puede estar substituido de una a cinco veces con halógeno o con C1-6alquilo, o de una a tres veces con C1-6alcoxi, siendo la cantidad total de átomos de anillo por lo menos de 5 ya lo sumo de 9; and / or two adjacent substituents R1 together form a bridge C1-7alquileno which may be interrupted by 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur and which may be monosubstituted to pentasubstituted by halogen or C1-6 alkyl, or one to three times with C1-6 alkoxy, wherein the total amount of ring atoms at least 5 and at most 9; y/o dos substituyentes R1 adyacentes juntos forman un puente C2-7alquenileno que puede estar interrumpido por 1 a 3 heteroátomos seleccionados entre oxígeno, nitrógeno y azufre y que puede estar substituido de una a cinco veces con halógeno o C1-6alquilo o de una a tres veces con C1-6alcoxi, siendo la cantidad total de átomos de anillo por lo menos de 5 ya lo sumo de 9; and / or two adjacent substituents R1 together form a bridge C2-7alquenileno which may be interrupted by 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur and which may be monosubstituted to pentasubstituted by halogen or C 1-6 alkyl or one to three times with C1-6alkoxy, wherein the total amount of ring atoms at least 5 and at most 9; R3 y R4 independientemente entre sí, representan hidrógeno, halógeno, -CN, C1-4alquilo o C1-4alcoxi; R3 and R4 independently represent hydrogen, halogen, -CN, C 1-4 alkyl or C 1-4 alkoxy; o R3 y R4 juntos forman C2-5alquileno; or R3 and R4 together form C2-5alquileno; R5 representa hidrógeno o C1-8alquilo; R5 represents hydrogen or C 1-8 alkyl; R6 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o estar substituidos de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo, o R5 y R6 conjuntamente son una cadena C2-5alquileno que puede estar interrumpida por un átomo de oxígeno o de azufre; R6 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl for their part be substituted one to five times by halogen or C1-4alkyl or be substituted one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl, or R5 and R6 together are a C2-5alquileno chain may be interrupted by an oxygen atom or sulfur ; R7 representa hidrógeno, C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o es C1-8alquilo, C3-8alquenilo o C3-8alquinilo substituidos de una a cinco veces con halógeno o de una a tres veces con substituido de una a tres veces con C1-4alcoxi o con fenilo, pudiendo el fenilo por su parte estar substituido de una a cinco veces con halógeno o con C1-4alquilo o de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo, o C1-4alquilsulfonilo; R7 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo, or C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo monosubstituted to pentasubstituted by halogen or one to three times with monosubstituted to trisubstituted with C 1-4 alkoxy or phenyl, wherein the phenyl in turn to be substituted one to five times by halogen or C1-4 alkyl or one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1 -4alquiltio, C1-4alquilsulfinilo, or 1-4 alkyl; R8 representa hidrógeno o C1-8alquilo; R8 represents hydrogen or C 1-8 alkyl; R9 representa hidrógeno o C1-8alquilo, o C1-8alquilo substituido de una a tres veces con -COOH, C1-8alcoxicarbonilo o -CN; R9 represents hydrogen or C 1-8 alkyl, or C 1-8 alkyl substituted one to three times with -COOH, C1-8alcoxicarbonilo or -CN; o R9 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; or R9 represents C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl for their part be substituted one to five times by halogen or C1-4 alkyl or substituted one to three times with C1-4haloalquilo, C1- 4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl; o R8 y R9 representan conjuntamente C2-5alquileno; or R8 and R9 together represent C2-5alquileno; R10 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo;R11 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, C1-4haloalquilo o C3-6haloalquenilo; R10 represents hydrogen, C1-4 alkyl, C3-6 cycloalkyl or C1-4haloalquilo; R11 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl, C3-8alquinilo, C1-4haloalquilo or C3-6haloalquenilo; R12 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo;R13 representa hidrógeno, C1-8alquilo, C3-8alquenilo o C3-8alquinilo; R12 represents hydrogen, C1-4 alkyl, C3-6 cycloalkyl or C1-4haloalquilo; R13 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo; o R13 representa fenilo o fenil-C1-6alquilo, pudiendo por su parte el anillo fenilo estar substituido de una a cinco veces con C1-4alquilo o de una a tres veces con C1-4halo-alquilo, C1-4alcoxi, -CN, -NO2, C1-8alquiltio, C1-8alquilsulfinilo o C1-8alquilsulfonilo; or R13 represents phenyl or phenyl-C1-6 alkyl, can in turn be substituted phenyl ring one to five times with C1-4 alkyl or one to three times with C1-4halo alkyl, C 1-4 alkoxy, -CN, - NO2, C1-8alquiltio, C1-8alquilsulfinilo or C1-8alquilsulfonilo; o R13 representa C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN, C1-6alquilamino, di(C1-6alquil)amino o con C1-4alcoxi; or R13 represents C 1-8 alkyl substituted one to five times by halogen or monosubstituted to trisubstituted by -CN, C 1-6 alkylamino, di (C1-6alkyl) amino or C 1-4 alkoxy; R14 representa hidrógeno, C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con o de una a tres veces con -CN o C1-4alcoxi; R14 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo, or C 1-8 alkyl substituted one to five times or once to three times with C 1-4 alkoxy or -CN; R15, R16 y R17 independientemente entre si representan cada uno de ellos C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN o C1-4alcoxi; R15, R16 and R17 independently of one another represent each C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo, or C 1-8 alkyl substituted one to five times by halogen or monosubstituted to trisubstituted by -CN or C1- 4alcoxi; R18 representa hidrógeno o C1-8alquilo; R18 represents hydrogen or C 1-8 alkyl; R19 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R19 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl for their part be substituted one to five times by halogen or C1-4 alkyl or substituted one to three times with C1 -4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl; o R18 y R19 conjuntamente representan una cadena C2-5alquileno que puede estar interrumpida por un átomo de oxígeno o de; or R18 and R19 together represent a C2-5alquileno chain may be interrupted by an oxygen atom or; R20 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R20 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl for their part be substituted one to five times by halogen or C1-4 alkyl or substituted one to three times with C1 -4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl; R21 representa hidrógeno o C1-8alquilo; R21 represents hydrogen or C 1-8 alkyl; R22 representa hidrógeno o C1-8alquilo, o es C1-8alquilo substituido de una a tres veces con -COOH, C1-8alcoxicarbonilo o -CN, o R22 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R22 represents hydrogen or C 1-8 alkyl, or C 1-8 alkyl substituted one to three times with -COOH, C1-8alcoxicarbonilo or -CN, or R22 represents C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl Meanwhile be monosubstituted to pentasubstituted by halogen or C1-4 alkyl or substituted one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo 1-4 alkyl or ; o R21 y R22 conjuntamente son una cadena C2-5alquileno; or R21 and R22 together are a chain C2-5alquileno; R23 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo; R23 represents hydrogen, C1-4 alkyl, C3-6 cycloalkyl or C1-4haloalquilo; R24 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo; R24 represents hydrogen, C1-4 alkyl, C3-6 cycloalkyl or C1-4haloalquilo; R25 representa hidrógeno, C1-4alquilo,C3-8alquenilo, C3-8alquinilo, C1-4haloalquilo o C3-6haloalquenilo; R25 represents hydrogen, C1-4 alkyl, C 3-8 alkenyl, C3-8alquinilo, C1-4haloalquilo or C3-6haloalquenilo; R26 representa hidrógeno o C1-8alquilo; R26 represents hydrogen or C 1-8 alkyl; R27 representa hidrógeno o C1-8alquilo, o es C1-8alquilo substituido de una a tres veces con -COOH, C1-8-alcoxicarbonilo o -CN, o R27 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R27 represents hydrogen or C 1-8 alkyl, or C 1-8 alkyl substituted one to three times with -COOH, C1-8 alkoxycarbonyl or -CN, or R27 represents C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl for their part be substituted one to five times by halogen or C1-4 alkyl or substituted one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, or C1 C1-4alquilsulfinilo -4alquilsulfonilo; o R26 y R27 conjuntamente representan una cadena C2-5alquileno; or R26 and R27 together represent a chain C2-5alquileno; R28 representa hidrógeno o C1-8alquilo; R28 represents hydrogen or C 1-8 alkyl; R29 y R30 independientemente entre sí representan hidrógeno, C1-8alquilo,C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN o C1-4alcoxi; R29 and R30 independently represent hydrogen, C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo, or C 1-8 alkyl substituted one to five times by halogen or monosubstituted to trisubstituted by -CN or C 1-4 alkoxy; R31 y R32 independientemente entre sí, representan C1-8alquilo, C3-8alquenilo o C3-8alquinilo, o C1-8alquilo substituido de una a cinco veces con halógeno o substituido de una a tres veces con -CN o C1-4alcoxi; R31 and R32 independently represent C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo, or C 1-8 alkyl substituted one to five times by halogen or monosubstituted to trisubstituted by -CN or C 1-4 alkoxy; m vale 0, 1, 2 o 3; m is 0, 1, 2 or 3; cada uno de los R2 independientemente de los demás, representa halógeno, -CN, -SCN, -OCN, -N3, -SF5, -NO2, -NR33R34, -CO2R35, -CONR36R37, -C(R38)=NOR39, -COR40, -OR41, -SR42, -SOR43, -SO2R44, -OSO2R45, -N([CO]pR46)COR47, -N(OR54)COR55, -N(R56)SO2R57, -N(SO2R58)SO2R59, -N=C(OR60)R61, -CR62(OR63)OR64, -OC(O)NR65R66, -SC(O)NR67R68, -OC(S)NR69R70 o -N-ftalimida; each R2 independently of the other, represents halogen, -CN, -SCN, -OCN, -N3, -SF5, -NO2, -NR33R34, -CO2R35, -CONR36R37, -C (R38) = NOR39, -COR40 , -OR41, -SR42, -SOR43, -SO2R44, -OSO2R45, -N ([CO] PR46) COR47, -N (OR54) COR55, -N (R56) SO2R57, -N (SO2R58) SO2R59, -N = C (oR 60) R61, -CR62 (OR63) OR64, -OC (O) NR65R66, -SC (O) NR67R68, -OC (S) NR69R70 or -N-phthalimide; y/o R2 representa un sistema de anillo heterocíclico de 5 a 7miembros que puede ser aromático, o estar saturado total o parcialmente y que puede contener de 1 a 4 heteroátomos seleccionados entre nitrógeno, oxígeno y azufre, pudiendo dicho sistema de anillo heterocíclico estar substituido de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, hidroxi-C1-4alquilo, C1-4alcoxi, C1-4alcoxi-C1-4alquilo, -CN, -NO2, C1-6alquiltio, C1-6alquilsulfinilo o C1-6alquilsulfonilo; and / or R2 represents a heterocyclic ring system of 5 to 7-membered which may be aromatic, or be completely saturated or partially and which may contain 1 to 4 heteroatoms selected from nitrogen, oxygen and sulfur, and said heterocyclic ring system being substituted one to five times by halogen or C1-4 alkyl or substituted one to three times with C1-4haloalquilo, hydroxy-C 1-4 alkyl, C 1-4 alkoxy, C 1-4 alkoxy-C 1-4 alkyl, -CN, -NO2, C1- 6alquiltio, C1-6alquilsulfinilo or C1-6alquilsulfonilo; R33 representa hidrógeno o C1-8alquilo; R33 represents hydrogen or C 1-8 alkyl; y R34 representa hidrógeno, C1-8alquilo, C3-8alquenilo, C3-8alquinilo, CH3C(O)-, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; and R34 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl, C3-8alquinilo, CH3C (O) -, phenyl or benzyl, where phenyl and benzyl for their part be substituted one to five times by halogen or C1-4 alkyl or substituted one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl; o R33 y R34 representan conjuntamente una cadena C2-5alquileno que puede estar interrumpida por un átomo de oxígeno o con un átomo de azufre; or R33 and R34 together represent a C2-5alquileno chain may be interrupted by an oxygen atom or a sulfur atom; R35 representa hidrógeno, C1-8alquilo,C3-8alquenilo o C3-8alquinilo, o representa C1-8alquilo, C3-8alquenilo o C3-8alquinilo substituidos de una a cinco veces con halógeno o substituido de una a tres veces con C1-4alcoxi o fenilo, pudiendo fenilo por su parte estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o substituido de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; R35 represents hydrogen, C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo, or represents C 1-8 alkyl, C 3-8 alkenyl or C3-8alquinilo monosubstituted to pentasubstituted by halogen or monosubstituted to trisubstituted by C 1-4 alkoxy or phenyl , phenyl may in turn be monosubstituted to pentasubstituted by halogen or C1-4 alkyl or substituted one to three times with C1-4haloalquilo, C 1-4 alkoxy, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or with 1-4 alkyl; R36 representa hidrógeno o C1-8alquilo; R36 represents hydrogen or C 1-8 alkyl; R37 representa hidrógeno o C1-8alquilo, o C1-8alquilo substituido de una a tres veces con -COOH, C1-8alcoxicarbonilo o -CN; R37 represents hydrogen or C 1-8 alkyl, or C 1-8 alkyl substituted one to three times with -COOH, C1-8alcoxicarbonilo or -CN; o R37 representa C3-8alquenilo, C3-8alquinilo, fenilo o bencilo, pudiendo fenilo y bencilo a su vez estar substituidos de una a cinco veces con halógeno o con C1-4alquilo o estar substituidos de una a tres veces con C1-4haloalquilo, C1-4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo o con C1-4alquilsulfonilo; or R37 represents C 3-8 alkenyl, C3-8alquinilo, phenyl or benzyl, where phenyl and benzyl in turn be substituted by one to five times by halogen or C1-4alkyl or be substituted one to three times with C1-4haloalquilo, C1 -4alcoxi, -CN, -NO2, C1-4alquiltio, C1-4alquilsulfinilo or 1-4 alkyl; o R36 y R37 conjuntamente representan C3-5alquileno; or R36 and R37 together represent C3-5alquileno; R38 representa hidrógeno, C1-4alquilo, C1-4haloalquilo o C3-6cicloalquilo; R38 represents hydrogen, C1-4 alkyl, C3-6 cycloalkyl or C1-4haloalquilo; R39 representa hidrógeno, C1-8alquilo, C3-8a R39 represents hydrogen, C 1-8 alkyl, C3-8a
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